Assessing groundwater quality and its sustainability in Joypurhat district of Bangladesh using GIS and multivariate statistical approaches

Sustainable groundwater quality is a key global concern and has become a major issue of disquiets in most parts of the world including Bangladesh. Hence, the assessment of groundwater quality is an important study to ensure its sustainability for various uses. In this study, a combination of multivariate statistics, geographical information system (GIS) and geochemical approaches was employed to evaluate the groundwater quality and its sustainability in Joypurhat district of Bangladesh. The results showed that the groundwater samples are mainly Ca–Mg–HCO₃ type. Principal component analysis (PCA) results revealed that geogenic sources (rock weathering and cation exchange) followed by anthropogenic activities (domestic sewage and agro-chemicals) were the major factors governing the groundwater quality of the study area. Furthermore, the results of PCA are validated using the cluster analysis and correlation matrix analysis. Based on the groundwater quality index (GWQI), it is found that all the groundwater samples belong to excellent to good water quality domains for human consumption, although iron, fluoride and iodide contaminated to the groundwater, which do not pose any significant health hazard according to World Health Organization’s and Bangladesh’s guideline values. The results of irrigation water quality index including sodium adsorption ratio (SAR), permeability index and sodium percentage (Na %) suggested that most of the groundwater samples are good quality water for agricultural uses. The spatial distribution of the measured values of GWQI, SAR, Fe (iron), EC (electrical conductivity) and TH (total hardness) were spatially mapped using the GIS tool in the study area.     

Contamination of soil and the medicinal plant <Emphasis Type="Italic">Phyllanthus niruri</Emphasis> Linn. with cadmium in ceramic industrial areas

Phyllanthus niruri is a plant that is used to prevent calcium oxalate crystallisation and to block the stone formation in urolithiasis. Contaminants in the environment can be readily taken up by medicinal plants due to their ability to absorb chemicals into their tissues. If contaminated plants are ingested, they have the potential to negatively affect human and environmental health. The aim of this study was to assess contamination in the soil and the medicinal plant P. niruri by cadmium (Cd) in ceramic industrial areas of Monte Carmelo, Brazil. Soil samples and plant samples (divided in root, shoot and leaves) were collected from a contaminated monitoring site and from a rural area (which was used as a reference site for comparative purposes). The Cd concentrations of the samples were analysed with an atomic absorption spectrometer. P. niruri was found to be sensitive to soil contamination by Cd that was attributed to ceramic industrial emissions. The results revealed that Cd bioaccumulation in the roots and shoots of P. niruri was associated with a significant increase (p?<?0.05) in the concentration of active lignan compounds (phyllanthin and hypophyllanthin) in the leaves. The identification of high concentrations of Cd and active lignan compounds suggests a risk of contamination of the site and the risk of a high dose of Cd to people exposed at the site.     

Treibhausgasemissionen zukünftiger Erdgasbereitstellung für Deutschland

Ohne Zusammenfassung Original erschienen in UWSF – Z Umweltchem ?kotox 20(2):133–144 (2008) DOI: Herausgeber: Martin Pehnt und Eckard Helmers     

Development of a test method against hot alkaline chemical splashes.

High temperature alkaline chemical liquids have caused injuries and hazardous situations in Finnish pulp manufacturing mills. There are no requirements and/or test method standards concerning protection against high temperature alkaline chemical splashes. This paper describes the test method development process to test and identify materials appropriate for hot liquid chemical hazard protection. In the first phase, the liquid was spilled through a stainless steel funnel and the protection performance was evaluated using a polyvinyl chloride (PVC) film under the test material. After several tentative improvements, a graphite crucible was used for heating and spilling the chemical, and a copper-coated K-type thermometer with 4 independent measuring areas was designed to measure the temperature under the material samples. The thermometer was designed to respond quickly so that peak temperatures could be measured. The main problem was to keep the spilled amount of chemical constant, which unfortunately resulted in significant variability in data.     

