Return to the River: Environmental Flow Policy in the United States and Canada1

Abstract: This paper provides an overview and summary of United States and Canadian federal, state, and provincial laws that offer some form of legal protection for environmental flows. Special attention is given to the new “second generation” law established in Texas and to ways western states are beginning to encourage transactions that help restore dewatered streams. Progress in the eastern states and some Canadian provinces to provide environmental flow protection is addressed. Based on this review, this paper presents recommended elements of a “model” environmental flow policy.     

Analysis and comparison of inertinite-derived adsorbent with conventional adsorbents

To increase U.S. petroleum energy-independence, the University of Texas at Arlington (UT Arlington) has developed a coal liquefaction process that uses a hydrogenated solvent and a proprietary catalyst to convert lignite coal to crude oil. This paper reports on part of the environmental evaluation of the liquefaction process: the evaluation of the solid residual from liquefying the coal, called inertinite, as a potential adsorbent for air and water purification. Inertinite samples derived from Arkansas and Texas lignite coals were used as test samples. In the activated carbon creation process, inertinite samples were heated in a tube furnace (Lindberg, Type 55035, Arlington, UT) at temperatures ranging between 300 and 850 degrees C for time spans of 60, 90, and 120 min, using steam and carbon dioxide as oxidizing gases. Activated inertinite samples were then characterized by ultra-high-purity nitrogen adsorption isotherms at 77 K using a high-speed surface area and pore size analyzer (Quantachrome, Nova 2200e, Kingsville, TX). Surface area and total pore volume were determined using the Brunauer Emmet, and Teller method, for the inertinite samples, as well as for four commercially available activated carbons (gas-phase adsorbents Calgon Fluepac-B and BPL 4 x 6; liquid-phase adsorbents Filtrasorb 200 and Carbsorb 30). In addition, adsorption isotherms were developed for inertinite and the two commercially available gas-phase carbons, using methyl ethyl ketone (MEK) as an example compound. Adsorption capacity was measured gravimetrically with a symmetric vapor sorption analyzer (VTI, Inc., Model SGA-100, Kingsville, TX). Also, liquid-phase adsorption experiments were conducted using methyl orange as an example organic compound. The study showed that using inertinite from coal can be beneficially reused as an adsorbent for air or water pollution control, although its surface area and adsorption capacity are not as high as those for commercially available activated carbons. Implications: The United States currently imports two-thirds of its crude oil, leaving its transportation system especially vulnerable to disruptions in international crude supplies. UT Arlington has developed a liquefaction process that converts coal, abundant in the United States, to crude oil. This work demonstrated that the undissolvable solid coal residual from the liquefaction process, called inertinite, can be converted to an activated carbon adsorbent. Although its surface area and adsorption capacity are not as high as those for commercially available carbons, the inertinite source material would be available at no cost, and its beneficial reuse would avoid the need for disposal.     

THE LAW OF THE COLORADO RIVER: COPING WITH SEVERE SUSTAINED DROUGHT1

ABSTRACT: The waters of the Colorado River are divided among seven states according to a complex ‘Law of the River’ drawn from interstate compacts, international treaties, statutes, and regulations. The Law of the River creates certain priorities among the states and the Republic of Mexico, and in the event of a severe sustained drought, the Law of the River dictates the distribution of water and operation of the elaborate reservoir system. Earlier work indicated that there is remarkable resilience in the system for established uses of water in the Lower Basin of the Colorado River. This work shows, based on an application of the Law of the River using computer modeling of operations of facilities on the Colorado River, that there may be serious environmental consequences and related legal restraints on how the water is used in times of shortage and that the existing legal and institutional framework governing the Colorado River does not adequately address all the issues that would be raised in a severe sustained drought. Several possible legal options for dealing with drought in the context of the Law of the River are identified.     

Air impacts from three alternatives for producing JP-8 jet fuel

To increase U.S. petroleum energy independence, the University of Texas at Arlington (UT Arlington) has developed a direct coal liquefaction process which uses a hydrogenated solvent and a proprietary catalyst to convert lignite coal to crude oil. This sweet crude can be refined to form JP-8 military jet fuel, as well as other end products like gasoline and diesel. This paper presents an analysis of air pollutants resulting from using UT Arlington's liquefaction process to produce crude and then JP-8, compared with 2 alternative processes: conventional crude extraction and refining (CCER), and the Fischer-Tropsch process. For each of the 3 processes, air pollutant emissions through production of JP-8 fuel were considered, including emissions from upstream extraction/production, transportation, and conversion/refining. Air pollutants from the direct liquefaction process were measured using a LandTEC GEM2000 Plus, Draeger color detector tubes, OhioLumex RA-915 Light Hg Analyzer, and SRI 8610 gas chromatograph with thermal conductivity detector.

According to the screening analysis presented here, producing jet fuel from UT Arlington crude results in lower levels of pollutants compared to international conventional crude extraction/refining. Compared to US domestic CCER, the UTA process emits lower levels of CO₂-e, NOx, and Hg, and higher levels of CO and SO₂. Emissions from the UT Arlington process for producing JP-8 are estimated to be lower than for the Fischer-Tropsch process for all pollutants, with the exception of CO₂-e, which were high for the UT Arlington process due to nitrous oxide emissions from crude refining. When comparing emissions from conventional lignite combustion to produce electricity, versus UT Arlington coal liquefaction to make JP-8 and subsequent JP-8 transport, emissions from the UT Arlington process are estimated to be lower for all air pollutants, per MJ of power delivered to the end user.

Implications: The United States currently imports two-thirds of its crude oil, leaving its transportation system especially vulnerable to disruptions in international crude supplies. At current use rates, U.S. coal reserves (262 billion short tons, including 23 billion short tons lignite) would last 236 years. Accordingly, the University of Texas at Arlington (UT Arlington) has developed a process that converts lignite to crude oil, at about half the cost of regular crude. According to the screening analysis presented here, producing jet fuel from UT Arlington crude generates lower levels of pollutants compared to international conventional crude extraction/refining (CCER).