碳素纤维在近岸海洋污染物磷酸盐、硅酸盐处理中的应用

对碳素纤维进行氧化改性,利用改性后的碳素纤维处理近岸污染海水,重点研究了改性碳素纤维对海水中活性磷酸盐和活性硅酸盐的吸附作用。考察了碳素纤维液相改性时间、碳素纤维投加量、活性磷酸盐初始浓度、活性硅酸盐初始浓度、吸附时间、海况、pH值等单因素对近岸海洋污染物磷酸盐、硅酸盐吸附效果的影响。研究结果表明:改性碳素纤维对硅酸盐的吸附效果较好,去除率可达70%,对活性磷酸盐的去除率为31%左右。通过正交实验确定改性碳素纤维材料修复模拟近岸海水的优化条件为:碳素纤维改性时间为1.5 h,投加量为0.01 g,硅酸盐初始浓度为3mg/L,磷酸盐初始浓度为20 mg/L,海况为3级,pH值为8,吸附时间为3 h。在此条件下,碳素纤维对磷酸盐的去除率可达31.06%,硅酸盐去除率可达70.88%。     

APPLICATION OF AN ENVIRONMENTAL AND ECONOMIC MODELING SYSTEM FOR WATERSHED ASSESSMENTS1

ABSTRACT: A National Pilot Project (NPP) on Livestock and the Environment was initiated in 1992 to help provide solutions to environmental problems associated with livestock production. A major development of the NPP was the Comprehensive Economic and Environmental Optimization Tool‐Livestock and Poultry (CEEOT‐LP), an integrated modeling system designed to produce economic and environmental indicators for alternative policy scenarios applied to intensive livestock production watersheds. The system consists of a farm‐level economic model (FEM) and two environmental models: the field‐scale APEX model and the watershed‐level SWAT model. To date, CEEOT‐LP has been applied to two watersheds in Texas and one in Iowa. Predicted reductions in P losses for two P‐based manure application rate scenarios, relative to baseline conditions, ranged from ?4 to ?54 percent across the three watersheds; however, N loss impacts ranged from a decrease of 34 percent to an increase of 79 percent. For five other alternative scenarios that were simulated for only one watershed, N and P loss impacts ranged between a reduction of 78 percent to an increase of 20 percent. Aggregate watershed‐level economic impacts of the seven scenarios spanned a spectrum of a 27 percent decrease to a 25 percent increase in profit, relative to the baseline.     

The impact of coal utilization in Texas under the National energy plan

The paper describes the results of a study of the impact of the National Energy on the trend towards increased utilization of coal and lignite in Texas with forecasts of increased coal and lignite utilization for the electric utility and industrial sectors. Environmental impacts of this increased coal and lignite use are projected in terms of increased air pollutant emissions and air quality impacts. Economic costs of compliance with alternative source emission regulations are also projected for the electric utility industry.Lignite consumption in Texas under the National Energy Plan is projected to increase from the present 13 million metric tons in 1976 to 57 million metric tons annually by 1985. Sub-bituminous coal consumption in Texas is projected to increase from 1 million metric per year in 1976 to 49 million metric tons per year in 1985. Bituminous coal consumption in Texas is expected to increase from less than one million metric tons per year in 1976 to about 3 million metric tons per year in 1985.Major increases in sulfur oxides emissions from coal and lignite combustion in Texas can be expected by 1985 of up to 1.5 × 10⁹ kg per year without controls and 0.2 × 10⁹ kg per year with controls. Increases in acid precipitation formation will result in north-east Texas from extensive lignite usage for electric power generation as a detriment to agriculture. The photochemical air pollution problem in the Houston area will probably worsen primarily because of increased nitrogen oxides and sulfur oxides emissions because of industrial coal combustion. Capital costs of air pollution controls in Texas for coal-fired utility boilers are estimated as up to U.S. $3.9 billion by 1985, with total operating costs of up to U.S. $1.2 billion per year.     

Sources and Transport of Phosphorus to Rivers in California and Adjacent States,U.S., as Determined by SPARROW Modeling

The SPARROW (SPAtially Referenced Regression on Watershed attributes) model was used to simulate annual phosphorus loads and concentrations in unmonitored stream reaches in California, U.S., and portions of Nevada and Oregon. The model was calibrated using de‐trended streamflow and phosphorus concentration data at 80 locations. The model explained 91% of the variability in loads and 51% of the variability in yields for a base year of 2002. Point sources, geological background, and cultivated land were significant sources. Variables used to explain delivery of phosphorus from land to water were precipitation and soil clay content. Aquatic loss of phosphorus was significant in streams of all sizes, with the greatest decay predicted in small‐ and intermediate‐sized streams. Geological sources, including volcanic rocks and shales, were the principal control on concentrations and loads in many regions. Some localized formations such as the Monterey shale of southern California are important sources of phosphorus and may contribute to elevated stream concentrations. Many of the larger point source facilities were located in downstream areas, near the ocean, and do not affect inland streams except for a few locations. Large areas of cultivated land result in phosphorus load increases, but do not necessarily increase the loads above those of geological background in some cases because of local hydrology, which limits the potential of phosphorus transport from land to streams.     

