Analysis of polycyclic aromatic hydrocarbons (PAHs) in airborne particles by direct sample introduction thermal desorption GC/MS

The technique of thermal desorption (TD)–GC/MS was evaluated for measuring airborne, 4–6 ring polycyclic aromatic hydrocarbons (PAHs) collected onto quartz filters. TD provides a more readily automated and sensitive alternative to traditional solvent extraction, decreasing the time/cost of analysis and reducing the risk of analyte loss or sample contamination. The developed method was successfully applied to the analysis of PAH standard solutions loaded on sorbent tubes packed with quartz wool and the graphitized carbon black sorbent Carbograph2. The optimized method showed high desorption efficiency over the whole range of target PAHs with good precision, linearity and sensitivity. The proposed method was verified on an urban dust Standard Reference Material (SRM 1649a); the experimentally determined concentrations agreed with the certified ranges (95% confidence limit) for all target compounds except benzo[a]anthracene, which fell just outside the narrow certified range. The desorption efficiency and the reproducibility of the method was evaluated by analysing pieces of real sample filters sampled from urban air for a period of 24 h. The results confirmed the homogeneity of the filter and showed high recovery efficiencies for all target PAHs.     

State-of-the-art and current challenges for TiO2/UV-LED photocatalytic degradation of emerging organic micropollutants

Environmental Science and Pollution Research - The development of ultraviolet light-emitting diodes (UV-LED) opens new possibilities for water treatment and photoreactor design. TiO2...     

Developing a SINTACS-based method to map groundwater multi-pollutant vulnerability using evolutionary algorithms

Environmental Science and Pollution Research - In this study, the modified SINTACS method, a rating-based groundwater vulnerability approach, was applied to data from the Campanian Plain, southern...     

Indoor air quality (IAQ) assessment in a multistorey shopping mall by high-spatial-resolution monitoring of volatile organic compounds (VOC)

In order to assess indoor air quality (IAQ), two 1-week monitoring campaigns of volatile organic compounds (VOC) were performed in different areas of a multistorey shopping mall. High-spatial-resolution monitoring was conducted at 32 indoor sites located in two storehouses and in different departments of a supermarket. At the same time, VOC concentrations were monitored in the mall and parking lot area as well as outdoors. VOC were sampled at 48-h periods using diffusive samplers suitable for thermal desorption. The samples were then analyzed with gas chromatography–mass spectrometry (GC–MS). The data analysis and chromatic maps indicated that the two storehouses had the highest VOC concentrations consisting principally of terpenes. These higher TVOC concentrations could be a result of the low efficiency of the air exchange and intake systems, as well as the large quantity of articles stored in these small spaces. Instead, inside the supermarket, the food department was the most critical area for VOC concentrations. To identify potential emission sources in this department, a continuous VOC analyzer was used. The findings indicated that the highest total VOC concentrations were present during cleaning activities and that these activities were carried out frequently in the food department. The study highlights the importance of conducting both high-spatial-resolution monitoring and high-temporal-resolution monitoring. The former was able to identify critical issues in environments with a complex emission scenario while the latter was useful in interpreting the dynamics of each emission source.     

Prenatal karyotyping in malformed fetuses

Experience with prenatal karyotyping of 237 fetuses with sonographic evidence of malformation is reported. Abnormal karyotype was found in 40 cases (16-8 per cent): chromosomal aberrations were found in 19 of the 178 fetuses with an isolated structural anomaly (10-6 per cent) and in 21 of the 59 fetuses with multiple malformations (35-6 per cent). Detailed cytogenetic and morphological information concerning fetuses affected by omphalocele, duodenal atresia, hydrocephalus, multicystic kidney, unilateral hydronephrosis and cystic hygroma is reported. The need for a very careful ultrasound evaluation of fetal anatomy in these pregnancies is stressed, as the risk of a chromosomal anomaly depends mainly on the existence of more than one ultrasonically diagnosed structural defect.     

