Insights into aqueous carbofuran removal by modified and non-modified rice husk biochars

Biochar has been considered as a potential sorbent for removal of frequently detected pesticides in water. In the present study, modified and non-modified rice husk biochars were used for aqueous carbofuran removal. Rice husk biochars were produced at 300, 500, and 700 °C in slow pyrolysis and further exposed to steam activation. Biochars were physicochemically characterized using proximate, ultimate, FTIR methods and used to examine equilibrium and dynamic adsorption of carbofuran. Increasing pyrolysis temperature led to a decrease of biochar yield and increase of porosity, surface area, and adsorption capacities which were further enhanced by steam activation. Carbofuran adsorption was pH-dependant, and the maximum (161 mg g^?1) occurred in the vicinity of pH 5, on steam-activated biochar produced at 700 °C. Freundlich model best fitted the sorption equilibrium data. Both chemisorption and physisorption interactions on heterogeneous adsorbent surface may involve in carbofuran adsorption. Langmuir kinetics could be applied to describe carbofuran adsorption in a fixed bed. A higher carbofuran volume was treated in a column bed by a steam-activated biochar versus non-activated biochars. Overall, steam-activated rice husk biochar can be highlighted as a promising low-cost sustainable material for aqueous carbofuran removal.     

Efficacy of woody biomass and biochar for alleviating heavy metal bioavailability in serpentine soil

Crops grown in metal-rich serpentine soils are vulnerable to phytotoxicity. In this study, Gliricidia sepium (Jacq.) biomass and woody biochar were examined as amendments on heavy metal immobilization in a serpentine soil. Woody biochar was produced by slow pyrolysis of Gliricidia sepium (Jacq.) biomass at 300 and 500 °C. A pot experiment was conducted for 6 weeks with tomato (Lycopersicon esculentum L.) at biochar application rates of 0, 22, 55 and 110 t ha^?1. The CaCl₂ and sequential extractions were adopted to assess metal bioavailability and fractionation. Six weeks after germination, plants cultivated on the control could not survive, while all the plants were grown normally on the soils amended with biochars. The most effective treatment for metal immobilization was BC500-110 as indicated by the immobilization efficiencies for Ni, Mn and Cr that were 68, 92 and 42 %, respectively, compared to the control. Biochar produced at 500 °C and at high application rates immobilized heavy metals significantly. Improvements in plant growth in biochar-amended soil were related to decreasing in metal toxicity as a consequence of metal immobilization through strong sorption due to high surface area and functional groups.     

Water security: Old concepts,new package,what value?

“Water security” has come to infiltrate prominent discourse in the international water and development community, and achieving it is often viewed as a new water sector target. Despite the elevated status that the concept has increasingly acquired, understandings of the term are murky and quantification is rare. To promote a more tangible understanding of the concept, this paper develops an index for evaluating water security at a country level. The index is comprised of indicators in five components considered to be critical to the concept: (i) basic needs; (ii) agricultural production; (iii) the environment; (iv) risk management; and (v) independence. Achieving water security in these components can be considered necessary but insufficient criteria to measure the achievement of security in related areas such as health, livelihoods, and industry. After populating indicators with data from Asia‐Pacific countries, results are interpreted and the viability of methods is discussed. This effort comprises an important first step for quantifying and assessing water security across countries, which should spur more concrete understanding of the term and discussion of its added value.     

Application of remote sensing techniques toward the role of traditional water bodies with respect to vegetation conditions

Sri Lanka being an agrarian country, the role of water is important for agricultural production. In Sri Lanka, various tank cascade systems, earthen dams and distribution canals have been accepted as few of the most complex ancient traditional water systems of the world. Rainfall, surface water, groundwater and runoff are linked with each other, they have close interactions to land cover classes such as forests and agriculture. The monitoring of vegetation conditions can show subsurface manifestations of groundwater. In this study, an effort to understand the role of traditional water reservoirs and groundwater recharge was made using remote sensing techniques. We have analyzed various vegetation indices such as Normalized Difference Vegetation Index (NDVI), Enhanced Vegetation Index (EVI-2), Soil-Adjusted Vegetation Index (SAVI), tasselled cap transformation analysis (TCA brightness, greenness and wetness) and their relations with the existence of soil, vegetation and water. Result shows that EVI, SAVI, and TCA-based Greenness Index indicates good relationship with the vegetation conditions as compared to other indices. Therefore, these indices could play a crucial role in depicting the interaction between soil, vegetation, and water. However, multi-temporal observations can provide significant results about these interactions more accurately.     

Chronic renal failure among farm families in cascade irrigation systems in Sri Lanka associated with elevated dietary cadmium levels in rice and freshwater fish (Tilapia)

Chronic renal failure (CRF), in the main agricultural region under reservoir based cascade irrigation in Sri Lanka has reached crisis proportion. Over 5,000 patients in the region are under treatment for CRF. The objective of this study is to establish the etiology of the CRF. Concentrations of nine heavy metals were determined in sediments, soils of reservoir peripheries, water and Nelumbo nucifera (lotus) grown in five major reservoirs that supply irrigation water. All five reservoirs carried higher levels of dissolved cadmium (Cd), iron (Fe) and lead (Pb). Dissolved Cd in reservoir water ranged from 0.03 to 0.06 mg/l. Sediment Cd concentration was 1.78-2.45 mg/kg. No arsenic (As) was detected. Cd content in lotus rhizomes was 253.82 mg/kg. The Provisional Tolerable Weekly Intake (PTWI) of Cd based on extreme exposure of rice is 8.702-15.927 mug/kg body weight (BW) for different age groups, 5-50 years. The PTWI of Cd due to extreme exposure of fish is 6.773-12.469 mug/kg BW. The PTWI on a rice staple with fish is 15.475-28.396 mug/kg BW. The mean urinary cadmium (UCd) concentration in CRF patients of age group 40-60 years was 7.58 mug Cd/g creatinine and in asymptomatic persons UCd was 11.62 mug Cd/g creatinine, indicating a chronic exposure to Cd. The possible source of Cd in reservoir sediments and water is Cd-contaminated agrochemicals. The CRF prevalent in north central Sri Lanka is a result of chronic dietary intake of Cd, supported by high natural levels of fluoride in drinking water, coupled with neglecting of routine de-silting of reservoirs for the past 20 years.     

