Labelling ecofriendly products in india — an emerging option for environmental production

Summary The labelling of ecofriendly products has been introduced in a number of developed countries to assist in the protection of the environment. Recently, developing countries like India, have introduced the scheme. This paper examines the steps involved in establishing the Indian Ecomark. For the successful implementation of the scheme the effective coordination of a number of agencies is necessary. Consumers, as well as manufacturers, have to be educated in the longterm benefits of the scheme. Initiatives necessary for the successful implementation of Ecomark have been highlighted.Mr S. S. Arvind is a member of faculty at the Centre for Energy, Environment and Technology, at the Administrative Staff College of India. He is currently on secondment to the Centre for Technology Development, Clark University, 950, Main Street, Worcester MA 01610-1477, USA. Mr E.V. Muley is a scientist working for the Ministry of Environment and Forests, Government of India, Paryavaran Bhavan, CGO Complex, Lodi Road, New Delhi 110003, India.     

Effect of multiwalled carbon nanotubes on UASB microbial consortium

The continuous rise in production and applications of carbon nanotubes (CNTs) has grown a concern about their fate and toxicity in the environment. After use, these nanomaterials pass through sewage and accumulate in wastewater treatment plants. Since, such plants rely on biological degradation of wastes; their activity may decrease due to the presence of CNTs. This study investigated the effect of multiwalled carbon nanotubes (MWCNTs) on upflow anaerobic sludge blanket (UASB) microbial activity. The toxic effect on microbial viability, extracellular polymeric substances (EPS), volatile fatty acids (VFA), and biogas generation was determined. The reduction in a colony-forming unit (CFU) was 29 and 58 % in 1 and 100 mg/L test samples, respectively, as compared to control. The volatile fatty acids and biogas production was also found reduced. The scanning electron microscopy (SEM) and fluorescent microscopy images confirmed that the MWCNT mediated microbial cell damage. This damage caused the increase in EPS carbohydrate, protein, and DNA concentration. Fourier transform infrared (FTIR) spectroscopy results supported the alterations in sludge EPS due to MWCNT. Our observations offer a new insight to understand the nanotoxic effect of MWCNTs on UASB microflora in a complex environment system.     

Development of eco-friendly bioplastic like PHB by distillery effluent microorganisms

During screening for poly-β-hydroxybutyrate (PHB) producing bacteria from distillery effluent sample, six out of 30 isolates comprising of three strains of Alcaligenes sp., two strains of Bacillus sp., and one strain of Pseudomonas sp. were found to accumulate varying levels of intracellular PHB. Amongst the various isolates, Alcaligenes sp. RZS4 was found as the potent PHB-producing organism, accumulating higher amounts of PHB. PHB productivity was further enhanced in the presence of oxygen, nitrogen-limiting conditions, and cloning of PHB synthesizing genes of Alcaligenes sp. RZS 4 into Escherichia coli. A twofold increase in PHB yield was obtained from recombinant E. coli vis-à-vis Alcaligenes sp.; the recombinant E. coli accumulated more PHB in NDMM, produced good amount of PHB in a single-stage cultivation process under both nutrient-rich and nutrient-deficient conditions. Extraction of PHB with acetone–alcohol (1:1) was found as suitable method for optimum extraction of PHB as this mixture selectively extracted PHB without affecting the non-PHB cell mass. PHB extract from recombinant E. coli showed the presence of C–H, =O stretching, =C–H deformation, =C–H, =CH, and =C–O functional groups characteristic of PHB.     

Nanosystems for drug delivery of coenzyme Q10

Coenzyme Q10 is an antioxidant present in the human body. Coenzyme Q10 has an essential role in various biochemical reactions. The deficiency of coenzyme Q10 in the body leads to disorders including neurological degeneration, ageing and cancer. Clinical trials have tested coenzyme Q10 as a drug or a dietary supplement. However, the major pharmaceutical issue of coenzyme Q10 delivery is its high molecular weight and poor water solubility. This limitation leads to its poor oral bioavailability. Several methods have been designed to overcome the poor water solubility of coenzyme Q10, such as size reduction and ionization. This article presents nanotechnology-based drug delivery systems for coenzyme Q10 with special emphasis on pharmacokinetic perspectives and clinical relevance. Systems include nanoparticles, solid dispersions, liposomes, nanoemulsions, self-emulsifying drug delivery systems, nanostructured lipid carriers, cyclodextrins and nanocapsules.     

A Time-Dependent System for Evaluating Groundwater Contamination Hazard Rating of Municipal Solid Waste Dumps

In developing countries, several old municipal solid waste dumps (unlined landfills) exist adjacent to large cities, releasing contaminants to the underlying aquifer, thus posing the hazard of groundwater contamination. These uncontrolled waste dumps need to be prioritized in terms of the groundwater contamination hazard posed by them, so that necessary control and remedial measures can be undertaken in a phased manner. This paper presents a time-dependent system for evaluating groundwater contamination hazard rating of municipal solid waste dumps. The system is based on source–pathway–receptor relationships and evaluates the relative value of hazard posed by a site over its entire leaching life, on a scale of 0–1,000. The system parameters have been selected based on literature and expert opinions. The Delphi technique is used to derive the relative importance weights of the system parameters. The proposed system is compared with six selected existing hazard rating systems. The comparison, made by way of score range analysis, shows that the proposed system exhibits a much wider range of hazard scores for various scenarios of site conditions, and hence the proposed system is more sensitive to varied site conditions. The application of different systems to six municipal solid waste dumps located in four cities of India shows that, whereas the existing systems individually produce clustered scores and return the same rank to more than one site, the proposed system produces significantly varying scores and return different ranks to different sites. This demonstrates that the proposed system improves decision making and makes a better basis for prioritization of municipal solid waste dumps for adopting control and remedial measures.     

