The influences of renewable electricity generation,technological innovation,financial development,and economic growth on ecological footprints in ASEAN-5 countries

Environmental Science and Pollution Research - The Southeast Asian countries have experienced significant degrees of economic growth over the years but have not managed to safeguard their...     

A hybrid statistical decision-making optimization approach for groundwater vulnerability considering uncertainty

Environmental Science and Pollution Research - Recognizing the vulnerable areas for contamination is a feasible way to protect groundwater resources. The main contribution of the paper is...     

Oil to 2000

Current surplus oil production capacity had its origins in the price increases of the 1970s. Those increases encouraged both energy conservation and the entry of new producers. Recent increases in oil demand reflect the belief among energy users that in real terms in the long term, prices will be stable. There is good reason to believe that this will be so, even at the current rate of increase it will be 15 years before demand matches current capacity. Given that situation it is difficult to see OPEC following any other pricing policy than the one currently in place. In the meantime market prices will further encourage vertical integration.     

Coagulation of highly turbid suspensions using magnesium hydroxide: effects of slow mixing conditions

Laboratory experiments were carried out to study the effects of slow mixing conditions on magnesium hydroxide floc size and strength and to determine the turbidity and total suspended solid (TSS) removal efficiencies during coagulation of highly turbid suspensions. A highly turbid kaolin clay suspension (1,213?±?36 nephelometric turbidity units (NTU)) was alkalized to pH 10.5 using a 5 M NaOH solution; liquid bittern (LB) equivalent to 536 mg/L of Mg²⁺ was added as a coagulant, and the suspension was then subjected to previously optimized fast mixing conditions of 100 rpm and 60 s. Slow mixing speed (20, 30, 40, and 50 rpm) and time (10, 20, and 30 min) were then varied, while the temperature was maintained at 20.7?±?1 °C. The standard practice for coagulation-flocculation jar test ASTM D2035-13 (2013) was followed in all experiments. Relative floc size was monitored using an optical measuring device, photometric dispersion analyzer (PDA 2000). Larger and more shear resistant flocs were obtained at 20 rpm for both 20- and 30-min slow mixing times; however, given the shorter duration for the former, the 20-min slow mixing time was considered to be more energy efficient. For slow mixing camp number (Gt) values in the range of 8,400–90,000, it was found that the mixing speed affected floc size and strength more than the time. Higher-turbidity removal efficiencies were achieved at 20 and 30 rpm, while TSS removal efficiency was higher for the 50-rpm slow mixing speed. Extended slow mixing time of 30 min yielded better turbidity and TSS removal efficiencies at the slower speeds.     

Effects of long-term irrigation with treated wastewater on soil quality,soil-borne pathogens,and living organisms: case study of the vicinity of El Hajeb (Tunisia)

Medium (i.e. 15 years) and long-term (i.e. 20 years) impact of irrigation using secondary-treated municipal wastewater (TWW) was assessed on two agricultural soil samples, denoted by E and G, respectively, in the vicinity of El Hajeb region (Southern Tunisia). Soil pH, electrical conductivity particle size grading, potential risk of salinity, water holding capacity and chemical composition, as well as organic matter content, pathogenic microorganisms and heavy metal concentrations in the TWW-irrigated (E and G) and rainwater-irrigated (T) soils at various depths, were monitored and compared during a 5-year experiment. Our study showed that bacterial abundance is higher in sandy–clayey soil, which has an enhanced ability to retain moisture and nutrients. The high level of bacterial flora in TWW-irrigated soils was significantly (p?<?0.05) correlated (r?=?~0.5) with the high level of OM. Avoidance assays have been used to assess toxic effects generated by hazards in soils. The earthworms gradually avoided the soils from the surface (20 cm) to the depth (60 cm) of the G transect and then the E transect, preferring the T transect. The same behaviour was observed for springtails, but they seem to be less sensitive to the living conditions in transects G and E than the earthworms. The avoidance response test of Eisenia andrei was statistically correlated with soil layers at the sampling sites. However, the avoidance response test of Folsomia candida was positively correlated with silt-clay content (+0.744*) and was negatively correlated with sand content (?0.744*).     

Preliminary on-road measurement of the effect of oxygenated fuel on CO emissions near Las Vegas, Nevada

A preliminary measurement of an oxygenated fuel effect for in-use vehicles travelling at freeway speed was conducted near Las Vegas, NV, in January 1991 and May 1992. The experimental design was based on two principal factors: (1) the large volume of traffic that visits Las Vegas from Southern California on three-day holiday weekends and (2) the fact that, at the time of the study, the Las Vegas area used oxygenated fuels in the winter and Southern California did not. Measurements were conducted at carefully selected sites 20 km southwest of Las Vegas near Sloan, NV, and were accomplished with the Fuel Efficiency Automoblie Test (FEAT) remote sensor developed at the University of Denver. The January 1991 measurements were made during the Las Vegas oxyfuel season, while the May 1992 control measurements were made outside the oxyfuel season. Over 24,500 individual CO concentrations were measured; registration data from over 5,500 of these vehicles were obtained from the license plate numbers. After corrections for differences in velocity and mean age, the Las Vegas outbound (oxyfuel) CO emissions on Monday morning of the January holiday weekend showed a difference of -18% +/- 11% compared to the inbound (non-oxyfuel) CO emissions on Friday evening preceding the holiday weekend.     