Soil nitrate nitrogen dynamics after biosolids application in a tobosagrass desert grassland

Dormant-season application of biosolids increases desert grass production more than growing season application in the first growing season after application. Differential patterns of NO3-N (plant available N) release following seasonal biosolids application may explain this response. Experiments were conducted to determine soil nitrate nitrogen dynamics following application of biosolids during two seasons in a tobosagrass [Hilaria mutica (Buckl.) Benth.] Chihuahuan Desert grassland. Biosolids were applied either in the dormant (early April) or growing (early July) season at 0, 18, or 34 dry Mg ha(-1). A polyester-nylon mulch was also applied to serve as a control that approximated the same physical effects on the soil surface as the biosolids but without any chemical effects. Supplemental irrigation was applied to half of the plots. Soil NO3-N was measured at two depths (0-5 and 5-15 cm) underneath biosolids (or mulch) and in interspace positions relative to surface location of biosolids (or mulch). Dormant-season biosolids application significantly increased soil NO3-N during the first growing season, and also increased soil NO3-N throughout the first growing season compared to growing-season biosolids application in a year of higher-than-average spring precipitation. In a year of lower-than-average spring precipitation, season of application did not affect soil NO3-N. Soil NO3-N was higher at both biosolids rates for both seasons of application than in the control treatment. Biosolids increased soil NO3-N compared to the inert mulch. Irrigation did not significantly affect soil NO3-N. Soil NO3-N was not significantly different underneath biosolids and in interspace positions. Surface soil NO3-N was higher during the first year of biosolids application, and subsurface soil NO3-N increased during the second year. Results showed that biosolids rate and season of application affected soil NO3-N measured during the growing season. Under dry spring-normal summer precipitation conditions, season of application did not affect soil NO3-N; in contrast, dormant season application increased soil NO3-N more than growing season application under wet spring-dry summer conditions.     

Effects of calcium hydroxide and calcium chloride addition to bentonite in iron ore pelletization.

Pyrite ash is created as waste from the roasting of pyrite ores during the production of sulphuric acid. These processes generate great amounts of pyrite ash waste that is generally land filled. This creates serious environmental pollution due to the release of acids and toxic substances. Pyrite ash waste can be utilized in the iron production industry as a blast furnace feed to process this waste and prevent environmental pollution. The essential parameters affecting the pelletization process of pyrite ash were studied using bentonite as a binder. Experiments were then carried out using bentonite and a mixture of bentonite with calcium hydroxide and calcium chloride in order to make the bentonite more effective. The metallurgical properties of pyrite ash, bentonite, calcium hydroxide, calcium chloride, a mixture of these and sintered pellets were studied using X-ray analysis. The crushing strength tests were carried out to investigate the strength of pyrite ash waste pellets. The results of these analyses showed that pyrite ash can be agglomerated to pellets and used in the iron production industry as a blast furnace feed. The crushing strength of the pellets containing calcium hydroxide and calcium chloride in addition to bentonite was better than the strength of pellets prepared using only bentonite binder.     

Working backwards to move forwards: Graph-based connectivity metrics for reserve network selection

In this paper we apply graph theory in a reserve selection exercise to explore the tradeoffs between maintaining connectivity and minimizing the total area of a protected area network. Rather than focus on a single organism, we used a multi-species approach and looked at the tradeoff curves for organisms with varying dispersal abilities. We first generated the tradeoff curves using a graph-based metric to determine the importance of individual patches for maintaining connectivity. We then performed an analogous set of analyses using patch size as a surrogate measure of importance.     

A modular approach to Integrated Assessment modeling

In this paper, we present a new approach to model coupling that probably forms the methodological basis of a new generation of Integrated Assessment models. This approach respects the knowledge and expertise that is embodied in existing models and encourages their gradual evolution. Modularity is the guiding principle. Our approach is distinguished by the way modules are coupled which is based on an interplay of a job control module, a numerical coupling module, and a couple of stand-alone functional modules. The numerical coupling module - the core component - serves to treat the feedbacks between the functional modules. A first implemented example that couples an economic and a climate module by means of a two-phase meta-optimization is presented here. The algorithm and mathematical structure behind are discussed as well as important features such as convergence behavior and reliability.