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Zhang Mancheng Wang Wei Lv Zongxiang Wang Shui 《Environmental science and pollution research international》2023,30(5):11926-11935
Environmental Science and Pollution Research - Adequately choosing the physicochemical characteristics of adsorbent is crucial in improving its adsorption performance. This work investigated the... 相似文献
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Qing ZHOU Mengqiao WANG Aimin LI Chendong SHUANG Mancheng ZHANG Xiaohan LIU Liuyan WU 《Frontiers of Environmental Science & Engineering》2013,7(3):412-419
A novel hyper-crosslinked resin (MENQ) modified with an anion exchange group was prepared using divinylbenzene (DVB) and methyl acrylate (MA) as comonomers via four steps: suspension polymerization, post-crosslinking, ammonolysis and alkylation reactions. The obtained resin had both a high specific surface area (793.34 m2·g-1) and a large exchange capacity (strong base anion exchange capacity, SEC: 0.74 mmol·g-1, weak base anion exchange capacity, WEC: 0.45 mmol·g-1). XAD-4 was selected as an adsorbent for comparison to investigate the adsorption behavior of tetracycline (TC) and humic acid (HA) onto the adsorbents. The results revealed that MENQ could effectively remove both TC and HA. The adsorption capacity of XAD-4 for TC was similar to that of MENQ, but XAD-4 exhibited poor performance for the adsorption of HA. The adsorption isotherms of TC and HA were well-fitted with the Freundlich model, which indicated the existence of heterogeneous adsorption through cation-π bonding and π–π interactions. The optimal solution condition for the adsorption of TC was at a pH of 5–6, whereas the adsorption of HA was enhanced with increasing pH of the solution. 相似文献
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Wei WANG Yan MA Qing ZHOU Chendong SHUANG Mancheng ZHANG Aimin LI 《Frontiers of Environmental Science & Engineering》2015,9(1):96
A rapid and effective method based on a novel permanent magnetic hypercrosslinked resin W150 was proposed for the removal of organic micropollutants in drinking water. W150 was prepared by suspension and post-crosslinking reaction and found to possess a high specific surface area of 1149.7 m2·g-1, a small particle size of 50 μm to 100 μm, and a saturation magnetization as high as 8 emu·g-1. W150 was used to eliminate nitrofurazone (NFZ) and oxytetracycline (OTC) from drinking water compared with commercial adsorbents XAD-4 and F400D. The adsorption kinetics of NFZ and OTC onto the three adsorbents well fitted the pseudo-second-order equation (r>0.972), and the adsorption isotherms were all well described by the Freundlich equation (r>0.851). Results showed that the reduction in adsorbent size and the enlargement in sorbent pores both accelerated adsorption. Moreover, the effect of particle size on adsorption was more significant than that of pore width. Given that the smallest particle size and the highest specific surface area were possessed by W150, it had the fastest adsorption kinetics and largest adsorption capacity for NFZ (180 mg·g-1) and OTC (200 mg·g-1). For the adsorbents with dominant micropores, the sorption of large-sized adsorbates decreased because of the inaccessible micropores. The solution pH and ionic strength also influenced adsorption. 相似文献
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