Arsenic distribution and pathway scenarios for sediments and water in a peri-urban Mongolian small-scale coal mining area (Nalaikh District,Ulaanbaatar)

The distribution of arsenic (As) in environmental compartments is investigated in the Nalaikh Depression of N-Mongolia. In Nalaikh, lignite coal is mined by artisanal small-scale mining (ASM) approaches. Because As is often associated with sulfuric minerals in coal, it was hypothesized that enrichment of As is related to coal ASM. A second hypothesis considered coal combustion in power plants, and stoves are a key source of As in the local environment. Three mobilization and distribution scenarios were developed for potential As pathways in this semiarid environment. About 43 soil and 14 water sites were analyzed for As concentrations and meaningful parameters in soil and water. About 28 topsoil samples were analyzed in surface-subsurface pairs in order to identify potential eolian surface enrichment. Additionally, fluvial-alluvial sediments and geogenic and anthropogenic deposits were sampled. Water was sampled as surface water, groundwater, precipitation, and industrial water. Results show that As does not pose a ubiquitous risk in the Nalaikh Depression. However, locally and specifically in water, As concentrations may exceed the WHO guideline value for drinking water by up to a factor of 10. A carefully selected sampling strategy allows the evaluation of the distribution scenarios, which reveals a combination of (a) geogenic As in groundwater and distribution via surface water with (b) anthropogenic As redistribution via eolian pathways. An immediate linkage between As redistribution and coal mining is not evident. However, As distribution in fly ash from coal combustion in the local power plant and yurt settlements is the most likely As pathway. Hence, the results indicate the potential influence of diffuse, low-altitude sources on As emission to the environment. As such, this study provides a good example for As distribution under semiarid climate conditions influenced by geogenic and anthropogenic factors.

     

Forecasting quantities of disused household CRT appliances--a regional case study approach and its application to Baden-Württemberg

Due to special requirements regarding logistics and recycling, disused cathode ray tube (CRT) appliances are handled in some countries as a separate waste fraction. This article presents a forecast of future household waste CRT quantities based on the past and present equipment of households with television sets and computer monitors. Additional aspects taken into consideration are the product life time distribution and the ongoing change in display technology. Although CRT technology is fading out, the findings of this forecast show that quantities of waste CRT appliances will not decrease before 2012 in Baden-Württemberg, Germany. The results of this regional case study are not quantitatively transferable without further analysis. The method provided allows analysts to consider how the time shift between production and discard could impact recycling options, and the method could be valuable for future similar analyses elsewhere.     

REGIONAL CHEMISTRY OF LAKES IN MASSACHUSETTS 1

ABSTRACT: We surveyed over 2000 lakes in the State of Massachusetts (1983–1984) to examine the spatial variations in their acid-base chemistry. Our survey differed from previous surveys by including small lakes and nonpristine urban lakes. For samples collected in October 1983 and 1984, the median acid neutralizing capacity (ANC) was 184 μeq L^?1 and 5.9 percent were acidic (ANC≤O). Small lakes (<4 ha) were more likely to be acidic than large lakes. Generally, sulfate was the dominant acidifying agent, although organic anions were dominant in some of the lakes in the Cape Cod Region. The ionic composition of the lakes showed strong regional patterns which appear to be related to geology and human population density. An analysis of variance of ANC shows the six regional categories in the state explain 51 percent of the variance, while a combined general linear model of lake drainage type, color, elevation, size, silica, and hydrogen ion deposition could explain only 4.9 percent of the variation in ANC. Calcium rich, high ionic strength lakes were present in the marble bedrock in the west, and relatively dilute lakes dominated by sodium and chloride were found near the coast. Chloride concentrations were also related to population density, suggesting road salt as a likely contributing source.