Large-scale green synthesis of Cu nanoparticles

This article reports a novel, eco-friendly herbal method to synthesize Cu nanoparticles in large scales. Cu nanoparticles are an alternative to Ag and Au nanoparticles and have potential applications in many industrial areas. Many synthetic routes have been documented for the preparation of copper nanoparticles, but very few routes are eco-friendly and large-scale. We report here the preparation of Cu nanoparticles from aqueous CuSO₄ using non-toxic and inexpensive materials like curd, milk, and herbal extracts such as tamarind and lemon juice as capping agents. X-ray diffraction and transmission electron microscopy show that produced particles are nanocrystalline copper 20–50 nm in size with a face-centered cubic structure. Fourier-transformed infrared spectroscopy evidences the role of organic acids in the capping process. The novelty of this work is the synthesis of Cu nanoparticles from CuSO₄ without electricity and using non-toxic, cheap capping agents.     

A numerical study of hypothetical storm surge and coastal inundation for AILA cyclone in the Bay of Bengal

The head Bay region bordering the Bay of Bengal is highly vulnerable to tropical cyclones. Catastrophic risks from storm surge and associated inundation are quite high due to high population density in coastal areas, socio-economic conditions, and shallow bathymetry. It features the world’s largest deltaic system comprising of ‘Sunderbans’ bordered by West Bengal and Bangladesh. In a geomorphologic sense, the head Bay region is a low-lying belt comprising several barrier islands and river drainage systems, numerous tidal creeks, and mud flats having a high risk for widespread inundation. In addition, the high tidal range together with low-lying topography leads to high risk and vulnerability from storm surge inundation. During May 2009, a severe cyclonic storm Aila struck West Bengal causing enormous destruction to life and property along coastal belts of West Bengal and Bangladesh. It was the strongest pre-monsoon cyclone in the past two decades that had landfall in West Bengal. This work reports on a numerical study for hypothetical storm surge and associated inundation from Aila using the ADCIRC model. The study covers a comprehensive qualitative analysis on water level elevation and onshore inundation for West Bengal and Bangladesh regions. The estimated peak storm surge was about 4 m in the Sunderban region that propagated into all major riverine systems, inundating the river banks as well the inland areas. Numerical simulations indicate an average inland penetration distance of 350 m with a maximum of 600 m at various coastal locations in West Bengal and Bangladesh. The study emphasizes the need and importance of inundation modeling system required for emergency preparedness and disaster management.     

Assessment of genotoxic effects of lead in occupationally exposed workers

The genotoxicological effects in 200 lead acid storage battery recycling and manufacturing industry workers in Hyderabad along with matched 200 controls were studied. The genetic damage was determined by comet, micronucleus (MN), and chromosomal aberration (CA) test in peripheral blood lymphocytes (PBL). The MN test was also carried out in buccal epithelial cells (BECs). Pb in ambient air, blood Pb (B-Pb) concentrations, and hematological parameters were measured. The superoxide dismutase (SOD), catalase (CAT), glutathione (GSH), glutathione peroxidase (GPx), and malondialdehyde (MDA) formed were also studied. The results of the present study showed that there was a statistically significant (P?P?GPx, and CAT levels were significantly decreased while GSH and MDA levels increased in exposed group when compared to control group. The present study suggests that environmental health standards should be enforced to control Pb contamination from battery industries to reduce human health risk.     

Performance and validation of a coupled parallel ADCIRC–SWAN model for THANE cyclone in the Bay of Bengal

An accurate prediction of near-shore sea-state is imperative during extreme events such as cyclones required in an operational centre. The mutual interaction between physical processes such as tides, waves and currents determine the physical environment for any coastal region, and hence the need of a parallelized coupled wave and hydrodynamic model. The present study is an application of various state-of-art models such as WRF, WAM, SWAN and ADCIRC used to couple and simulate a severe cyclonic storm Thane that developed in the Bay of Bengal during December 2011. The coupled model (ADCIRC–SWAN) was run in a parallel mode on a flexible unstructured mesh. Thane had its landfall on 30 December, 2011 between Cuddalore and Pondicherry where in-situ observations were available to validate model performance. Comprehensive experiment on the impact of meteorological forcing parameters with two forecasted tracks derived from WRF model, and JTWC best track on the overall performance of coupled model was assessed. Further an extensive validation experiment was performed for significant wave heights and surface currents during Thane event. The significant wave heights measured along satellite tracks by three satellites viz; ENVISAT, JASON-1 and JASON-2, as well in-situ near-shore buoy observation off Pondicherry was used for comparison with model results. In addition, qualitative validation was performed for model computed currents with HF Radar Observation off Cuddalore during Thane event. The importance of WRF atmospheric model during cyclones and its robustness in the coupled model performance is highlighted. This study signifies the importance of coupled parallel ADCIRC–SWAN model for operational needs during extreme events in the North Indian Ocean.     