Changing the planting date as a climate change adaptation strategy for rice production in Kurunegala district, Sri Lanka

The effect of changing the planting date on the dry season rice yield was simulated by using the software Decision Support System for Agrotechnology Transfer (DSSAT 4.5) for four rice varieties grown in Kurunegala district, Sri Lanka under expected climate change. Daily weather data up to the year 2090 were downscaled to the district from Global Climate Model outputs under the emission scenarios A2 and B2 published by the Intergovernmental Panel on Climate Change using the Statistical Downscaling Model (SDSM 4.2). The DSSAT model was applied to simulate future rice yields from four rice varieties grown in the district under three different planting dates: (1) planting in May—the base condition; (2) advancing the planting date by 1 month, i.e., to June; and (3) planting 1 month earlier, i.e., in April. Results show that the seasonally averaged dry season rice yield would increase compared to the base condition when the planting date is advanced by 1 month and, on the other hand, the seasonally averaged rice yield would decrease compared to the base condition when the planting date is delayed by 1 month for all four varieties under both A2 and B2 scenarios. Advancing the rice planting date by 1 month for all four rice varieties can be identified as a non-cost climate change adaptation strategy for rice production in Kurunegala district.     

Effects of carbon nanotube and biochar on bioavailability of Pb,Cu and Sb in multi-metal contaminated soil

This study examined the effects of carbon nanotube and biochar on the bioavailability of Pb, Cu and Sb in the shooting range soils for developing low-cost remediation technology. Commercially available multi-walled carbon nanotube (MWCNT) and biochar pyrolyzed from soybean stover at 300 °C (BC) at 0.5, 1 and 2.5% (w w^?1) were used to remediate the contaminated soil in an incubation experiment. Both DTPA (bioavailable) and TCLP (leaching) extraction procedures were used to compare the metal/loid availability and leaching by the amendments in soil. The addition of BC was more effective in immobilizing mobile Pb and Cu in the soil than that in MWCNT. The BC reduced the concentrations of Pb and Cu in the soil by 17.6 and 16.2%, respectively. However, both MWCNTs and BC increased Sb bioavailability by 1.4-fold and 1.6-fold, respectively, in DTPA extraction, compared to the control. The toxicity characteristic leaching procedure (TCLP) test showed that the leachability of Pb in the soil amended with 2.5% MWCNT was 1.3-fold higher than that the unamended soil, whereas the BC at 2.5% decreased the TCLP-extractable Pb by 19.2%. Precipitation and adsorption via electrostatic and π–π electron donor–acceptor interactions were postulated to be involved in the interactions of Pb and Cu with surfaces of the BC in the amended soils, whereas ion exchange mechanisms might be involved in the immobilization of Cu in the MWCNT-amended soils. The application of BC derived from soybean stover can be a low-cost technology for simultaneously immobilizing bioavailable Pb and Cu in the shooting range soils; however, neither of amendments was effective in Sb immobilization.     

Developed fungal–bacterial biofilms as a novel tool for bioremoval of hexavelant chromium from wastewater

Remediation measures for hexavalent chromium [Cr(VI)] are required for a safe environment. As a recent development in microbiology, bacterial biofilms are being studied as effective bioremediation agents. When bacteria are in fungal surface-attached biofilm mode, they are called fungal–bacterial biofilms (FBBs). They have not been tested for bioremediation so far. Hence, this study was conducted to develop FBBs and glass-wool-attached bacterial biofilms (BBs), and to evaluate Cr(VI) tolerability and removal of bacterial monocultures, BBs and FBBs. FBBs showed a significantly high level of Cr(VI) tolerance and resistance compared with its BBs or monocultures. After 10 days, up to 90% of Cr(VI) had been removed, which was significantly higher than that of BBs or its monocultures. Thus, it is clear that FBBs can be used as a novel tool to decontaminate Cr(VI) both in situ and ex situ.     

Incorporating community objectives in improved wetland management: the use of the analytic hierarchy process

Wetlands in Australia provide considerable ecological, economic, environmental and social benefits. However, the use of wetlands has been indiscriminate and significant damage to many Australian wetlands has occurred. During the last 150 years one third of the wetlands in Victoria have been lost. A conspicuous problem in wetland management is the paucity of involvement by stakeholders. This paper uses the Analytic Hierarchy Process (AHP) to incorporate stakeholder objectives in the 'Wonga Wetlands' on the Murray River. The study shows that the AHP can explicitly incorporate stakeholder preferences and multiple objectives to evaluate management options. The AHP also provides several approaches for policy makers to arrive at policy decisions.     

Correction to: Effects of carbon nanotube and biochar on bioavailability of Pb,Cu and Sb in multi-metal contaminated soil

Environmental Geochemistry and Health - Unfortunately, in the original publication of the article, Prof. Yong Sik Ok’s affiliation was incorrectly published. The author’s affiliation is...