The selenium content of Welsh soils with special reference to bedrock and contamination from sulphide ores

This paper describes a survey of total selenium contents of surface soil samples in Wales. Samples were collected from three areas: over Silurian shales where deficiences in sheep have been reported, in an area severely affected by pollution from lead mining and in an area where black, marine shales outcrop. Selenium levels were low over the Silurian shales but high in the other two areas. Statistical analysis of the data permitted the separating out of a basal range of selenium values low enough to account for the reports of deficiences in sheep. Some selenium values were high enough to suggest the possibility of selenosis in sheep.     

Soil and plant concentrations of cadmium and zinc in the vicinity of a smelter

Cadmium, zinc and lead concentrations in soils and plants near a smelter at Avonmouth are reported for samples collected in May 1979 and in May 1980. The total metal soil concentrations fall as distance from the smelter increases and decrease rapidly with depth for cadmium and zinc. The concentrations of these two metals are highly correlated at all depths. Near the smelter, where the carbon content and pH values of the soils are lowest, almost all the cadmium, as measured by EDTA extraction, is available. Concentration of metals in plants also decrease with distance from the smelter, with concentrations being lower in samples collected in 1980. This is possibly due to a seasonal variation in biomass, producing a dilution effect. We conclude that uptake of cadmium and that of zinc by grass species have different relationships to the carbon content of the soil.     

Plants that accumulate metals (Part VI): Further studies of an Australian nickel accumulating plant

Analyses for nickel, copper, cobalt and zinc of some leaf, stem and root samples ofHybanthus floribundus from the Eastern Goldfields area of Western Australia is reported. All four metals appear to behave differently. Nickel is taken into the roots, but accumulates in the tops. Copper is largely excluded, but is evenly distributed at low levels. Cobalt is taken up to a greater extent than copper and is evenly distributed. Zinc is accumulated in the roots and is largely excluded from the tops. Plant-soil metal concentrations are discussed. Extraction studies show that nickel in the leaves, and to a lesser extent in woody parts, is associated with pectic carbohydrates. Accumulation and selectivity of uptake are discussed.     

Silver concentrations in Welsh soils and their dispersal from derelict mine sites

In west and north Wales silver was mined extensively between 1750 and 1900, where it was frequently present as its sulphide form, argentite, whilst also occurring as a guest element in galena and sphalerite. Determination of the silver content of a range of soil types from areas devoid of mines by flameless atomic absorption spectrometry established normal background levels. Soils derived from black shales, or rich in organic matter were inherently richer in silver than the sandstone or limestone derived soils examined. Soils once exposed to contamination from the mining activities of the 19th Century can still be identified as they show elevated levels of silver. Fluvially derived contamination is confined to valley floodplains, but aerial transportation of mine spoil wastes enhance metal levels around derelict mine sites. Spoil analysed from areas of different geology contained a range of silver values reflecting variations in ore type, grain size and technique of ore extraction.