Heterogeneous and homogeneous catalytic ozonation of benzothiazole promoted by activated carbon: kinetic approach

Ozone oxidation combined with activated carbon adsorption (O(3)/AC) has recently started to be developed as a single process for water and wastewater treatment. While a number of aspects of aqueous ozone decomposition are well understood, the importance and relationship between aqueous ozone decomposition and organic contaminant degradation in the presence of activated carbon is still not clear. This study focuses on determining the contribution of homogeneous and heterogeneous reactions to organic contaminants removal in O(3)/AC system. Benzothiazole (BT) was selected as a target organic pollutant due to its environmental concern. A reactor system based on a differential circular flow reactor composed by a 19 cm(3) activated carbon fixed bed column and 1 dm(3) storage tank was used. Ozone was produced from pure and dry oxygen using an Ozocav ozone generator rated at 5 g O(3)h(-1). Experimental results show that BT removal rate was proportional to activated carbon dosage. Activated carbon surface contribution to BT oxidation reactions with ozone, increased with pH in absence of radical scavengers. The radical reaction contribution within the pH range 2-11 accounted for 67-83% for BT removal in O(3)/AC simultaneous treatment. Results suggest that at pH higher than the pH of the point of zero charge of the activated carbon dissociated acid groups such as carboxylic acid anhydrides and carboxylic acids present on activated carbon surface could be responsible for the observed increase in the ozone decomposition reaction rate. A simplified mechanism and a kinetic scheme representing the contribution of homogeneous and heterogeneous reactions on BT ozonation in the presence of activated carbon is proposed.     

Analysis of aerosol particles and coarse particulate matter concentrations in Chillán, Chile, 2001-2003

Daily particle samples were collected in Chillán, Chile, at six urban locations from September 1, 2001, through September 30, 2003. Aerosol samples were collected using monitors equipped with a Sierra Andersen 246-b cyclone inlet on Teflon filters. Average concentrations of coarse particulate matter (PM10) for the 2001-2003 period ranged from 43.4 microg/m3 to 81.8 microg/m3 across the six sites. Annual PM10 concentration levels exceeded the European Union concentration limits. Mean PM10 levels during the cold season (April through September) were more than twice as high as those observed in the warm season (October through March). Average contributions to PM10 from organic matter, soil dust, nitrate (NO3-), elemental carbon, ammonium (NH4+), and sulfate (SO4(2-)) were 31%, 27%, 11%, 8%, 7%, and 5%, respectively. The chemical analyses indicated that carbonaceous substances were the most abundant components of PM10 in cold months, whereas crustal material was the most abundant component of PM10 during warm months. Higher concentration levels were observed in the downtown area suggesting a clear anthropogenic origin, whereas in the rural sites the source was mainly natural, such as resuspended soil dust associated with traffic on unpaved roads and agricultural activities.     

建立我国生态环境标准体系的初步构想

我国的生态环境标准极其薄弱，建立生态环境标准体系是我国生态环境保护的迫切需要。借鉴我国目前针对污染防治的环境标准体系，提出了我国生态环境标准体系的基本框架，以及生态环境标准制订的原则和重点。     

生态气象监测评估业务平台的设计与应用

  针对目前生态气象监测轨道业务的特点，结合工作的实际需要，运用C和C++语言建立了生态气象监测评估业务平台。在程序设计中，采用了生成中间交换文件的结构组织，能够对各模块的输出结果进行详尽直观的分析，并提供了等值线色斑图与区域填充等多种图形绘制方式。该系统可处理AVHRR和EOS/MODIS卫星遥感资料，对气象观测报文进行解译、数据分类管理和质量控制，统计计算水体密度指数、湿润指数、植被覆盖指数、土地退化指数、灾害指数和生态质量综合评价指标，以图形、图像的形式输出生态气象监测评估产品，实现了卫星遥感与生态气象地面监测数据的有效组织和智能化管理。将系统应用于湖南省生态质量气象评价，业务化运行的结果表明，该系统具有较好的业务实用性。〖HJ1〗〖HJ〗
〖HT5”H〗     

江西武夷成矿带铜多金属矿产资源远景评价与展望

华南武夷山地区处于扬子、华夏两大构造单元交接叠加地段,构造变形复杂,中生代岩浆活动强烈,具有十分优越的成矿条件,矿产资源潜力巨大.本文以正在武夷山成矿带开展的矿产远景调查工作和资源评价工作所取得的阶段性成果为基础,分析了武夷山成矿带的成矿地质背景、主要矿床类型及近几年的找矿勘查成果,并对武夷成矿带江西省境内铜多金属矿产资源潜力进行了初步评价,划分了十七个找矿远景区.     

