Field dissipation of oxyfluorfen in onion and its dynamics in soil under Indian tropical conditions

Oxyfluorfen, a diphenyl-ether herbicide is being used to control annual and perennial broad-leaved weeds and sedges in a variety of field crops including onion. The present study was aimed to investigate the dynamics and field persistence of oxyfluorfen in onion plant, bulb and soil under Indian tropical conditions. Application of four rates of oxyfluorfen viz., 200, 250, 300 and 400 g AI ha^?1 as pre-emergence gave good weed control in field experiment with onion. The oxyfluorfen residue dissipated faster in plant than in soil respectively, with a mean half-life of 6.1 and 11.2 days. Dissipation followed first-order kinetics. In laboratory column leaching experiments, 17 percent of the applied oxyfluorfen was recovered from the soil and indicates its solubility in water and mobility in sandy clay loam soil was low. A sorption study revealed that the adsorption of oxyfluorfen to the soil was highly influenced by the soil organic carbon with the K_oc value of 5450. The study concludes that the dissipation of oxyfluorfen in soil and onion was dependent on the physico-chemical properties of the soil and environmental conditions.     

Correction to: Impact of precipitation disparity on groundwater fluctuation in a semi-arid region (Vellore district) of southern India using geospatial techniques

Environmental Science and Pollution Research - A Correction to this paper has been published: https://doi.org/10.1007/s11356-021-13406-7     

Impact of precipitation disparity on groundwater fluctuation in a semi-arid region (Vellore district) of southern India using geospatial techniques

Environmental Science and Pollution Research - In the present study, impact of precipitation disparity on groundwater level fluctuation was carried out in Vellore district, Tamil Nadu, India, using...     

Forest policies and programs affecting vulnerability and adaptation to climate change

Due to large scale afforestation programs and forest conservation legislations, India’s total forest area seems to have stabilized or even increased. In spite of such efforts, forest fragmentation and degradation continues, with forests being subject to increased pressure due to anthropogenic factors. Such fragmentation and degradation is leading to the forest cover to change from very dense to moderately dense and open forest and 253 km² of very dense forest has been converted to moderately dense forest, open forest, scrub and non-forest (during 2005–2007). Similarly, there has been a degradation of 4,120 km² of moderately dense forest to open forest, scrub and non-forest resulting in a net loss of 936 km² of moderately dense forest. Additionally, 4,335 km² of open forest have degraded to scrub and non-forest. Coupled with pressure due to anthropogenic factors, climate change is likely to be an added stress on forests. Forest sector programs and policies are major factors that determine the status of forests and potentially resilience to projected impacts of climate change. An attempt is made to review the forest policies and programs and their implications for the status of forests and for vulnerability of forests to projected climate change. The study concludes that forest conservation and development policies and programs need to be oriented to incorporate climate change impacts, vulnerability and adaptation.     

CO<Subscript>2</Subscript>-fertilization and potential future terrestrial carbon uptake in India

There is huge knowledge gap in our understanding of many terrestrial carbon cycle processes. In this paper, we investigate the bounds on terrestrial carbon uptake over India that arises solely due to CO ₂ -fertilization. For this purpose, we use a terrestrial carbon cycle model and consider two extreme scenarios: unlimited CO₂-fertilization is allowed for the terrestrial vegetation with CO₂ concentration level at 735 ppm in one case, and CO₂-fertilization is capped at year 1975 levels for another simulation. Our simulations show that, under equilibrium conditions, modeled carbon stocks in natural potential vegetation increase by 17 Gt-C with unlimited fertilization for CO₂ levels and climate change corresponding to the end of 21st century but they decline by 5.5 Gt-C if fertilization is limited at 1975 levels of CO₂ concentration. The carbon stock changes are dominated by forests. The area covered by natural potential forests increases by about 36% in the unlimited fertilization case but decreases by 15% in the fertilization-capped case. Thus, the assumption regarding CO₂-fertilization has the potential to alter the sign of terrestrial carbon uptake over India. Our model simulations also imply that the maximum potential terrestrial sequestration over India, under equilibrium conditions and best case scenario of unlimited CO₂-fertilization, is only 18% of the 21st century SRES A2 scenarios emissions from India. The limited uptake potential of the natural potential vegetation suggests that reduction of CO₂ emissions and afforestation programs should be top priorities.     

