Stabilization and utilization of hospital waste as road and asphalt aggregate

This article reports the operational results of the effective utilization of hospital waste molten slag produced using a high-temperature melting system, and being operated at a hospital in Selangor, Malaysia. The hospital waste is incinerated and subsequently melted at 1200°C. Scanning election microscope (SEM)/EDX results showed that the slag produced after melting contained amounts of SiO₂, CaO, and Al₂O₃ in excess of 53%, 9%, and 16%, respectively. The results from a leaching analysis on the slag produced proved that the melting process had successfully stabilized the heavy metals. The use of this slag as an alternative material to replace conventional aggregates for road construction was studied. The results from aggregate and asphalt mix tests showed that the slag produced fulfills all the requirements of an alternative aggregate. The average asphalt content, or the optimum asphalt content to be mixed with hospital waste molten slag, was found to be about 5.53%.     

Synthesis of piperazine functionalized magnetic sporopollenin: a new organic-inorganic hybrid material for the removal of lead(II) and arsenic(III) from aqueous solution

Environmental Science and Pollution Research - The present work describes the successful functionalization/magnetization of bio-polymeric spores of Lycopodium clavatum (sporopollenin) with...     

Influence of polymethyl acrylate additive on the formation of particulate matter and NOX emission of a biodiesel–diesel-fueled engine

Environmental Science and Pollution Research - The aim of this study is to investigate the effect of the polymethyl acrylate (PMA) additive on the formation of particulate matter (PM) and nitrogen...     

Investigation on the effect of sintering temperature on kaolin hollow fibre membrane for dye filtration

Despite its extraordinary price, ceramic membrane can still be able to surpass polymeric membrane in the applications that require high temperature and pressure conditions, as well as harsh chemical environment. In order to alleviate the high cost of ceramic material that still becomes one of the major factors that contributes to the high production cost of ceramic membrane, various attempts have been made to use low cost ceramic materials as alternatives to well-known expensive ceramic materials such as alumina, silica, and zirconia in the fabrication of ceramic membrane. Thus, local Malaysian kaolin has been chosen as the ceramic material in this study for the preparation of kaolin hollow fibre membrane since it is inexpensive and naturally abundant in Malaysia. Due to the fact that the sintering process plays a prominent role in obtaining the desired morphology, properties, and performances of prepared ceramic membrane, the aim of this work was to study the effect of different sintering temperatures applied (ranging from 1200 to 1500 °C) in the preparation of kaolin hollow fibre membrane via dry/wet phase inversion-based spinning technique and sintering process. The morphology and properties of membrane were then characterised by SEM, AFM, FTIR, XRD, and three-point bending test, while the performances of membrane were investigated by conducting water permeation and Reactive Black 5 (RB5) dye rejection tests. From the experimental results obtained, the sintering temperature of 1400 °C could be selected as the optimum sintering temperature in preparing the kaolin hollow fibre membrane with the dense sponge-like structure of separation layer that resulted in the good mechanical strength of 70 MPa with the appreciable water permeation of 75 L/h m² bar and RB5 rejection of 68%.     

Do renewable energy and globalization enhance ecological footprint: an analysis of top renewable energy countries?

Environmental Science and Pollution Research - This paper aims at estimating the dynamic impact of renewable and non-renewable energy consumption, globalization, urbanization, and economic growth...     

Ethanol mediated As(III) adsorption onto Zn-loaded pinecone biochar: Experimental investigation, modeling, and optimization using hybrid artificial neural network-genetic algorithm approach

Organic matters (OMs) and their oxidization products often influence the fate and transport of heavy metals in the subsurface aqueous systems through interaction with the mineral surfaces. This study investigates the ethanol (EtOH)-mediated As(III) adsorption onto Zn-loaded pinecone (PC) biochar through batch experiments conducted under Box–Behnken design. The effect of EtOH on As(III) adsorption mechanism was quantitatively elucidated by fitting the experimental data using artificial neural network and quadratic modeling approaches. The quadratic model could describe the limiting nature of EtOH and pH on As(III) adsorption, whereas neural network revealed the stronger influence of EtOH (64.5%) followed by pH (20.75%) and As(III) concentration (14.75%) on the adsorption phenomena. Besides, the interaction among process variables indicated that EtOH enhances As(III) adsorption over a pH range of 2 to 7, possibly due to facilitation of ligand–metal(Zn) binding complexation mechanism. Eventually, hybrid response surface model–genetic algorithm (RSM–GA) approach predicted a better optimal solution than RSM, i.e., the adsorptive removal of As(III) (10.47 μg/g) is facilitated at 30.22 mg C/L of EtOH with initial As(III) concentration of 196.77 μg/L at pH 5.8. The implication of this investigation might help in understanding the application of biochar for removal of various As(III) species in the presence of OM.     

