Carbonaceous resin capsule for vapor-phase monitoring of volatile hydrocarbons in soil: partitioning and kinetic model verification

The resin capsule system (RCS) was tested as a means of providing data on the presence and forms of volatile hydrocarbons. Results indicated that resin capsules provided data showing sensitivity to soil variables (texture and moisture content) and time. The objectives of this paper are to evaluate the RCS methodology and to determine whether carbonaceous resin capsules provide results that can be described by fundamental chemical partitioning and kinetic principles. Findings revealed a significant relationship between quantities of benzene, toluene, ethylbenzene, and xylene adsorbed on the capsule and quantities partitioned into the vapor phase. Kinetic evaluation indicated that the vapor adsorption by the resin capsule is regulated by diffusion processes. No verification of rate-limiting processes was possible due to limitations imposed by the experimental design, but it appears that during early stages, adsorption rate was limited by vapor diffusion through the soil. The resin capsule data also reflected differences that would be expected due to properties of the organic liquids present. These results provide further evidence that the RCS could be developed to suggest direct in situ monitoring to reveal quantities and nature of organic substances in soils.     

Gini coefficient to assess equity in domestic water supply in the Yellow River

Yellow River, is designated as “the cradle of Chinese civilization” and played a key role not only in the country’s economic development but also in the historic and cultural identity of the Chinese people. With the rapid economic development and population growth, water demand for industry and households has increased significantly in the Yellow River basin; this has caused an increasing gap between water supply and demand. Competing water demands triggered conflicts between disparate water users on different scales such as the rich and the poor, or between different sectors and regions, such as domestic and agriculture, agriculture and industry, upstream and downstream, rural and urban areas, etc. Ensuring equity in water supply for conflicting water users is one of the major challenges that facing water managers and in particular water management in the Yellow River basin. In this paper, a method has been developed to calculate the Gini coefficient of water use as an indicator to measure the equality in domestic water supply. A dual domestic water use structure model is employed for this purpose. The developed method is subsequently applied to assess the equality in domestic water supply in the Yellow River. Data of population growth, domestic water use and economic development over the time period 1999-2006 are used to calculate the Gini coefficient of water use over the same length of period. The result shows a decreasing trend in Gini coefficient of domestic water use in the Yellow River basin after 2001 which means domestic water use is becoming more and more equitable in the basin. The study justifies that the Gini coefficient of water use can be used and recommended as a useful tool for the water management especially in the context of global change.     

Chemically modified biochar produced from conocarpus waste increases NO<Subscript>3</Subscript> removal from aqueous solutions

Biochar has emerged as a universal sorbent for the removal of contaminants from water and soil. However, its efficiency is lower than that of commercially available sorbents. Engineering biochar by chemical modification may improve its sorption efficiency. In this study, conocarpus green waste was chemically modified with magnesium and iron oxides and then subjected to thermal pyrolysis to produce biochar. These chemically modified biochars were tested for NO₃ removal efficiency from aqueous solutions in batch sorption isothermal and kinetic experiments. The results revealed that MgO-biochar outperformed other biochars with a maximum NO₃ sorption capacity of 45.36 mmol kg^?1 predicted by the Langmuir sorption model. The kinetics data were well described by the Type 1 pseudo-second-order model, indicating chemisorption as the dominating mechanism of NO₃ sorption onto biochars. Greater efficiency of MgO-biochar was related to its high specific surface area (391.8 m² g^?1) and formation of strong ionic complexes with NO₃. At an initial pH of 2, more than 89 % NO₃ removal efficiency was observed for all of the biochars. We conclude that chemical modification can alter the surface chemistry of biochar, thereby leading to enhanced sorption capacity compared with simple biochar.     

THE POTENTIAL FOR REMOTE SENSING OF LOESS SOILS SUSPENDED IN SURFACE WATERS1

ABSTRACT: The potential for detecting the concentration and type of soils suspended in surface water through remote sensing techniques was investigated by studying the spectral reflectance of two types of soils in suspension. In a large tank filled with 7510 liters of water, 20 levels of suspended sediment (soil) concentration (SSC), ranging from 50 to 1000 mg/l were prepared. A high resolution spectroradiometer was used to measure the reflectance at each SSC level. The reflectance spectra of two contrasting soils were distinct in the visible and near infrared (NIR) portions of the electromagnetic spectrum. The wavelength range between 580–690 nm (visible) was found to be optimal for indicating the type of soil, whereas, the wavelength range between 714–880 (NIR) was found to be appropriate for estimating the concentration of sediment suspended in surface waters.     

Water resources management strategy for adaptation to droughts in China

Water Scarcity and drought are recurrent phenomena in China. In the context of environmental change, an increasing tendency in drought frequency and severity is observed in China in recent years. Therefore, it is imperative to take necessary initiatives to reduce the impacts of drought. In this paper, an attempt is made to identify the best water management strategies to cope with droughts. For this objective the records of historical droughts and their impacts in China over the period of 1950?C2009 are analyzed. It is observed that the drought affected area has increased nearly by 12 folds and the drought damaged area has increased by about 22 times in China in last 60?years. Over 87,000 reservoirs were built with a total water storage capacity of about 7,064 billion m³ to cope with droughts. However, this structural supply-based management strategy was not enough to meet the increasing water demand caused by rapid economic development and population growth. A typical relationship between socio-economic development and water resources management strategy to attain sustainability in water management is developed in this study. The relationship shows that the demand-side water management strategies can be the best option to meet the challenges posed by increased severity of drought, population growth, economic development and possible climate change. The concept is later verified through the analysis of changing pattern of water consumptions by different sectors in last 60?years.     