Recreational Value of an Oasis in Oman

Increasing demand for water to develop non-agricultural activities is causing water to be diverted to high-value uses at the expense of irrigation. However, agriculture provides a flow of amenities in the desert environment which are not either accounted or paid. Oases are spread all over the globe and are threatened for various reasons among which is the high pressure of demand for fresh water. This paper estimates the recreation use value of an oasis. The paper is based on the Misfat Al-Abryeen oasis in Oman, a man-made area of streams and woodland. The travel cost method is used through an on-site questionnaire distributed to 230 visitors. Around 75% of visitors to the oasis also visited other historical or ecological sites during the same day-trip. The econometric model is estimated using negative binomial regression with endogenous stratification. The average consumer surplus, or benefit, from visiting Misfat Al-Abryeen is estimated at US104.74 per individual per trip. The total social benefit from this oasis is estimated at 104.74 per individual per trip. The total social benefit from this oasis is estimated at 366,590 per year. These results underscore the importance of the role played by irrigated agriculture in the provision of amenity services for the tourism sector in a desert environment. The sustainability of the irrigation activity depends on the recognition of the recreation role of oases and the transfer of part of these benefits to the farmers who maintain the irrigation system. The implementation of an entrance fee to the oasis might increase farmers’ profit by 6–21%.     

Precipitation softening: a pretreatment process for seawater desalination

Reduction of membrane fouling in reverse osmosis systems and elimination of scaling of heat transfer surfaces in thermal plants are a major challenge in the desalination of seawater. Precipitation softening has the potential of eliminating the major fouling and scaling species in seawater desalination plants, thus allowing thermal plants to operate at higher top brine temperatures and membrane plants to operate at a reduced risk of fouling, leading to lower desalinated water costs. This work evaluated the use of precipitation softening as a pretreatment step for seawater desalination. The effectiveness of the process in removing several scale-inducing materials such as calcium, magnesium, silica, and boron was investigated under variable conditions of temperature and pH. The treatment process was also applied to seawater spiked with other known fouling species such as iron and bacteria to determine the efficiency of removal. The results of this work show that precipitation softening at a pH of 11 leads to complete elimination of calcium, silica, and bacteria; to very high removal efficiencies of magnesium and iron (99.6 and 99.2 %, respectively); and to a reasonably good removal efficiency of boron (61 %).     

Iron-impregnated zeolite catalyst for efficient removal of micropollutants at very low concentration from Meurthe river

In this paper, for the first time, faujasite Y zeolite impregnated with iron (III) was employed as a catalyst to remove a real cocktail of micropollutants inside real water samples from the Meurthe river by the means of the heterogeneous photo-Fenton process. The catalyst was prepared by the wet impregnation method using iron (III) nitrate nonahydrate as iron precursor. First, an optimization of the process parameters was conducted using phenol as model macro-pollutant. The hydrogen peroxide concentration, the light wavelength (UV and visible) and intensity, the iron loading immobilized, as well as the pH of the solution were investigated. Complete photo-Fenton degradation of the contaminant was achieved using faujasite containing 20 wt.% of iron, under UV light, and in the presence of 0.007 mol/L of H₂O₂ at pH 5.5. In a second step, the optimized process was used with real water samples from the Meurthe river. Twenty-one micropollutants (endocrine disruptors, pharmaceuticals, personal care products, and perfluorinated compounds) including 17 pharmaceutical compounds were specifically targeted, detected, and quantified. All the initial concentrations remained in the range of nanogram per liter (0.8–88 ng/L). The majority of the micropollutants had a large affinity for the surface of the iron-impregnated faujasite. Our results emphasized the very good efficiency of the photo-Fenton process with a cocktail of a minimum of 21 micropollutants. Except for sulfamethoxazole and PFOA, the concentrations of all the other microcontaminants (bisphenol A, carbamazepine, carbamazepine-10,11-epoxide, clarithromycin, diclofenac, estrone, ibuprofen, ketoprofen, lidocaine, naproxen, PFOS, triclosan, etc.) became lower than the limit of quantification of the LC-MS/MS after 30 min or 6 h of photo-Fenton treatment depending on their initial concentrations. The photo-Fenton degradation of PFOA can be neglected. The photo-Fenton degradation of sulfamethoxazole obeys first-order kinetics in the presence of the cocktail of the other micropollutants.     

Biodiesel synthesis and characterization using welted thistle plant (Carduus acanthoides) as source of new non-edible seed oil

In this work we applied base catalyzed transesterification to convert non-edible welted thistle oil (Carduus acanthoides) as new non-edible feedstock into biodiesel (Fatty acid methyl esters). The highest biodiesel yield of 88% was obtained using optimized reaction conditions of 70°C and 5:1 molar ratio (methanol:oil). The synthesized esters were characterize and confirmed by the application of NMR and FT-IR techniques. Gas chromatography and mass spectroscopy identified different fatty acids as palmatic acid (C16:0), oleic acid (C18:1), linoleic acid (18:2), arachidic acid (C20:0), eicosanic acid (C20:1), and erucic acid (C22:1) in the oil of welted thistle. Six corresponding methyl esters reported in welted thistle oil biodiesel includes 9-hexadecenoic acid, hexadecanoic acid, 9-octadecadienoic acid, 11-eicosanoic acid, eicosanoic acid and 13-docosenoicacid. Fuel properties, such as density @40°C Kg/L (0.8470), kinematic viscosity @ 40°C c St (4.37), flash point (95°C), cloud point (+4°C), pour point (?5°C), and sulfur contents (0.0112% wt) of the biodiesel produced were compatible with American Society for Testing and Materials D 6751 specifications.