A novel framework to classify marginal land for sustainable biomass feedstock production

To achieve food and energy security, sustainable bioenergy has become an important goal for many countries. The use of marginal lands to produce energy crops is one strategy for achieving this goal, but what is marginal land? Current definitions generally focus on a single criterion, primarily agroeconomic profitability. Herein, we present a framework that incorporates multiple criteria including profitability of current land use, soil health indicators (erosion, flooding, drainage, or high slopes), and environmental degradation resulting from contamination of surface water or groundwater resources. We tested this framework for classifying marginal land in the state of Nebraska and estimated the potential for using marginal land to produce biofuel crops. Our results indicate that approximately 1.6 million ha, or 4 million acres, of land (approximately 8% of total land area) could be classified as marginal on the basis of at least two criteria. Second-generation lignocellulosic bioenergy crops such as switchgrass ( Panicum virgatum L.), miscanthus (Miscanthus giganteus), native prairie grasses, and short-rotation woody crops could be grown on this land in redesigned landscapes that meet energy and environmental needs, without significant impacts on food or feed production. Calculating tradeoffs between the economics of redesigned landscapes and current practices at the field scale is the next step for determining functional designs for integrating biofuel feedstock production into current land management practices.     

Unique phenotypes in the sperm of the earthworm Eudrilus eugeniae for assessing radiation hazards

The earthworm, Eudrilus eugeniae is a segmented worm. It has two pairs of testes whose cells are highly proliferative. It was found that the earthworm, which is irradiated with X-ray, shows the following phenotypic changes in its sperm: fragmented acrosome in the head, break in the tail, and the appearance of zigzag sperm tail. Sperm morphology can be used as a tool to study radiation hazards in local areas. These three phenotypes were not observed in the sperm of worms exposed to different concentration of toxic chemicals such as sodium arsenate, lead acetate, and mercuric chloride. In contrast, exposure of worms to ethidium bromide caused fragmented acrosome in the head of their sperm cells.     

Impact of climate change on Indian forests: a dynamic vegetation modeling approach

We make an assessment of the impact of projected climate change on forest ecosystems in India. This assessment is based on climate projections of the Regional Climate Model of the Hadley Centre (HadRM3) and the dynamic global vegetation model IBIS for A2 and B2 scenarios. According to the model projections, 39% of forest grids are likely to undergo vegetation type change under the A2 scenario and 34% under the B2 scenario by the end of this century. However, in many forest dominant states such as Chattisgarh, Karnataka and Andhra Pradesh up to 73%, 67% and 62% of forested grids are projected to undergo change. Net Primary Productivity (NPP) is projected to increase by 68.8% and 51.2% under the A2 and B2 scenarios, respectively, and soil organic carbon (SOC) by 37.5% for A2 and 30.2% for B2 scenario. Based on the dynamic global vegetation modeling, we present a forest vulnerability index for India which is based on the observed datasets of forest density, forest biodiversity as well as model predicted vegetation type shift estimates for forested grids. The vulnerability index suggests that upper Himalayas, northern and central parts of Western Ghats and parts of central India are most vulnerable to projected impacts of climate change, while Northeastern forests are more resilient. Thus our study points to the need for developing and implementing adaptation strategies to reduce vulnerability of forests to projected climate change.     

Di（2-ethylhexyl）phosphoric acid-coconut oil supported liquid membrane for the separation of copper ions from copper plating wastewater

Permeation of Cu(II) from its aqueous solution through a supported liquid membrane (SLM) containing di(2-ethylhexyl)phosphoric acid (D2EHPA) carrier dissolved in coconut oil has been studied. The effects of Cu(II), pH (in feed), H2SO4 (stripping) and D2EHPA (in membrane) concentrations have been investigated. The stability of the D2EHPA-coconutoil has also been evaluated. High Cu(II) concentration in the feed leads to an increase in flux from 4.1 × 10-9 to 8.9 × 10-9 mol/(m2·s) within the Cu(II) concentration range 7.8×10-4-78.6×10-4 mol/L at pH of 4.0 in the feed and 12.4 × 10-4 mol/L D2EHPA in the membrane phase. Increase in H2SO4 concentration in strip solution leads to an increase in copper ions flux up to 0.25 mol/L H2SO4, providing a maximum flux of 7.4 × 10-9 mol/(m2·s). The optimum conditions for Cu(II) transport are, pH of feed 4.0, 0.25 mol/L H2SO4 in strip phase and 12.4 × 10-4 mol/L D2EHPA (membrane) in 0.5 (m pore size polytetrafluoroethylene (PTFE) membrane. It has been observed that Cu(II) flux across the membrane tends to increase with the concentration of copper ions. Application of the method developed to copper plating bath rinse solutions has been found to be successful in the recovery of Cu(II). rane. It