Compost amendment of Cu-Zn minespoil reduces toxic bioavailable heavy metal concentrations and promotes establishment and biomass production of Bromus carinatus (Hook and Arn.)

A series of lab and greenhouse studies were undertaken to understand how Cu and Zn toxicity influences Bromus carinatus (Hook and Arn.) growth, to what degree an organic amendment (yard waste compost) may reduce Cu and Zn bioavailability in Cu-Zn minespoil and promote plant growth in combination with fertilizer, and how the vertical distribution of compost in the minespoil influences rooting depth. Root Cu and Zn toxicity thresholds were determined to be 1 mgL(-1) and 10 mgL(-1) in solution, respectively. The compost amendment had exceptionally high Cu and Zn binding capacities (0.17 and 0.08 g metal g C(-1), for Cu and Zn, respectively) that were attributed to high compost humic and fulvic acid concentrations. Maximum plant biomass was achieved when minespoil was amended with compost and fertilizer in combination. Fertilizer alone had no effect on plant growth. Mixing compost into the minespoil was essential to promote adequate rooting depth.     

Potential use of thermophilic dark fermentation effluents in photofermentative hydrogen production by Rhodobacter capsulatus

Biological hydrogen production by a sequential operation of dark and photofermentation is a promising route to produce hydrogen. The possibility of using renewable resources, like biomass and agro-industrial wastes, provides a dual effect of sustainability in biohydrogen production and simultaneous waste removal. In this study, photofermentative hydrogen production on effluents of thermophilic dark fermentations on glucose, potato steam peels (PSP) hydrolysate and molasses was investigated in indoor, batch operated bioreactors. An extreme thermophile Caldicellulosiruptor saccharolyticus was used in the dark fermentation step, and Rhodobacter capsulatus (DSM1710) was used in the photofermentation step. Addition of buffer, Fe and Mo to dark fermentor effluents (DFEs) improved the overall efficiency of hydrogen production. The initial acetate concentration in the DFE needed to be adjusted to 30–40 mM by dilution to increase the yield of hydrogen in batch light-supported fermentations. The thermophilic DFEs are suitable for photofermentative hydrogen production, provided that they are supplemented with buffer and nutrients. The overall hydrogen yield of the two-step fermentations was higher than the yield of single step dark fermentations.     

Non-thermal production of pure hydrogen from biomass: HYVOLUTION

The objectives and methodology of the EU-funded research project HYVOLUTION devoted to hydrogen production from biomass are reviewed.The main scientific objective of this project is the development of a novel two-stage bioprocess employing thermophilic and phototrophic bacteria, for the cost-effective production of pure hydrogen from multiple biomass feedstocks in small-scale, cost-effective industries. Results are summarised of the work on pretreatment technologies for optimal biodegradation of energy crops and bio-residues, conditions for maximum efficiency in conversion of fermentable biomass to hydrogen and CO₂, concepts of dedicated installations for optimal gas cleaning and gas quality protocols, as well as innovative system integration aimed at minimizing energy demand and maximizing product output.The main technological objective is the construction of prototype modules of the plant which, when assembled, form the basis of a blueprint for the whole chain for converting biomass to pure hydrogen. A brief outline is presented of the progress made towards developing reactors for thermophilic hydrogen production, reactors for photoheterotrophic hydrogen production and equipment for optimal gas cleaning procedures.     

Hydrogen for a sustainable global economy

The topic of this special issue of the Journal of Cleaner Production is “Sustainable Hydrogen from Biomass.” It is of interest to practitioners in the energy sector, governmental policy makers, researchers, educators, as well as to the general public. The purpose of this special issue is to increase public awareness and to stimulate exchange of information among actors expected to play important roles in making hydrogen available for the sustainable energy system of the future.Hydrogen as a biofuel, that is, hydrogen produced from biomass in a sustainable way is recognised as an important component of the fuel market for the future low or non-carbon based energy systems. In this special issue, the main focus is on hydrogen produced from vegetable biomass by fermentation. The development of a two-stage bioprocess for the cost-effective and environmentally friendly production of pure hydrogen from multiple biomass feedstocks is elucidated by a collection of papers presenting preliminary results of Integrated Research Project HYVOLUTION supported by the 6th Framework Programme of the European Union. The attention is turned to:- the over-all concept and characteristics of the two-stage hydrogen fermentation process,- key technological issues of fermentative hydrogen production,- the availability of vegetable feedstocks including agricultural byproducts that suitable for fermentative processing,- prospects of societal integration and sustainability of the fermentative hydrogen production technology.Other papers included in this special issue are devoted to:- simultaneous production of hydrogen and methane by fermentation of lactose-containing feedstocks derived from byproducts of milk processing,- hydrogen gas generation from organic material by electrohydrogenesis, that is, a bioelectrochemical process performed in reactors known as a microbial electrolysis cells,- the ideas for Europe-wide effort on education of hydrogen users and training of skilled staff needed for facilitating the transition to the future hydrogen economy.     

“They give you lots of information,but ignore what it's really about”: residents' experiences with the planned introduction of a new high-voltage power line

Cases of strong local opposition to the planned introduction of new high-voltage power lines (HVPLs) have been documented in the past. During and after the planning process for a new HVPL, local residents will be informed about the siting process and its outcomes. Although it has been suggested in the literature that this communication plays an important role in residents' responses to a new HVPL, it has been rarely empirically studied. In this qualitative study, we conducted in-depth interviews with 15 residents about their experiences with the planned introduction of a new HVPL near their homes. Thematic analysis revealed that residents' experiences were centred around negative expectations of living near the new HVPL and perceived injustice of the planning process and its outcomes. Residents' perception that communication was not tailored to their information needs played a significant role in these negative experiences. Suggestions for improving communication will be discussed.     

Prospects of utilization of sugar beet carbohydrates for biological hydrogen production in the EU

Hydrogen can be produced through dark anaerobic fermentation using carbohydrate-rich biomass, and through photofermentation using the organic acids produced from dark fermentation. Sugar beet is an ideal energy crop for fermentative production of hydrogen in the EU due to its environmental profile and its potential availability in the area. In this work, various aspects of cultivating sugar beet in the EU for biohydrogen were highlighted, with special focus on The Netherlands and Greece. Moreover, fermentation of sugar beet juice with Caldicellulosiruptor saccharolyticus at sucrose concentration 10 g/l was performed, and was found comparable to the fermentation on pure sucrose except that the hydrogen production was 10% higher on sugar beet juice. A conservative estimate of the annual hydrogen potential in the EU was made (300 × 10⁶ kg hydrogen), considering the utilization of sugar beet pulp in hydrogen production.