Conversion of rice husk ash to zeolite beta

White rice husk ash (RHA), an agriculture waste containing crystalline tridymite and alpha-cristobalite, was used as a silica source for zeolite Beta synthesis. The crystallization of zeolite Beta from RHA at 150 degrees C in the presence of tetraethylammonium hydroxide was monitored by XRD, FTIR and (29)Si MAS NMR techniques. It was found that zeolite Beta started to form after 12h and the complete crystallization of zeolite Beta phase was achieved after 2d. XRD, (29)Si MAS NMR and solid yield studies indicate that the transformation mechanism of silica present in RHA to zeolite Beta involves dissolution of the ash, formation of an amorphous aluminosilicate after 6h of crystallization, followed by dissolution in the mother liquor and final transformation to pure zeolite Beta crystals.     

Anti-oviposition activities of used sock media against a dengue vector: prospects of eco-friendly control and solutions to pollution

Yearly, huge amounts of sock refuse are discarded into the environment. Socks contain many molecules, and worn ones, which are rich in smell-causing bacteria, have a strong influence on animals’ behaviors. But the impacts of sock odor on the oviposition behavior of dengue vectors are unknown. We assessed whether Aedes albopictus changes its oviposition activity in response to the presence of used socks extract (USEx) in potential breeding grounds, using choice and no-choice bioassays (NCB). When furnished even chances to oviposit in two sites holding USEx and two others containing water (control), Ae. albopictus deposited significantly less eggs in USEx than in water sites. A similar pattern of oviposition preference was also observed when there were more oviposition options in water. When there were greater oviposition opportunities in USEx sites, Ae. albopictus oviposited preferentially in water. Females laid significantly more eggs during the NCB involving water than USEx. Also, significantly more mature eggs were retained by females in the NCB with USEx than in that with water. These observations strongly suggest the presence of molecules with either repellent or deterrent activities against Ae. albopictus females and provide an impetus to advocate the integration of used socks in dengue control programs. Such applications could be a realistic end-of-life recourse to reroute this waste from landfills.

     

The effect of weather data on the spread of COVID-19 in Jordan

Environmental Science and Pollution Research - This study aims to analyze the correlation between the daily confirmed COVID-19 cases in Jordan and metrological parameters including the average...     

A Modeling System to Assess Land Cover Land Use Change Effects on SAV Habitat in the Mobile Bay Estuary

Estuarine ecosystems are largely influenced by watersheds directly connected to them. In the Mobile Bay, Alabama watersheds we examined the effect of land cover and land use (LCLU) changes on discharge rate, water properties, and submerged aquatic vegetation, including freshwater macrophytes and seagrasses, throughout the estuary. LCLU scenarios from 1948, 1992, 2001, and 2030 were used to influence watershed and hydrodynamic models and evaluate the impact of LCLU change on shallow aquatic ecosystems. Overall, our modeling results found that LCLU changes increased freshwater flows into Mobile Bay altering temperature, salinity, and total suspended sediments (TSS). Increased urban land uses coupled with decreased agricultural/pasture lands reduced TSS in the water column. However, increased urbanization or agricultural/pasture land coupled with decreased forest land resulted in higher TSS concentrations. Higher sediment loads were usually strongly correlated with higher TSS levels, except in areas where a large extent of wetlands retained sediment discharged during rainfall events. The modeling results indicated improved water clarity in the shallow aquatic regions of Mississippi Sound and degraded water clarity in the Wolf Bay estuary. This integrated modeling approach will provide new knowledge and tools for coastal resource managers to manage shallow aquatic habitats that provide critical ecosystem services.     

Design for safety in Safecharts with risk ordering of states

Safecharts is a variant of Statecharts intended exclusively for safety critical systems design. With two separate representations for functional and safety requirements, Safecharts brings the distinctions and dependencies between them into sharper focus, helping both designers and auditors alike in modelling and reviewing safety features. Safecharts incorporates ways to represent equipment failures and failure handling mechanisms and uses a safety-oriented classification of transitions and a safety-oriented scheme for resolving any unpredictable non-deterministic pattern of behaviour. It achieves these through an explicit representation of risks posed by hazardous states by means of an ordering of states and a concept called risk band. Recognising the possibility of gaps and inaccuracies in safety analysis, Safecharts do not permit transitions between states with unknown relative risk levels. However, in order to limit the number of transitions excluded in this manner, Safecharts provides a default interpretation for relative risk levels between states not covered by the risk ordering relation, requiring the designer to clarify the risk levels in the event of a disagreement and thus improving the risk assessment process.     

Composition of heavy metals and airborne fibers in the indoor environment of a building during renovation

The renovation of a building will certainly affect the quality of air in the vicinity of where associated activities were undertaken, this includes the quality of air inside the building. Indoor air pollutants such as particulate matter, heavy metals, and fine fibers are likely to be emitted during renovation work. This study was conducted to determine the concentration of heavy metals, asbestos and suspended particulates in the Biology Building, at the Universiti Kebangsaan, Malaysia (UKM). Renovation activities were carried out widely in the laboratories which were located in this building. A low-volume sampler was used to collect suspended particulate matter of a diameter size less than 10 μm (PM??) and an air sampling pump, fitted with a cellulose ester membrane filter, were used for asbestos sampling. Dust was collected using a small brush and scope. The concentration of heavy metals was determined through the use of inductively coupled plasma-mass spectroscopy and the fibers were counted through a phase contrast microscope. The concentrations of PM?? recorded in the building during renovation action (ranging from 166 to 542 μg m?3) were higher than the value set by the Department of Safety and Health for respirable dust (150 μg m?3). Additionally, they were higher than the value of PM?? recorded in indoor environments from other studies. The composition of heavy metals in PM?? and indoor dust were found to be dominated by Zn and results also showed that the concentration of heavy metals in indoor dust and PM?? in this study was higher than levels recorded in other similar studies. The asbestos concentration was 0.0038 ± 0.0011 fibers/cc. This was lower than the value set by the Malaysian Department of Occupational, Safety and Health (DOSH) regulations of 0.1 fibers/cc, but higher than the background value usually recorded in indoor environments. This study strongly suggests that renovation issues need to be considered seriously by relevant stakeholders within the university in order to ensure that the associated risks toward humans and indoor environment are eliminated, or where this is not feasible, minimized as far as possible.     

CO2 sequestration by propagation of the fast-growing Azolla spp.

Environmental Science and Pollution Research - Azolla is a group of aquatic floating plants that can achieve very high growth rates compared to other aquatic macrophytes, with a doubling time of...     

Coffee,its roasted form,and their residues cause birth failure and shorten lifespan in dengue vectors

Environmental Science and Pollution Research - In dengue mosquitoes, successful embryonic development and long lifespan are key determinants for the persistence of both virus and vector. Therefore,...     

Sediment microbial fuel cells for bioremediation of pollutants and power generation: a review

Environmental Chemistry Letters - Worldwide pollution of almost all natural media by toxic compounds is a major public health issue requiring the development of advanced remediation techniques such...