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Mehmet Sinan Bilgili Gamze Varank Elif Sekman Selin Top Didem Özçimen Remziye Yazıcı 《Environmental Modeling and Assessment》2012,17(3):289-300
Since phenols and phenolic compounds in many industrial wastewaters are toxic organic contaminants for humans and aquatic
life, to remove these compounds via the most efficient way is very important for environmental remediation treatment. In this
context, almost all of the isotherm models (Freundlich, Langmuir, Temkin, Redlich–Peterson, Sips, and Khan) for adsorption
in the literature were applied to explain the adsorption mechanism of 4-chlorophenol on activated carbon in this study. Also
theoretical modeling data were obtained using model equations; interpolation and analysis of variance were made to compare
data by using statistics software. In addition, the thermodynamic and kinetic studies for adsorption mechanism were included
in the article. The adsorption of 4-chlorophenol on activated carbon fits well to the pseudo-first-order kinetic model than
the pseudo-second-order, intraparticular diffusion and Bangham models. It is also indicated that 4-chlorophenol adsorption
by granular activated carbon would be attributed to a type of transition between physical and chemical adsorption rather than
a pure physical or chemical adsorption process. As a result, an environmental remediation problem and the adsorption mechanism
on activated carbon that can be regarded as a solution to this problem are described and explained using the mathematical
models and calculations in this study. 相似文献
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Spherical TiO2 nanoparticles (npTiO2) were prepared by controlled hydrolysis of tetraethoxy orthotitanate under a nitrogen atmosphere. ZnO nanoparticles (npZnO) were prepared using hydrothermal methods. The crystal structure, chemical, thermal and morphological properties of npZnO and npTiO2 were characterised using Fourier Transform Infrared Spectrometer, enery-dispersive X-ray spectroscopy, X-ray diffraction, and scanning electron microscope techniques. The short- and long-term experiments were started with neonates taken from the same culture and laboratory condition. In the acute experiments, npTiO2, npZnO, and cocktail concentrations were applied. 96h-LC50 values were 1.8, 0.7, and 0.1?mg?L?1, respectively (p?<?.05). For the chronic experiments, different npTiO2 concentrations were performed. 21d-LC50 value was 1.0?mgL?1 (p?<?.05). Morphometry became progressively worse in concentrations of more than 1?mgL?1 npTiO2. Neonate and young individuals were more sensitive to death because of their low tolerance. This result was affected by population progeny and growth rates (p?<?.05). While control and 0.5?mgL?1 npTiO2 groups were determined as growing population, 1.5 and 2?mgL?1 npTiO2 groups had decreased population size as R0 values. Consequently, the relationships between nanoparticle accumulation within Daphnia magna and its population structure and body morphometry for each concentration were important indicators. Its tolerance level to nanoparticles under laboratory conditions reflected its replacement and behaviour in the ecosystem. 相似文献
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Kazar Soydan Didem Turgut Nalan Yalçın Melis Turgut Cafer Karakuş Perihan Binnur Kurt 《Environmental science and pollution research international》2021,28(22):27511-27519
Environmental Science and Pollution Research - Pesticides may cause a potential risk to human health when applied in excess to control pests, diseases, and weeds in crop fields. In the current... 相似文献
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Cem Kesgin Sevil Yücel Didem Özçimen Azade Attar 《International Journal of Green Energy》2016,13(3):328-333
Ultrasonic irradiation is considered an effective way to increase mass transfer between immiscible liquid–liquid phases in a heterogeneous system leading to faster transesterification and higher yield and saving excess methanol and catalyst. In this study, the transesteri?cation of hazelnut oil with methanol and ethanol was performed in the presence of potassium hydroxide or sodium methoxide as a catalyst using two types of ultrasonic irradiation with a probe (20 kHz, 200 W) and a bath (35 kHz, 400 W); a conventional production method was also used. The reaction time, alcohol:oil molar ratio, catalyst type (KOH or NaOCH3), and catalyst amount (wt.% of oil) were studied as experimental parameters. The highest methyl ester conversion was obtained as 98.12% by using ultrasonic probe at a 5:1 methanol:oil molar ratio with KOH 1 wt.% of oil as catalyst in 20-min reaction time at autogenous temperature. The application of ultrasonic irradiation by using a probe decreased the level of energy consumption, showing that this method may be a promising alternative compared with the conventional production method. 相似文献