Win-win opportunities and environmental regulation: testing of porter hypothesis for Indian manufacturing industries

This paper studies the effect of environmental regulation on the productive efficiency of water polluting industries in India. The panel data of 92 firms belonging to sugar industry of India during the period 1996-99 are used to test the Porter hypothesis of having win-win opportunities for the firms subjected to the regulation. The main empirical result is that the technical efficiency of firms increases with the degree of compliance of firms to the environmental regulation and the water conservation efforts there by supporting the Porter hypothesis.     

Benefits of the development and dissemination of climate-smart rice: <Emphasis Type="Italic">ex ante</Emphasis> impact assessment of drought-tolerant rice in South Asia

In the era of climate change, rice (Oryza sativa L.) production is increasingly affected by the rising frequency and severity of various abiotic stresses such as flood and drought. In some cases, 100 % yield loss can be attributed solely to these stresses. Hence, there is an urgent need to develop climate-smart rice that is more resilient to abiotic stresses. As the development and dissemination of climate-smart rice varieties entail costs, this article examines the net economic benefits of developing and disseminating successful drought-tolerant rice in South Asia where rice area prone to drought far outweighs area with other abiotic stresses. Drought causes major rice yield losses not only in South Asia but also in other parts of Asia and Africa. Using the ORYZA2000 (ORYZA model series were developed at the International Rice Research Institute (IRRI) in the early 1990s in collaboration with Wageningen University and Research Centre (WUR) and 16 national agricultural research and extension systems in Asia. ORYZA2000 is an update and integration of earlier versions of the ORYZA model. More detailed documentation of ORYZA2000 can be found in (http://books.irri.org/9712201716_content.pdf)) crop growth simulation model, we demonstrate that a successful drought-tolerant rice variety can provide yield gains in South Asia of a minimum of 1.71 % to a maximum of 8.96 % when there is no change in the climate and under different climate scenarios projected by Canadian General Circulation Models (CGCMs). Moreover, our economic analysis shows that the economic benefits from the successful development and dissemination of droughttolerant rice more than outweigh the research investments needed to develop a variety. Although the research, development, and dissemination of a climate-smart drought-tolerant rice variety in the South require USD 84 million, our economic model indicates that rice production will be higher by a minimum of 6 million tons worth USD 3.3 billion, and rice prices will be lower by a minimum of USD 72 per ton when a drought-tolerant variety is adopted in South Asia (as compared to the case without this new variety). This can lead to improved rice food security and better nutritional outcomes for the poor.     

Environmental regulation, productive efficiency and cost of pollution abatement: a case study of the sugar industry in India

In this paper the input distance function is estimated for the Indian Sugar industry under alternative assumptions of weak and strong disposability of bad outputs. The estimated distance function is used to make the estimates of environmental efficiency, Malmquist productivity index and shadow prices of pollutants. The technical efficiency measure estimated under the assumption of weak disposability of bad outputs is utilized to test the Porter hypothesis. Marginal costs of pollution abatement functions are estimated for different pollutants of water. Pollutant specific taxes are computed using the tax-standards method.     

Organizational adoption of sustainable manufacturing practices in India: integrating institutional theory and corporate environmental responsibility

Organizations are increasingly engaging in socially and environmentally sustainable initiatives. This paper focuses on the institutional isomorphism mechanisms to analyse the organizational adoption of sustainable manufacturing practices like eco-design, source reduction, and environmental management practices. This paper empirically examines the role of institutional influence in the organizational adoption of sustainable manufacturing practices among firms in India. The results of this study confirm the significance of the three institutional isomorphism mechanisms in influencing sustainable responses, but not all mechanisms influence the organizational response equally. In particular, the results show a strong influence of self-regulatory normative isomorphism on the implementation.