Color removal from paper mill effluent through adsorption technology

The bagasse fly ash, obtained from the local sugar industry, has been used as an inexpensive and effective adsorbent for the removal of color from pulp and paper industry. Effect of various operating variables, viz., contact time, initial concentration, adsorbent dose and particle size on the removal of color has been studied and discussed. It is found that for optimum removal of color, contact time for adsorption equilibrium equals to 60 min., at dosage of 2 g/l of baggase fly ash. The material exhibits good removal capacity (86%) and follows both the Langmuir and the Freundlich models.     

Degradation of anionic surfactants during drying of UASBR sludges on sand drying beds

Anionic surfactant (AS) concentrations in wet up-flow anaerobic sludge blanket reactor (UASBR) sludges from five sewage treatment plants (STPs) were found to range from 4480 to 9233mgkg(-1)drywt. (average 7347mgkg(-1)drywt.) over a period of 18 months. After drying on sand drying beds (SDBs), AS in dried-stabilized sludges averaged 1452mgkg(-1)drywt., a reduction of around 80%. The kinetics of drying followed simple first-order reduction of moisture with value of drying constant (k(d))=0.051d(-1). Reduction of AS also followed first-order kinetics. AS degradation rate constant (k(AS)) was found to be 0.034d(-1) and half-life of AS as 20 days. The order of rates of removal observed was k(d)>k(AS)>k(COD)>k(OM) (drying >AS degradation>COD reduction>organic matter reduction). For the three applications of dried-stabilized sludges (soil, agricultural soil, grassland), values of risk quotient (RQ) were found to be <1, indicating no risk.     

Limnochemistry and nutrient dynamics in Upper Lake, Bhopal, India

In limnetic ecosystem, water quality depends upon physical, chemical, and biological factors. Effects of temperature, light scattering, and absorption by suspended and dissolved matter, transport, and mixing of nutrients within the lake are the significant factors as far as water quality is concerned. Nutrient loading into the lake and internal cycling of nutrients is always a matter of concern and critical to number of processes. During the winter season, heat and momentum transfer at the lake surface and the temperature-density relation of water destabilize the water column and drive vertical mixing and transport processes. The deepening of the surface layer produces nutrient transfer from the hypolimnion into the euphotic zone of epilimnion. It may also resuspend sediments that would have settled under stratified conditions, or redistribute particles that may still be in suspension. Thus, there exists a complex connection between the hydrodynamics and water quality issues. Present study is an effort to understand how seasonal changes in the limnetic ecosystem regulate the limnochemistry and movement of nutrient. The study revealed that significant variations of nutrients and organic load were observed between epilimnion and hypolimnion during summer season, and the lake was found in hyper-eutrophic condition throughout the study period.     

An HPLC method development for the assessment of degradation products of anthraquinone dye

The behavior of metsulfuron-methyl and its residues in an artificial pond was studied using a ¹⁴C isotopic tracer technique. Throughout the experimental period, the majority of metsulfuron-methyl residues were sustained in the pond water. Furthermore, the metsulfuron-methyl residues were just found in the surface layer of the sediment, and the transfer distance of these residues had only reached 9?C12 cm by the end of the experiment. The extract residues of metsulfuron-methyl in sediment were slightly higher than those of the bound residues (BR) during the initial experiment stage, while the BR dominated the surface sediment after 45 days. Finally, the metsulfuron-methyl residues could be combined with humus in the surface sediment, and the distribution of metsulfuron-methyl residues in fulvic acid was significantly higher than that in humic acid.     

Greenhouse gas emissions from municipal solid waste management in Indian mega-cities: a case study of Chennai landfill sites

Municipal solid waste generation rate is over-riding the population growth rate in all mega-cities in India. Greenhouse gas emission inventory from landfills of Chennai has been generated by measuring the site specific emission factors in conjunction with relevant activity data as well as using the IPCC methodologies for CH4 inventory preparation. In Chennai, emission flux ranged from 1.0 to 23.5mg CH4m(-2)h(-1), 6 to 460microg N2Om(-2)h(-1) and 39 to 906mg CO2m(2)h(-1) at Kodungaiyur and 0.9 to 433mg CH4m(-2)h(-1), 2.7 to 1200microg N2Om(-2)h(-1) and 12.3 to 964.4mg CO2m(-2)h(-1) at Perungudi. CH4 emission estimates were found to be about 0.12Gg in Chennai from municipal solid waste management for the year 2000 which is lower than the value computed using IPCC, 1996 [IPCC, 1996. Report of the 12th session of the intergovernmental panel of climate change, Mexico City, 1996] methodologies.