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Pfendler Stéphane Einhorn Olympe Karimi Battle Bousta Faisl Cailhol Didier Alaoui-Sosse Laurence Alaoui-Sosse Badr Aleya Lotfi 《Environmental science and pollution research international》2017,24(31):24611-24623
Environmental Science and Pollution Research - Ultra-violet C (UV-C) treatment is commonly used in sterilization processes in industry, laboratories, and hospitals, showing its efficacy against... 相似文献
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Stéphane Pfendler Olympe Einhorn Faisl Bousta Abderrahim Khatyr Laurence Alaoui-Sossé Lotfi Aleya Badr Alaoui-Sossé 《Environmental science and pollution research international》2017,24(27):21601-21609
A laboratory investigation of UV-C effects was conducted over a 62-h period: a much higher dose than in classic UV-C treatment was applied to five pigments and two painting binders used by prehistoric humans. Colorimetric parameters were compared to a control to see if UV-C can change pigment and binder color. Infrared spectroscopy, scanning electron microscopy, inductively coupled plasma and X-ray crystallography were also carried out to confirm colorimetric measurement. In order to understand how microorganism may physically deteriorate paintings, limestone blocks were painted and monitored until their complete colonization by algae, cyanobacteria, fungi and/or mosses. The results show that UV-C has no effect on mineral compounds. Conversely, it is noteworthy that binder color changed under both UV-C light conditions as well as in visible light. Concerning painted blocks, a fast proliferation has been observed with deterioration of the paintings. These results show the high importance of treating biofilm as soon as possible. Moreover, these findings may be a promising avenue inducing cave managers to use friendly UV-C light to treat contaminated cave paintings and also in the prevention of biodeterioration by lampenflora. 相似文献
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Photo-induced degradation of diuron in aqueous solution by nitrites and nitrates: kinetics and pathways 总被引:2,自引:0,他引:2
The photo-induced degradation of diuron (3-(3,4-dichlorophenyl)-1,1-dimethylurea) in aqueous solution under simulated solar irradiation has been investigated in the presence of NO3-/NO2- ions. The degradation rates were compared by varying environmental parameters including substrate and inducer concentrations, oxygen content and pH. The photoproducts were identified by extensive LC-ESI-MS and LC-ESI-MS-MS studies after SPE preconcentration on prepacked cartridges. In both NO3- and NO2- conditions, oxidation of the N-(CH3)2 terminus group is the main process leading to the N-monodemethylated (NHCH3), N-formyl (N(CH3)CHO) and the uncommon and unstable carbinolamine (N(CH3)CH2OH) by-products. Cl/OH substituted and nitrated phenylureas are formed minorily. Degradation pathways involving OH* and NO2* (or dimer) radicals as reactive species are proposed. 相似文献
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Pfendler Stéphane Einhorn Olympe Alaoui-Sossé Laurence Bousta Faisl Alaoui-Sossé Badr Aleya Lotfi 《Environmental science and pollution research international》2021,28(3):2987-2994
Environmental Science and Pollution Research - In La Glacière cave (France), the touristic activity has been conducted to an environmental parameter change that has led to photosynthetic... 相似文献
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Ghanem A Bados P Estaun AR de Alencastro LF Taibi S Einhorn J Mougin C 《Chemosphere》2007,69(9):1368-1373
Indirect soil pollution by heavy metals and organics may occur when sewage sludge is used as fertilizer. It is essential to define the nature and amounts of pollutants contained in sewage sludge in order to assess environmental risk. Here, we present results from a one-year monitoring of herbicides (glyphosate, diuron and atrazine) and their major degradates in sewage sludge sampled from three wastewater treatment plants and one composting unit in the vicinity of Versailles, France. The concentrations of these compounds were determined, as well as these of the surfactant nonylphenol. We demonstrated the presence of glyphosate and aminomethylphosphonic acid at the mg kg(-1) (dry matter) level in all samples. Diuron was detected at the microg kg(-1) (d.m.) level, whereas its degradate and triazine compounds were below the limits of quantification. Nonylphenol amounts were higher than the future European limit value of 50 mg kg(-1) (d.m.). 相似文献
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The nitrate-induced photodegradation of phenylureas in water was demonstrated to occur efficiently using natural sunlight irradiation. The kinetics of disappearance was found to be dependent on the inducer and substrate concentrations, the phenylurea structure and the origin and composition of the aqueous matrix including the presence of nitrite. The measured effects under sunlight were of the same order of those measured previously in the lab using our solar light simulated system. However, by-product distribution might differ substantially particularly considering the nitration pathway. 相似文献
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