The occurrence of heavy metals in irrigated and non-irrigated arable soils,NW Albania

The study analysed the content of heavy metals in surface soil and sediment samples from the Bregu i Matit Plain in NW Albania in relation to irrigation in order to evaluate the soil pollution and the potential risk to human health. Evaluation of soil pollution was performed using the enrichment factor and geo-accumulation index. Contents of cadmium, chromium and nickel of irrigated soils were significantly higher than those of non-irrigated soil, while contents of lead (in three of the irrigated locations), zinc and arsenic (in one of the irrigated locations) were significantly lower. Correlation analysis (CA) and principal component analysis (PCA) indicated that the primary source of the first three metals was irrigation, and the last three metals were originated from other anthropic sources, like the use of chemicals, etc. Enrichment factor (E _f) calculation showed that irrigated soils were most enriched in cadmium, chromium, copper and nickel. Index of geo-accumulation (I _geo) revealed that arable soils of Bregu i Matit are unpolluted to moderately polluted with cadmium, chromium, copper and zinc and moderately to strongly polluted with nickel and arsenic. The presence of heavy metals in the studied soils indicates a potential risk of transfer of these elements in the food chain. Therefore, further studies on the speciation of heavy metals in the studied soils in order to evaluate their mobility are needed.     

Development of an efficient and sensitive analytical method for the determination of copper at trace levels by slotted quartz tube atomic absorption spectrometry after vortex-assisted dispersive liquid-liquid microextraction in biota and water samples using a novel ligand

This study describes the determination of trace levels of copper by slotted quartz tube atomic absorption spectrometry after dispersive liquid-liquid microextraction. A ligand synthesized from the reaction of salicylaldehyde and 1-naphthylamine was used to form coordinate copper complex prior to extraction. All parameters that influence the output of complex formation, extraction, and instrumental measurement were optimized to enhance the absorbance signal of copper. Under the optimum conditions, about 104-fold enhancement in sensitivity was recorded over the conventional flame atomic absorption spectrometer, corresponding to a 0.51 ng/mL detection limit. The percent relative standard deviation calculated for the lowest concentration (4.8%) indicated high precision for the experimental procedure. Accuracy and applicability of the optimum method were determined by performing spiked recovery tests on urine, lake water, and mineral water samples. Satisfactory recovery results were obtained between 82.2 and 106.3% at four different concentrations. Matrix matching method was also performed to increase the accuracy of quantification, and the percent recovery calculated for 175 ng/mL was 105.14%.     

Environmental management of the stone cutting industry

Environmental Management of the stone cutting industry in Hebron is required to reduce the industry's adverse impact on the downstream agricultural land and the adverse impact on the drinking water aquifers. This situation requires the implementation of an industrial wastewater management strategic approach and technology, within the available technical and financial resources. Ten pilot projects at different locations were built at Hebron to reduce or eliminate the incompatible discharge of the liquid and solid waste to the environment and improve the stone cutting industry's effluent quality. A review of existing practices and jar test experiments were used to optimize the water recycling and treatment facilities. The factors reviewed included influent pumping rates and cycles, selection of the optimal coagulant type and addition methods, control of the sludge recycling process, control over flow rates, control locations of influent and effluent, and sludge depth. Based on the optimized doses and Turbidity results, it was determined that the use of Fokland polymer with an optimal dose of 1.5mg/L could achieve the target turbidity levels. The completion of the pilot projects resulted in the elimination of stone cutting waste discharges and an improvement in the recycled effluent quality of 44-99%. This in turn reduced the long term operating costs for each participating firm. A full-scale project that includes all the stone cutting firms in Hebron industrial area is required.     

Between national soft regulations and strong economic incentives: local climate and energy strategies in Sweden

This paper contributes to the current discussion on whether ‘soft’ regulation actually influences policy outcomes by examining the effects of national policy instruments on municipal climate and energy planning. Sweden has experienced shifts in the incentive context over the last decades complementing soft planning regulations with stringent conditions for getting national economic support to local energy and climate action. We hypothesize that when soft regulations are surrounded by detailed conditions for getting state support, there will be higher degrees of local institutionalization of climate and energy strategies. The importance of economic support as part of national policy is confirmed by evidence from local energy and climate strategies and from interviews with local decision-makers. We also find that specific municipal features such as earlier municipal engagement in national support programs and relevant inter-municipal networks function as drivers for the institutionalization of local action.