Chemical valorization of forest and agricultural by-products. Obtention, chemical characteristics, and mechanical behavior of a novel family of hydrophobic films

Esterification of hemicelluloses of the xylan family was performed in order to produce hydrophobic films. Acylation reactions were carried out with lauroyl chloride in the N,N-dimethylacetamide/lithium chloride homogeneous system using 4-dimethylaminopyridine as activator and were induced by microwave irradiation. In the experimental conditions used, 108 and 172% mass ratios were obtained for the dodecyl-grafted xylan and heteroxylan, respectively. The degrees of substitution (DS) were 1.3 (maximum 2) for xylan and 1.2 (maximum 2.1) for heteroxylan. These products were further characterized by FT-IR spectroscopy. The mechanical and thermomechanical behavior of this new family of hydrophobic films were analyzed and compared to those obtained from cellulose with a similar DS by the means of tensile tests. Our results indicate that the dodecyl-grafted xylan film presents the best rigidity-resistance to traction ratio.     

Thio arsenosugars in freshwater mussels from the Danube in Hungary

In contrast to the large body of data on naturally-occurring arsenic compounds in marine organisms, relatively little is known about arsenic speciation in freshwater biota. We report an investigation using HPLC-ICPMS into the arsenic compounds in five species of freshwater mussels collected from five sites from the Danube in Hungary. Total arsenic concentrations in the mussels ranged from 3.8-12.8 mg As kg(-1). The arsenic speciation patterns were broadly similar for mussels representing each of the five species and five sites, but quite different from those reported for marine mussels. The major extractable arsenicals were two oxo arsenosugars (glycerol sugar and phosphate sugar), and their thio analogues (thio glycerol sugar and thio phosphate sugar). Arsenobetaine, usually the major arsenical in marine organisms, was not a significant compound in the freshwater mussels and was detected in only three of the 11 samples. This is the first report of thio arsenosugars in freshwater biota and suggests that these compounds may be common and widespread naturally-occurring arsenicals.     

Predictors of intentions to leave the ward,the hospital,and the nursing profession: A longitudinal study

The stages preceding and following the intention to withdraw from an organization have not been adequately examined. Data were collected at two time periods from a sample of 146 nurses working in a general hospital located in a large metropolitan area in Israel. Essentially, intention to withdraw from three levels — ward, hospital and profession — were examined. LISREL was used to test alternative longitudinal models for the best fitting set of linkages among variables. The findings supported a progression model of withdrawal intention. According to this conceptualization, a nurse first decides to leave the ward, then the hospital, and, finally, the profession. Theoretical and practical implications of the results were presented.     

Monitoring the changes in impervious surface ratio and urban heat island intensity between 1987 and 2011 in Szeged,Hungary

Landsat time series data make it possible to continuously map and examine urban land cover changes and effects on urban environments. The objectives of this study are (1) to map and analyse an impervious surface and its changes within a census district and (2) to monitor the effects of increasing impervious surface ratios on population and environment. We used satellite images from 1987, 2003 and 2011 to map the impervious surface ratio in the census district of Szeged, Hungary through normalized spectral mixture analysis. Significant increases were detected from 1987 to 2011 in industrial areas (5.7–9.1%) and inner residential areas (2.5–4.8%), whereas decreases were observed in the city centre and housing estates due to vegetation growth. Urban heat island (UHI) values were derived from the impervious surface fraction map to analyse the impact of urban land cover changes. In 2011, the average value in the industrial area was 1.76 °C, whereas that in the inner residential area was 1.35–1.69 °C. In the city centre zones and housing estates, values ranging from 1.4 to 1.5 °C and from 1.29 to 1.5 °C, respectively, were observed. Our study reveals that long-term land cover changes can be derived at the district level from Landsat images and that their effects can be identified and analysed, providing important information for city planners and policy makers.     

Correlates of relocation intention and emotional responses to an Israeli plant relocation

Prior to a relocation of a governmental organization in Israel, 155 workers responded to a questionnaire tapping three criteria: the intention to relocate, positive feelings, and stress reactions. The questionnaire also addressed potential correlates: biographical data, family-related variables, perceived attitudes of co-workers, job satisfaction and centrality, and anticipations regarding work and nonwork aspects. The intention to relocate was associated mainly with the perceived attitude of the spouse and the children. Stress experienced was most strongly related to the future job prospects, and the positive emotions were mostly correlated with the perceived favourability of the anticipated changes. The family-related variables were found to be significantly correlated with all the criteria. These results suggest that organization should direct efforts on spouse and children in order to influence employees' decisions and feelings regarding relocation. This and other implications are discussed.     

AZFc deletion detected in a newborn with prenatally diagnosed Yq deletion

A case of prenatally diagnosed Yq deletion is described. Fluorescence in situ hybridisation (FISH) was used to identify the abnormal chromosome and to exclude mosaicism. Based on the cytogenetic result and the ultrasound investigation the pregnancy was continued. A newborn with normal male genitalia was delivered. Microdeletion analysis of the Yq showed the absence of the AZFc region. This type of deletion has been described as being associated with azoospermia or oligozoospermia with a progressive decrease of sperm number over time. Long-term andrological follow-up of the newborn will be necessary with eventual cryoconservation of sperm at early adulthood. The present report proposes that AZF analysis combined with FISH has an important role in accurate genetic counselling in sex chromosome anomalies. Copyright © 2001 John Wiley & Sons, Ltd.