History of titanium dioxide regulation as a food additive: a review

Environmental Chemistry Letters - Since its discovery in the late eighteenth century and mass production in the early twentieth century, titanium dioxide has been used in a wide range of...     

Quantitative,chemical, and mineralogical characterization of flue gas desulfurization by-products

The objective of this study was to demonstrate that simple fractionation and selective dissolution techniques can be used to provide detailed chemical and mineralogical analyses of flue gas desulfurization by-products. The material studied was a mine grout prepared as a 1:1 mixture (wt./wt.) of fly ash (FA) and filter cake (FC) with hydrated lime (50 g kg(-1)) added to improve handling. The hydrated lime was composed mostly of calcite (CaCO3), portlandite [Ca(OH)2], lime (CaO), and brucite [Mg(OH)2] (515, 321, 55, and 35 g kg(-1), respectively) and had low (<6 g kg(-1)) concentrations of most trace elements. The FC contained hannebachite (CaSO3 x 0.5H2O) (786 g kg(-1)) with smaller quantities (<10 g kg(-1)) of calcite, quartz (SiO2), brucite, and gypsum (CaSO4 x 2H2O). Except for B and Cu, trace element concentrations were comparable to those in the hydrated lime. The FA contained both magnetic (222 g kg(-1)) and nonmagnetic (778 g kg(-1)) fractions. The former was composed mostly of hematite (Fe2O3), magnetite (Fe3O4), and glass (272, 293, and 287 g kg(-1), respectively), whereas the latter was enriched in glass, quartz, and mullite (Al6Si2O13) (515, 243, and 140 g kg(-1), respectively). Etching with 1% HF showed that 60 to 100% of trace elements were concentrated in the glass, although some metals (Co, Cr, and Mn) were clearly enriched in the magnetic phase. The aged grout contained 147 g kg(-1) ettringite [Ca6Al2(SO4)3(OH)12 x 26H2O] in addition to 314 g kg(-1) hannebachite and 537 g kg(-1) insoluble phases (mullite, quartz, hematite, magnetite, and glass).     

Climate change impacts on European agriculture revisited: adding the economic dimension of grasslands

Forage and more widely grassland systems are difficult to analyze in economic terms because a large proportion of what is produced is not marketed. Economic misestimation of these farm products may dramatically alter projected climate change impacts. This study estimates the economic value of grass and assesses the impact of climatic variations on grassland–livestock systems by taking various environmental and climatic factors into account. Accordingly, grass yield responses to nitrogen inputs (N-yield functions) have been simulated using the grassland biogeochemical PaSim model and then fed into the economic farm-type supply AROPAj model. We developed a computational method to estimate shadow prices of grass production, allowing us to better estimate the effects of climatic variability on grassland and crop systems. This approach has been used on a European scale under two Intergovernmental Panel on Climate Change climate scenarios (AR4 A2 and B1). Results show a significant change in land use over time. Accordingly, due to decreases in feed expenses, farmers may increase livestock, thereby increasing overall greenhouse gas emissions for all scenarios considered. As part of autonomous adaptation by farming systems, N-yield functions extending to pastures and fodders allow us to improve the model and to refine results when marketed and non-marketed crops are considered in a balanced way.