Growth,production and biomass of the burrowing protobranch mollusc Yoldia limatula in the Bideford River,Prince Edward Island,Canada

Samples of the population of Yoldia limatula Say were obtained from the Bideford River, Malpeque Bay, Prince Edward Island, Canada, during the summers of 1979 and 1980 by means of a dredge and a Ponar grab sampler. Size frequency analysis demonstrated that individuals in the size range 25- to 35-mm shell length were numerically dominant in May, June and July. Recruitment of juveniles in August resulted in the dominance of individuals of 5 mm and smaller which comprised 50% of the population at that time. The overall sex ratio was 48.8% males to 51.2% females. From annual lengths measured at successive winter growth bands it was determined that one-yr olds attained a shell length of between 13.8 and 17.7 mm, two-yr olds between 26.7 and 28.0 mm, three-yr olds between 33.8 and 35.2 mm, and foru-yr olds had a mean length of 38.7 mm. Y. limatula produced a croppable annual yield of between 1.19 and 2.65 g dry tissue weight m^-2 with P/B ratios of 0.65 and 1.45 respectively.     

二氧化氯消毒前后污水毒性的变化及消毒条件的影响

采用发光细菌试验和umu试验,分别考察了二氧化氯投加量和反应时间对污水二氧化氯消毒后急性毒性和遗传毒性变化的影响.结果表明,随着二氧化氯消毒剂投加量的增加,消毒后水样的急性毒性不断增大,但遗传毒性逐渐减小后趋于稳定.随着反应时间的延长,二氧化氯的消耗量不断增大,消毒后水样的急性毒性先增大后减小,遗传毒性逐渐减小后趋于稳定.由于消毒条件对污水急性毒性和遗传毒性有着不同的影响,说明污水中产生急性毒性和产生遗传毒性的物质不同,对于某一种污水,通过控制消毒条件可以使消毒后污水的急性毒性和遗传毒性都较低.     

Simulating Soil Water Content,Evapotranspiration, and Yield of Variably Irrigated Grain Sorghum Using AquaCrop

Use of models to simulate crop production has become important in optimizing irrigation management in arid and semiarid regions. However, applicability and performance of these models differ across regions, due to differences in environmental and management factors. The AquaCrop model was used to simulate soil water content (SWC), evapotranspiration (ET), and yield for grain sorghum under different irrigation regimes and dryland conditions at two sites in Central and Southern High Plains. Prediction error (P_e), estimated as the difference between simulated and measured divided by measured, for SWC ranged from ?17% to 4% in fully irrigated, ?3% to ?10% in limited irrigated, and ?16% to 25% in dryland treatments. The P_e within ±4%, ?5%, and ?17% to 24% were attained for seasonal ET under fully irrigated, limited irrigated, and dryland conditions, respectively. P_e values for grain yield were within those previously reported and ranged from ?10% to 12%, ?12% to 7%, and 9% to 17% for fully irrigated, limited irrigated and dryland conditions, respectively. Overall performance of the AquaCrop model showed it could be used as an effective tool for evaluating the impacts of variable crop and irrigation managements on the production of grain sorghum in the study area. Finally, the application of the model in the study area revealed planting date has a significant impact on sorghum yield and irrigation requirements, but the impact of planting density was negligible. Editor's note : This paper is part of the featured series on Optimizing Ogallala Aquifer Water Use to Sustain Food Systems. See the February 2019 issue for the introduction and background to the series.     

Evaluation of pesticides multiresidue contamination of khat leaves from Jazan region,Kingdome Saudi Arabia,using solid-phase extraction – gas chromatography/mass spectrometry

The habit of khat chewing is widespread with a deep-rooted sociocultural tradition in these regions and as such poses a public health problem. The use of pesticides is considered to be indispensable practice for the production of adequate food supply for the increasing demands by the global population and for control of insect-borne diseases. Thus, contamination of the environment with pesticides and entry of these chemicals into the food chain is unavoidable especially in developing countries. The main objective of our current study was to assess pesticide pollution of khat leaves (unknown origin) obtained while being smuggled into the Kingdom of Saudi Arabia and to be used in Jazan area. A total of 120 khat leaf samples were extracted using solid-phase extraction followed by gas chromatography/mass spectrometry analysis for the presence of 69 standard pesticides using an internal standard, tiphenyl phosphate. No pesticide residues were detected in all the studied samples. These data as preliminary and more experiments need to be performed to confirm our present findings. Routine monitoring of the pesticide residues is important for the prevention, control, and reduction of environmental pollution and also for legal decisions to minimize health risks.     

Drinking water quality assessment in Southern Sindh (Pakistan)

The southern Sindh province of Pakistan adjoins the Arabian Sea coast where drinking water quality is deteriorating due to dumping of industrial and urban waste and use of agrochemicals and yet has limited fresh water resources. The study assessed the drinking water quality of canal, shallow pumps, dug wells, and water supply schemes from the administrative districts of Thatta, Badin, and Thar by measuring physical, chemical, and biological (total coliform) quality parameters. All four water bodies (dug wells, shallow pumps canal water, and water supply schemes) exceeded WHO MPL for turbidity (24%, 28%, 96%, 69%), coliform (96%, 77%, 92%, 81%), and electrical conductivity (100%, 99%, 44%, 63%), respectively. However, the turbidity was lower in underground water, i.e., 24% and 28% in dug wells and shallow pumps as compared to open water, i.e., 96% and 69% in canal and water supply schemes, respectively. In dug wells and shallow pumps, limits for TDS, alkalinity, hardness, and sodium exceeded, respectively, by 63% and 33%; 59% and 70%, 40% and 27%, and 78% and 26%. Sodium was major problem in dug wells and shallow pumps of district Thar and considerable percent in shallow pumps of Badin. Iron was major problem in all water bodies of district Badin ranging from 50% to 69% and to some extent in open waters of Thatta. Other parameters as pH, copper, manganese, zinc, and phosphorus were within standard permissible limits of World Health Organization. Some common diseases found in the study area were gastroenteritis, diarrhea and vomiting, kidney, and skin problems.