Leachate characterization in semi-aerobic and anaerobic sanitary landfills: A comparative study

This study analyzes and compares the results of leachate composition at the semi-aerobic Pulau Burung Landfill Site (PBLS) (unaerated pond and intermittently aerated pond) and the anaerobic Kulim Sanitary Landfill in the northern region of Malaysia. The raw samples were collected and analyzed for twenty parameters. The average values of the parameters such as phenols (1.2, 6.7, and 2.6 mg/L), total nitrogen (448, 1200, and 300 mg/L N-TN), ammonia-N (542, 1568, and 538 mg/L NH₃-N), nitrite (91, 49, and 52 mg/L NO₂^?-N), total phosphorus (21, 17, and 19 mg/L), BOD₅ (83, 243, and 326 mg/L), COD (935, 2345, and 1892 mg/L), BOD₅/COD (0.096,0.1124,0.205%), pH (8.20, 8.28, and 7.76), turbidity (1546, 180, and 1936 Formazin attenuation units (FAU)), and color (3334, 3347, and 4041 Pt Co) for leachate at the semi-aerobic PBLS (unaerated and intermittently aerated) and the anaerobic Kulim Sanitary Landfill were recorded, respectively. The obtained results were compared with previously published data and data from the Malaysia Environmental Quality Act 1974. The results indicated that Pulau Burung leachate was more stabilized compared with Kulim leachate. Furthermore, the aeration process in PBLS has a considerable effect on reducing the concentration of several pollutants. The studied leachate requires treatment to minimize the pollutants to an acceptable level prior to discharge into water courses.     

The effects of three sympatric ladybird species on oviposition by Menochilus sexmaculatus (Coleoptera: Coccinellidae)

Oviposition site selection has a strong impact on the spatial distribution and sustenance of a species. This site selection by ladybirds (Coleoptera: Coccinellidae) is known to be well mediated amongst other factors by the oviposition deterring pheromones present in conspecific larval tracks. It would be also useful to the organism to be sensitive to heterospecific larval tracks, to protect from intraguild predation; however, this has not yet garnered much attention and there are only a few scattered studies with ambiguous results. The present study thus investigates the oviposition deterring effects of heterospecific presence and semiochemicals of heterospecific life stages (eggs, fourth instar larvae, pupae, adult males and females) of ladybird species, viz. Coccinella septempunctata, C. transversalis, Propylea dissecta on females of Menochilus sexmaculatus. Results reveal that the presence of all heterospecific life stages inhibits oviposition of M. sexmaculatus and the inhibition is density dependent. Semiochemicals of eggs, larval and adult tracks also show density-dependent inhibitory effects. The semiochemical-induced oviposition inhibition was stage specific with respect to the degree of inhibition. Of all heterospecific species tested, maximum and minimum oviposition deterrence of M. sexmaculatus was against C. septempunctata and P. dissecta, respectively. Comparison of our previously published results on oviposition inhibition in M. sexmaculatus due to conspecific presence with the current ones revealed increased inhibition in conspecific presence than heterospecific indicating ability to differentiate.     

Modeling the spatial dynamics of regional land use: the CLUE-S model

Land-use change models are important tools for integrated environmental management. Through scenario analysis they can help to identify near-future critical locations in the face of environmental change. A dynamic, spatially explicit, land-use change model is presented for the regional scale: CLUE-S. The model is specifically developed for the analysis of land use in small regions (e.g., a watershed or province) at a fine spatial resolution. The model structure is based on systems theory to allow the integrated analysis of land-use change in relation to socio-economic and biophysical driving factors. The model explicitly addresses the hierarchical organization of land use systems, spatial connectivity between locations and stability. Stability is incorporated by a set of variables that define the relative elasticity of the actual land-use type to conversion. The user can specify these settings based on expert knowledge or survey data. Two applications of the model in the Philippines and Malaysia are used to illustrate the functioning of the model and its validation.