“Modern agriculture” transfers many pesticides to watercourses: a case study of a representative rural catchment of southern Brazil

Environmental Science and Pollution Research - The total cultivated area in Brazil reached to 62 million ha in 2018, with the predominance of genetically modified soybean and corn (36 and 17...     

Physiological responses of beet and cabbage plants exposed to copper and their potential insertion in human food chain

Environmental Science and Pollution Research - Copper (Cu) can be toxic to vegetables when it is absorbed and accumulated at large concentrations, a fact that increases the risk of excessive...     

Three-dimensional data interpolation for environmental purpose: lead in contaminated soils in southern Brazil

Monitoring of heavy metal contamination plume in soils can be helpful in establishing strategies to minimize its hazardous impacts to the environment. The objective of this study was to apply a new approach of visualization, based on tridimensional (3D) images, of pseudo-total (extracted with concentrated acids) and exchangeable (extracted with 0.5 mol L^?1 Ca(NO₃)₂) lead (Pb) concentrations in soils of a mining and metallurgy area to determine the spatial distribution of this pollutant and to estimate the most contaminated soil volumes. Tridimensional images were obtained after interpolation of Pb concentrations of 171 soil samples (57 points × 3 depths) with regularized spline with tension in a 3D function version. The tridimensional visualization showed great potential of use in environmental studies and allowed to determine the spatial 3D distribution of Pb contamination plume in the area and to establish relationships with soil characteristics, landscape, and pollution sources. The most contaminated soil volumes (10,001 to 52,000 mg Pb kg^?1) occurred near the metallurgy factory. The main contamination sources were attributed to atmospheric emissions of particulate Pb through chimneys. The large soil volume estimated to be removed to industrial landfills or co-processing evidenced the difficulties related to this practice as a remediation strategy.     

Copper availability assessment of Cu-contaminated vineyard soils using black oat cultivation and chemical extractants

Grapevines grown on acid soils with low fertility in southern Brazil are treated with intense foliar applications of copper (Cu) fungicides, resulting in an increased level of Cu in the soil and increased toxicity. The present study evaluated the accumulation and bioavailability of Cu, and soils with varying levels of Cu from the main producing regions of southern Brazil were collected. The forms of Cu present in the soil were assessed using chemical extractants; additionally, oat cultivation was performed, reflecting the use of the plant as an indicator of Cu bioavailability. Cu accumulated in the topsoil, mainly in bioavailable forms, and there was also an increase of Cu up to a depth of 0.4 m. Cu was primarily found in the mineral fraction, with apparent saturation of the soil organic matter functional groups. Inceptisol and Alfisol soils with a long history of cupric fungicide application were found to have levels of Cu toxic to oat plants. Furthermore, accumulated copper in Alfisol soil from the Campanha Gaúcha region of the state of Rio Grande do Sul had higher bioavailability compared to Cu accumulated in Inceptisol soil from the Serra Gaúcha region. In addition, the copper concentration in roots was found to serve as an indicator of Cu bioavailability in soil, but not of copper phytotoxicity in plants.     

Comparison of the Effect of Plasticizers on PHBV—and Organoclay—Based Biodegradable Polymer Nanocomposites

The aim of this work was to evaluate the effect of different plasticizers on the morphology, crystallization, and mechanical properties of poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV)/organomodified montmorillonite (OMt) nanocomposites. We investigated three different plasticizers: dioctyl phthalate (DOP), a commonly used additive in the polymer industry, and two natural and biodegradable plasticizers: epoxidized soybean oil (ESO) and triethyl citrate (TEC). The nanocomposites with 3 wt% OMt were obtained by melt processing in an internal mixer. The plasticizers were used alone or in combination with clay in a concentration of 10 wt%. X-ray diffraction and scanning electron microscopy results revealed a partially intercalated structure. The degree of crystallinity was higher for all of the samples compared to neat PHBV, although the melting temperature decreased with the use of plasticizers combined with OMt. The impact strength results were dependent on the interaction between the components of the system. Triethyl citrate was the most effective plasticizer due to its more pronounced interaction with the PHBV matrix, which yielded improvements in processing conditions and PHBV’s flexibility and impact properties.     

Parental awareness and perception for correct use of child restraint systems and airbags in Brazil

Objective: The objective of this study was to obtain information about the current knowledge and habits of parents who transport children in cars in Brazil.

Methods: A cross-sectional survey was conducted using specifically designed self-report questionnaires to parents of children attending a private pediatric office in a town in southwest Brazil. Data were collected regarding children's age, gender, height, and weight and possession of an automobile child restraint system (CRS), its type, frequency and adequacy of use, and reasons for not possessing or not using the devices. Parents were asked whether their cars were equipped with airbags and about the use of the restraints in seats with airbags.

Results: We interviewed parents of 293 children transported in cars who met the criteria for use of a CRS. Children were younger than 1 year in 15.3% of the cases, between 1 and 4 years in 38.6%, and older than 4 in 46.1%. Cars were equipped with CRS in 78.5% of the cases, but in only 58% of the cases was the device proper for child's age and adequately installed in the seat. Among owners of the devices, 84.3% reported that they always used it. Reasons for infrequency were forgetting the device at home or in another car (6.4%), the child disliking the device (3.2%), or the false impression that the child was grown enough not to use it (3.2%)l 87.1% did not justify why they did not always use the CRS. Considering type of CRS, correct installation of the seat, and frequency of use, only 44.4% of children under 1 year, 69.9% of those 1 to 4 years, and 52.6% over age 4 were protected. Only 28.6% of the parents knew that children should never be positioned in a seat with active airbags.

Conclusion: Considering appropriateness for age, correctness of installation (in the back seat in the correct orientation), and frequency of use, only 50.85% (149/293) of the children were reported as always protected with a CRS. Children between 1 and 4 years were more likely to always use a CRS in this Brazilian survey. We were also able to identify an important gap in the knowledge about airbags among parents. Further efforts are needed to correct those distortions.