Correction to: Contrasting effects of engineered carbon nanotubes on plants: a review

Environmental Geochemistry and Health - Unfortunately, in the original publication of the article, Prof. Yong Sik Ok’s affiliation was incorrectly published. The author’s affiliation is...     

Impact of climate change on regional irrigation water demand in Baojixia irrigation district of China

Water scarcity in China would possibly be aggravated by rapid increase in water demand for irrigation due to climate change. This paper focuses on the mechanism of climate change impact on regional irrigation water demand by considering the dynamic feedback relationships among climate change, irrigation water demand and adaptation measures. The model in implemented using system dynamics approach and employed in Baojixia irrigation district located in Shaanxi Province of China to analyses the changes in irrigation water demand under different climate change scenarios. Obtained results revealed that temperature will be the dominant factor to determine irrigation water demand in the area. An increase of temperature by 1 °C will result in net irrigation water demand to increase by about 12,050?×?10⁴ m³ and gross water demand by about 20,080?×?10⁴ m³ in the area. However, irrigation water demand will not increase at the same rate of temperature rise as the adaptation measures will eventually reduce the water demand increased by temperature rise. It is expected that the modeling approach presented in this study can be used in adopting policy responses to reduce climate change impacts on water resources.     

Environmental flows and its evaluation of restoration effect based on LEDESS model in Yellow River Delta wetlands

Due to freshwater supplement scarcity and heavy human activities, the fresh water wetland ecosystem in Yellow River Delta is facing disintegrated deterioration, and it is seriously affecting the health of the Yellow River ecosystem. This paper identifies the restoration objectives of wetland aiming to protect ecological and economic values and development as well as the water resources of the Yellow River. The hydraulic and groundwater coupling model and Landscape Ecological Decision and Evaluation Support System (LEDESS) of the Yellow River Delta were established to calculate environmental flows of degraded wetlands. LEDESS is a computer-based model developed and used to assess and evaluate the effects of land-use changes on nature. In this study, LEDESS is used to assess and evaluate the ecological effects and the restoration possibilities considering several environmental flows’ supplement scenarios. This included the changes of suitable habitat conditions and its ecological carrying capacities for indicator species, e.g., Red-crowned crane (Grus japonensis), Oriental stork (Ciconia boyciana), and Saunder’s gull (Larus relictus), and changing of ecological patterns. The results showed that replenishing fresh water to wetlands is one of the effective adaptive measures to mitigate wetland degradation and improve its habitat quality and carrying capacities. This study indicated that landscape ecology approach is not only considered as a good way to solve complex problems in ecosystem management but also can be used to decide on the environmental flows and assess its ecological effects in large-scale wetland rehabilitation. This integrated method could make environmental flows estimated and assessment more rational than the results of hydrologic methods. It could assist decision makers to “see” the ecological effects after water supplementing and so alleviate the contradictions between environmental flows and production water demands, and can facilitate the implementation of environmental flows in most countries with water resources shortage.     

Plants growing in a mining area: screening for metal accumulator plants possibly useful for bioremediation

A field study was conducted in an iron mine in Hamedan (Iran) to find native accumulator plants and to evaluate the extent of metal bioaccumulation in the naturally growing vegetation. The concentrations of total As, Cd, Cr, Fe, Mn, Mo, Ni, Pb, Si, and Zn were found to be higher in the mine than in soil. These plants accumulated the highest amounts of the following metals in their roots: Euphorbia cheiradenia As, Stipa barbata Cd, Pb and Cr, Euphorbia macroclada Cu, Centaurea iberica Fe, Reseda lutea Mo, Salvia spinosa Ni and Zn, and Xanthium strumarium Se. In the aerial parts, the highest metal accumulation was found in Epilobium fragilis As, Carthamus oxyacantha Cd, Fe, Mn, and Pb, Verbascum speciosum Cu, Centaurea iberica Mo, Salvia spinosa Ni and Cr, Glaucium grandiflorum Se, and Malva neglecta Zn. Enrichment factors and bioconcentration factors were also determined; C. oxyacantha, S. spinosa, M. neglecta, C. iberica, V. speciosum, G. grandiflorum, and E. fragilis are the most effective accumulators and are proposed for phytoremediation of polluted soils.     

Contrasting effects of engineered carbon nanotubes on plants: a review

Rapid surge of interest for carbon nanotube (CNT) in the last decade has made it an imperative member of nanomaterial family. Because of the distinctive physicochemical properties, CNTs are widely used in a number of scientific applications including plant sciences. This review mainly describes the role of CNT in plant sciences. Contradictory effects of CNT on plants physiology are reported. CNT can act as plant growth inducer causing enhanced plant dry biomass and root/shoot lengths. At the same time, CNT can cause negative effects on plants by forming reactive oxygen species in plant tissues, consequently leading to cell death. Enhanced seed germination with CNT is related to the water uptake process. CNT can be positioned as micro-tubes inside the plant body to enhance the water uptake efficiency. Due to its ability to act as a slow-release fertilizer and plant growth promoter, CNT is transpiring as a novel nano-carbon fertilizer in the field of agricultural sciences. On the other hand, accumulation of CNT in soil can cause deleterious effects on soil microbial diversity, composition and population. It can further modify the balance between plant-toxic metals in soil, thereby enhancing the translocation of heavy metal(loids) into the plant system. The research gaps that need careful attention have been identified in this review.