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One of the methods to diminish the internal phosphorus (P) loading is inactivation of P by aluminum (Al). After addition of Al to lake water an Al(OH)3 floc is formed, which settles to the bottom and initially form a lid on the sediment surface. The effects of Chironomus plumosus larvae on sediment nutrient fluxes and P binding-sites in the sediment after addition of Al were tested. C. plumosus larvae were added to sediment cores in which sediment–water fluxes of nutrients were measured four times. After one month, the sediment was sectioned with depth and P fractions were measured by sequential chemical extraction. The chironomids created burrows through the Al layer which caused a significantly increased efflux of P from the Al treated sediment, because the P had only limited contact to the added Al. The chironomids also affected the P fractions in the sediment by their bioturbating activity. Thus, they caused increased Al concentrations in the upper part of the Al treated sediment. This created an enhanced contact between Al and P in the upper 7 cm of the sediment and, as a result, an increased binding of P to Al and a lowered porewater P. The DIP efflux is therefore expected to be lowered after the initial phase. Al had no effects on the nitrogen fluxes, but the chironomids enhanced the release, and decreased the release or increased the uptake by the sediments.  相似文献   
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ABSTRACT: Complex hydrologic models, designed for simulating larger watersheds, require a huge amount of input data. Most of these models use spatially distributed data as inputs. Spatial data can be aggregated or disaggregated for use as input to a model, which can impact model outputs. Although, it is efficient to minimize data redundancy by aggregating the spatial data, upscaling reduces the detail/resolution of input information and increases model uncertainty. On the other hand, a large number of model inputs with high degrees of disaggregation take more computer time and space to process. Hence, a balance between striving for a maximum level of aggregation and a minimum level of information loss has to be achieved. This study presents a definition of an appropriate level of discretization, derived by establishing a relationship between a model's efficiency and the number of subwater‐sheds modeled. An entropy based statistical approach/tool called Subwatershed Spatial Analysis Tool (SUSAT) was developed to find an objective choice of an appropriate level of discretization. The new approach/tool was applied to three watersheds, each representing different hydrologic conditions, using a hydrologic model. Coefficients of efficiency and entropy estimated at different levels of discretization were used to validate the success of the new approach.  相似文献   
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Reducing pesticide loads in surface waters implies identifying the pathways responsible for the pollution. The current study documents the pesticide contamination of the river Zwester Ohm, a 4917-ha catchment in Germany with 41% of the land used for crop production. Discharges and concentrations of 19 pesticides were measured continuously at three locations for 15 mo. The load detected at the outlet of the catchment amounted to 9048 g a.i. The losses represent 0.22% of the pesticides applied by the farmers. The contamination showed a seasonal pattern following the pesticide application times. The wastewater treatment plant system (WWTPS) in the catchment (two wastewater treatment plants [WWTP], 14 combined sewer overflows (CSO), four CSO tanks) emits during dry weather periods purified sewage and during storm events sewage mixed with stormwater runoff into the river. The contribution by the WWTPS to the pesticide load was defined as point-source pollution (PSP). The load was dominated by PSP with at least 77% of the total pollution. No significant interdependencies between intrinsic properties of the pesticides, hydrometeorological factors, and the loads occurring in the stream could be found. Therefore, it is not possible to predict PSP for other catchments based on the results from this study. Whereas 65% of the total load entered the river via the WWTP, a portion of 12% was attributed to the CSO. The study points out that the influence of CSO on PSP should be taken into account in future catchment studies in areas with comparable agricultural structure.  相似文献   
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