Recent shoreline evolution and beach erosion along the central Adriatic coast of Italy: the case of Molise region

A study on the modern dynamics and shoreline changes from 1954 to 2014 of the Molise coast (central Adriatic Sea) has been carried out. Short to long-term shoreline changes and associated surface area variations have been assessed in GIS environment for the study coast, subdivided in nine coastal segments (S1-S9), by using 100-m regularly spaced transects. In addition, the possible influence of natural and anthropogenic factors, especially of climatic variability and engineered shoreline defense structures, has been investigated. The Molise coast has experienced notable long-term erosion (period 1054-2014) that caused an overall coastal land loss of approximately 940,000 m². Erosion was, yet, limited to coastal segments S1 and S7, nearest to the mouths of major rivers, namely Trigno and Biferno, while the major part of the study coast has remained essentially stable or even advanced. Increased shoreline protection by defense structures has generally favoured shoreline stability and frequently generated shoreline advance, except for segments S1 and S7. Observed differences in shoreline change rates over time at the decadal to interannual scale, have not find a response in the analysis of available data on meteo-marine conditions of the Molise coast and climate variability indices, pointing out the need to improve knowledge on meteomarine conditions and on climatic variability forcing of the study area. From 2004 to 2014, the Molise shoreline remained essentially stable. Nonetheless, most recent shoreline changes (period 2011-2014) and modern shoreline dynamics indicate that erosion has become more widespread, involving at least part of segments S2-S3 and S8-S9, located south of the river mouth segments. The localized long-term shoreline retreat and most recent shoreline erosion appear to be primarily related to channel adjustments of the Biferno and Trigno rivers that occurred since the 1950s under the control of human interventions on the rivers, especially the construction respectively of a dam and a check dam along their lower courses, that trap of most of their solid load, affecting so adversely the sediment budget of the river mouths areas and adjacent beaches. Overall data acquired on the recent shoreline evolution and modern shoreline dynamics of the Molise coast and on related causal factors provide a good basic knowledge for regional coastal management purposes, and for further scientific purposes. Particularly, they suggest the opportunity to deepen a number of aspects such as the relationship between the coast and river catchments feeding it, the possible influences on the Molise shoreline dynamics of the neighbouring coasts, the efficiency/obsolescence of defense structures and the present-day vulnerability to coastal erosion of the Molise coast.     

The assessment of the coastal vulnerability and exposure degree of Gran Canaria Island (Spain) with a focus on the coastal risk of Las Canteras Beach in Las Palmas de Gran Canaria

The Coastal Vulnerability and Exposure Degree (CVED) of the Gran Canaria Island and the coastal risk of Playa de Las Canteras (Las Palmas de G.C.) have been assessed by means of a GIS analysis. The evaluation of coastal vulnerability (H) has been performed by using two different levels of analysis: the first one regarding the entire Island (Coastal Vulnerability Index method - CVI), the second one regarding specifically Las Canteras Beach, selected for its socio-economic importance (Coastal Vulnerability Assessment method - CVA). The application of the CVI method, based on geologic-geomorphologic and meteomarine data easily available, has allowed the regional scale assessment of coastal vulnerability (H) along the Gran Canaria coastline and, therefore, the individuation of more critical coast stretches deserving further analysis. The application of the CVA method, based on more specific morphologic-sedimentary beach features that allow to consider both the beach retreat due to storm surge and the coastal inundation due to run-up on the beach, has provided a large scale detail on the coastal vulnerability of Las Canteras Beach. Socio-economic and damage indexes have been determined for the 15 coastal municipalities included in the study area and, by means of the resulting matrix product, the degree of exposure (E_x) along the Gran Canaria coast has been assessed. Finally, the combination of coastal vulnerability and exposure levels has allowed to obtain the Coastal Vulnerability and Exposure Degree (CVED) for the entire Island and the risk levels that characterize specifically Las Canteras Beach. Major results in terms of CVED highlight prevailing low vulnerability and exposure levels along the western coast, and overall high vulnerability and exposure levels along the eastern coast, from Las Palmas de G.C. to San Bartolomé de Tirajana. The focus made on Playa de Las Canteras has allowed to identify the areas characterized by medium and high risk levels that represent approximately one third (940 m) of the entire beach and are located in its central part. The used two-level analysis approach has proved its efficiency by highlighting the degree of coastal vulnerability along the study coast and, especially, more critical coast stretches (CVI method) such as the Playa de Las Canteras that can be successfully analysed with the CVA approach allowing for a large-scale assessment of risk aspects, essential for a correct definition of priority management strategies. Results obtained with the present study, along with the awareness of the increasing phenomena of coastal erosion and marine flooding arising on the mid-long term due to the effects of global climate change, highlight the need for the competent public administrations of Gran Canaria to develop a strategic approach to coastal management and sustainable development that considers as a whole socio-economic values and natural resources, coastal vulnerability and exposure degree, and risk aspects.