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World data centre for greenhouse gases     

Changing places, changing emissions: The cross-scale reliability of greenhouse gas emission inventories in the US

Greenhouse gas (GHG) emission inventories, which currently inform abatement policy discussions, are developed mostly from national scale data. Nevertheless, although the policy debate tends to take place in global and national arenas, action to abate GHG emissions is inherently within the provenance of local institutions and communities. The purpose of this paper is to examine how much information is lost by not estimating GHG emissions data at scales finer than the whole US. Such information may be critical in bridging global and local policy. Differences in the composition of GHG emission sources based on GHG emission inventories at three nested spatial scales (national, state, local) for four study sites (in Kansas, North Carolina, Ohio and Pennsylvania) are analysed, drawing upon initial results of a large collaborative study known as the 'Association of American Geographers-Global Change in Local Places (GCLP)' project. The concept of spatial sovereignty of emissions is developed to test the cross-scale reliability of emission inventories. For the test year 1990, close agreement is found in the by-gas composition of GHG emissions among national, state and local inventories. Spatial sovereignty in this case is maintained. However close agreement is not found in the by-source composition of GHG emissions among national, state and local inventories. Spatial sovereignty in this case is not maintained. Regular compilation of state and local emissions source inventories may be necessary to track important spatial and temporal deviations from national trends.     

Stability of pentobarbital in soil

Intravenous injection of barbiturates, particularly pentobarbital (5-ethyl-5-pentan-2-yl-1,3-diazinane-2,4,5-trione), is a widely used method to euthanize large animals such as horses. However, one concern with this method is the fate of pentobarbital after the disposal of the carcass. As tissues decompose, pentobarbital may leach into the soil and from there migrate to groundwater. A method using methanol extraction, solid phase concentration, and liquid chromatography (LC/MS) has been developed to measure pentobarbital in soils. Recovery of pentobarbital from soil averaged approximately 85% from different soil types including topsoil, potting soil, sand, stall sweepings, and loam. The method was capable of detecting pentobarbital levels of 0.1 ppm. A calibration curve was constructed with a linear range of 1 ppm to 100 ppm. The limit of quantification was 0.5 ppm. The rate of degradation of pentobarbital in sand, topsoil, and potting soil was measured over a 17-week period. At the end of week 17, approximately 17% of the pentobarbital remained in the sand, 19% remained in the topsoil, and 10% remained in the potting soil. While there was a significant decrease in the pentobarbital recovered from the soil, there were still detectable amounts of pentobarbital present in the soil after 17 weeks. To determine the importance of bacterial degradation, the three soil types were autoclaved before addition of pentobarbital. After autoclaving, no degradation of pentobarbital was observed in sand and one topsoil sample, while there was no difference in the degradation of pentobarbital in autoclaved potting soil versus potting soil that had not undergone autoclaving.