Comparative assessment of sustainable development in South American countries on the basis of the Sustainable Society Index

This study reports an overview of the economic, social and environmental performance of the main South American countries (SAC) as measured by the Sustainable Society Index. This is a well-known composite indicator, composed of 21 indicators, grouped in seven categories, covering environmental, social and economic wellbeing dimensions. Thirteen European countries recently incorporated into the European Union (NEUC) are considered as a reference. The study covers the period 2006–2016. The South American Region features significant natural resources and plays an important role in the global economy. However, there is concern about the long-term sustainability of social and economic development, given the high rate of economic growth based on the production of low added-value primary products. Sustainable development requires reasonable balance between economic, social and environmental performance, as well as a sustained and balanced increase in performance associated with those fundamental dimensions. Moreover, it is important to agree on minimum performance levels for all performance indicators, taking into account particular social, economic and environmental realities. SAC feature a clear imbalance in some categories affecting the economic, social and environmental wellbeing dimensions, showing either stagnation or significant decrease in recent years. It can be concluded that in the light of findings reported here, South American countries are far from being on the pathway towards sustainable development.     

A study of the particulate matter PM10 composition in the atmosphere of Chillán, Chile

Inhalable particulate matter (PM10) concentrations were measured over 24-h intervals at six different urban sites in the city of Chillán from September 2001 to April 2003. Sampling locations were selected to represent central city, commercial, residential, and industrial portions of the city. Chemical composition of PM10 was performed to samples of 47 mm diameter Teflon membranes within the city of Chillán. The spatial and temporal variability of the chemical composition of PM10 was evaluated taking into account additional data from meteorology and further air pollutants. The majority of PM mass was comprised of carbon, nitrate, sulfate, ammonium, and crustal components but in different proportion on different days and at different sites. The chemical analyses showed that carbonaceous substances and crustal material were the most abundant component of PM10 during the winter and summer, respectively. The concentrations of PM10 were higher during the cold season than during the warm season. The PM10 concentrations were higher in the downtown area of the city of Chillán, where also the chemical composition was more variable due to urban traffic and other anthropogenic sources.     

基于层次分析法的城市河流生态修复评估

城市的发展改变了许多河流的自然水文环境，并导致河流生态系统中水质、物理生境和生物完整性下降。评估受损河流水体修复的效果，需要结合物理、化学的参数，以及对生物结构、多样性和过程的影响。构建了包含河流水力、水质、水生生物、河岸带及物理结构5个方面15个指标的城市河流生态修复评估指标体系，运用群组决策的层次分析法(AHP)，确定了各指标的权重，重要性排序前5位依次为：水质污染指数、鱼类IBI、水源补给量、藻类多样性、透明度。并以我国南方城市岐江河整治修复状况为例进行综合评价，结果表明,河流生态系统修复评估结果为可以接受，体现了河流整治工程使河流水质、生态的状况有所改善，但河流生态系统恢复需要较长的周期，修复初期生态系统仍处于受损状态。〖     

接种不同普通活性污泥培养厌氧氨氧化污泥的研究

采用厌氧氨氧化反应器（ASBR）,分别以普通厌氧活性污泥、混合污泥、好氧活性污泥为种泥,通过对氨氮,NO2^--N等指标监测、分析及污泥颜色的观察,研究采用不同普通活性污泥为种泥启动ASBR的可行性及差异。结果表明．ASBR反应器A和B成功启动,C因反应器故障．启动失败。采用厌氧活性污泥为接种污泥（反应器A）,当进水N的容积负荷为kg／（m^3·d）时,氨氮平均去除率为14.4％。P（NO2^--N）：p（NH4^＋-N）变化量为1．24。采用混合污泥为接种污泥（反应器B）．N的容积负荷于前者相同时,氨氮去除率平均29．7％,p（NO2^--N）：p（NH4^＋-N）变化量为1．27。采用混合普通活性污泥作为种泥培养厌氧氨氧化污泥优于单一厌氧普通活性污泥。