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Didem Dizdaroglu Tan Yigitcanlar 《Journal of Environmental Planning and Management》2016,59(11):1982-2006
This paper introduces a policy-making support tool called ‘Micro-level Urban-ecosystem Sustainability IndeX (MUSIX)’. The index serves as a sustainability assessment model that monitors six aspects of urban ecosystems – hydrology, ecology, pollution, location, design, and efficiency – based on parcel-scale indicators. This index is applied in a case study investigation in the Gold Coast City, Queensland, Australia. The outcomes reveal that there are major environmental problems caused by increased impervious surfaces from growing urban development in the study area. The findings suggest that increased impervious surfaces are linked to increased surface runoff, car dependency, transport-related pollution, poor public transport accessibility, and unsustainable built environment. This paper presents how the MUSIX outputs can be used to guide policy-making through the evaluation of existing policies. 相似文献
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Kumru Didem Atalay Gülin Feryal Can Ergün Eraslan 《International journal of occupational safety and ergonomics》2018,24(3):373-385
This study aims to define the relationship between risk degrees and risk indexes on different functional structures with the assumption that risk degrees may not always present a linear relationship with the risk indexes. In this way, risk indexes suitable for expert evaluation of working conditions and computed using three different membership functions are determined. Among the membership functions used, one is preferred as linear and the others are preferred as non-linear. Additionally, a new fuzzy risk assessment (RA) algorithm is developed using these three membership functions. With this new fuzzy RA algorithm, a more flexible and precise process becomes available, while information loss during the determination of the risk index of danger sources is prevented. As a result, non-linear increasing membership function is selected as most suitable for the expression of the relationship between risk degrees and risk indexes. 相似文献
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Patterns of epilithic diatom species distribution in relation to environmental variables from 12 sampling sites on the main stream and some of its tributaries in the Nilüfer Stream Basin were determined using multivariate statistical techniques. The stream basin has been heavily influenced by anthropogenic effects. The upper part of the basin that is distant from pollution sources mostly has a spring water quality, while the lower part where the stream flows through the urban area and receives domestic and industrial wastewater has a quite low quality. Ordination techniques using both diatom taxa and 21 environmental variables revealed non- to slightly polluted upper basin sites and highly polluted lower basin sites along the stream. The results showed that the stream catchment is polluted gradually from upstream to downstream and that most of the downstream sites have very low water quality especially in summer months. A total of 134 epilithic diatom taxa belonging to 50 genera were recorded for 12 sample sites. Partial CCA results indicated that water temperature (T), discharge (Q), and total phosphorus (TP) were the most important variables affecting the distribution of diatom species. Unpolluted or slightly polluted upper basin sites were dominated by Achnanthidium minutissimum, Cocconeis placentula var. euglypta, Gomphonema olivaceum, and Navicula tripunctata. Highly polluted lower basin sites were characterized by high levels of organic and inorganic matters and low dissolved oxygen (DO) values. Species widespread in the highly polluted lower basin sites such as Nitzschia umbonata, Nitzschia amphibia, Nitzschia capitellata, Nitzschia palea, Nitzschia paleacea, Luticola mutica, and Stephanodiscus niagarae were mostly related to pollution indicator variables such as ammonium nitrogen (NH4 +–N), sodium (Na+), total phosphorus (TP), and total organic matter (TOM). 相似文献
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Demir Didem Özdemir Sadin Ceylan Seda Yalcin M. Serkan Sakım Burcu Bölgen Nimet 《Journal of Polymers and the Environment》2022,30(6):2462-2473
Journal of Polymers and the Environment - In this study, styrax liquidus (sweet gum balsam) extracted from Liquidambar orientalis Mill. incorporated PCL fibrous scaffolds were prepared using the... 相似文献
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