Characterization of Organic Compounds in Compost-Amended Soil

Samples of compost-amended soil from waste dumping sites in Lagos Metropolis were extracted with dichloromethane (3 × 20 cm³) and the extract was evaporated at 35 °>C. The residue was extracted with 2,2,4-trimethylpentane, and portions of the solution were applied to a column containing silica gel from which aliphatic and aromatic hydrocarbons were eluted with n-hexane and toluene respectively. Analysis of the n-hexane fraction using gas chromatography showed the presence of a mixture of aliphatic hydrocarbons, ranging from C₉ to C₂₅, while ultraviolet analysis of the toluene fraction suggested 1,2-benzanthracene; 2,3-benzphenanthrene, chrysene and pyrene as polyaromatic compounds present in samples analyzed. The crude extracts were highly coloured and viscous. Total extractable organic residues in the 2,2,4-trimethylpentane extracts ranged from 36 to 89 mg g^-1 of soil.     

Water Quality Assessment of Osun River: Studies on Inorganic Nutrients

The present investigation provides data of some ions, namely Na⁺, Ca²⁺, NH₄ ⁺,Cl^-, NO₃ ^-,CN^- and PO₄ ^3- on water samples of river Osun,selected rivers in the region and groundwaters. The pH,temperature, electrical conductivity (EC), total dissolvedsolids (TDS), total hardness (TH) and total carbon (IV) oxide(TCO₂) have also been determined to asses the chemicalstatus and pollution levels of these water sources. The highervalues of certain parameters with respect to the acceptablestandard limits for drinking water indicate the pollution inboth groundwater and river water samples of the study area, and make the waters unsuitable for various applications. Thehigh pollution river water source showed higher levels ofphosphate, nitrate and ammonium ions (P < 0.05). There is nosignificant difference (P < 0.05) between the meanconcentrations of other inorganic nutrients in the high and lowpollution water source types. The correlation coefficientbetween quality parameter pairs of river water and groundwatersamples are determined and the significance of these parametersin both types of water sources are discussed.