Phosphorus-based metabolic pathway tracers in surface waters

Environmental Science and Pollution Research - Trophic status in surface waters has been mostly monitored by measuring soluble reactive phosphorus (SRP) and total phosphorus (TP). Additional to...     

Unusually high-pitched neonate distress calls of the open-habitat Mongolian gazelle (<Emphasis Type="Italic">Procapra gutturosa</Emphasis>) and their anatomical and hormonal predictors

In neonate ruminants, the acoustic structure of vocalizations may depend on sex, vocal anatomy, hormonal profiles and body mass and on environmental factors. In neonate wild-living Mongolian gazelles Procapra gutturosa, hand-captured during biomedical monitoring in the Daurian steppes at the Russian-Mongolian border, we spectrographically analysed distress calls and measured body mass of 22 individuals (6 males, 16 females). For 20 (5 male, 15 female) of these individuals, serum testosterone levels were also analysed. In addition, we measured relevant dimensions of the vocal apparatus (larynx, vocal folds, vocal tract) in one stillborn male Mongolian gazelle specimen. Neonate distress calls of either sex were high in maximum fundamental frequency (800–900 Hz), but the beginning and minimum fundamental frequencies were significantly lower in males than in females. Body mass was larger in males than in females. The levels of serum testosterone were marginally higher in males. No correlations were found between either body mass or serum testosterone values and any acoustic variable for males and females analysed together or separately. We discuss that the high-frequency calls of neonate Mongolian gazelles are more typical for closed-habitat neonate ruminants, whereas other open-habitat neonate ruminants (goitred gazelle Gazella subgutturosa, saiga antelope Saiga tatarica and reindeer Rangifer tarandus) produce low-frequency (<200 Hz) distress calls. Proximate cause for the high fundamental frequency of distress calls of neonate Mongolian gazelles is their very short, atypical vocal folds (4 mm) compared to the 7-mm vocal folds of neonate goitred gazelles, producing distress calls as low as 120 Hz.     

Trends in airborne particulates in Stuttgart, Germany: 1972-2005

Since 1972, at the University of Hohenheim in Stuttgart, Germany, airborne particulate matter (PM12 and then PM10) was continuously collected on filters and analyzed for environmentally relevant elements by X-ray fluorescence analysis. The resulting long-term time series are suitable for the investigation of trends and of seasonal variation. For the period 1972-2005, monthly and annual concentration mean values of 13 elements (Br, Ca, Cr, Cu, Fe, K, Mn, Ni, Pb, S, Ti, V, and Zn) in the air are presented. Trend curves were fitted and the mean yearly variation of the concentration for these elements was calculated and represented graphically. All trend curves show a diminution of the air pollution during this period, but to different extents. Mean trends in percent per year were calculated for each element both for the entire investigation period and for three data subsets of 10-11 years. Possible explanations are discussed in detail.     

Integrated shoreline management and tourism development on the cross-border World Heritage Site: A case study from the Curonian spit (Lithuania/Russia)

The varied and very dynamic landscape with a high biological diversity is a distinctive feature of the Curonian spit at the regional scale. Throughout the 20th century the main morphodynamic trend in the littoral of the Curonian spit was shoreline grading on the lagoon side, whereas on the marine side the increasing erosion at the foot of the spit, and increasing accretion at the head of the spit prevailed. The results of a discriminant analysis (Wilkes’ λ = 0.001626 and F = 29.267 when p < 0.001) show that sites with prevailing erosion, accretion and sediment input from the drifting dunes form regular inter-related spatial structures in the littoral with distinctive resulting discontinuities of the sediment drift along the lagoon coast. Dune littoral cells are characterized by Aeolian sediment input and distribution ‘down-drift’, (usually northwards) from the source. The most likely changes in the current development trends of the lagoon shore zone of the Curonian spit are related to expected climate changes and further slowing down of the dune drift. The probability of storms and ice-drift events, and their impact on coasts is expected to increase as a result of climate change. The dune advance will gradually slow down, and with it, the sand input to the coastal zone will decline. In this paper, we define integrated shoreline management as a system of long-term shoreline management measures, which is based on a littoral cell approach and aimed at harmonizing human activity in the coastal zone with the natural development of the shoreline. We propose an integrated management program for the lagoon shoreline of the Curonian spit, which is site-specific for each littoral cell as a coastal management unit. Drifting dunes and seaside beaches are the natural amenities, which are best known and best appreciated on the Curonian spit by 49% of the respondents representing the total Lithuanian population. A responsible tourism development should be considered as the key means for proper appreciation of the drifting dunes and natural coasts by society, which means to acknowledge and cherish the aesthetic and conservation values of dune and coastal landscapes of the Curonian spit as a World Heritage Site. There are at least two pre-conditions for this: (1) to provide visitors with sufficient information about diverse values and functions of the Curonian dunes and coasts within a broader regional and global heritage conservation context; (2) to enable tourists to enjoy the most impressive dune and coastal landscapes at close range. In this paper we propose to encourage active dune tourism, to reintroduce grazing into the Curonian dune areas, to restore and to preserve the most impressive landscapes of the highest white drifting dunes by bringing the blown out sand from the leeward foot of the dunes back to the crest artificially.     

Biogeochemical assessment of the urban area in Moscow

The biogeochemical and ecological assessment of the industrial city territory including urban soils and trees was carried out. Chemical (macroelement and microelement) composition of the city soils, morphological and biochemical properties of the linden leaves, possible impact of de-icing salts on soil and tree state, the correlation between the content of trace elements, and the S-containing plant compounds (phytochelatins) were included in the assessment. It was found that concentrations of trace elements in the soils near road with intensive traffic are changed from the soils, located at a distance of 40–50 m from the road. They have higher concentrations of As, Fe, Mn, Se, and Sr and lower concentration of Zn. The linden leaves from the roadside were characterized by the increase in As, Cu, Fe, Zn, and Cr and sharp decrease in the Mn and Sr concentrations. The analysis of soil water extracts showed a slight decrease of pH and low content of Ca, Mg, K, and Na for the distant sites. The phytochelatin test of linden leaves was weakly effective as well as asymmetry degree study of leaf lamina. The main differences were observed in the damage symptoms of leaves (chlorosis and necrosis) and the content of pigments (chlorophyll and carotenoids). The biochemical and ecological assessment of soils and trees showed relatively satisfactory ecological state of the investigated area in Moscow. The data obtained shows the weak local impact of the application of de-icing salts and automobile emissions.     

Runoff fluctuations in the Selenga River Basin

Regional Environmental Change - The Selenga River has historically provided 50% of the total freshwater water input to the Lake Baikal, transporting substances and pollutants that can considerably...     

Persistent organic pollutants,heavy metals and parasites in the glaucous gull (Larus hyperboreus) on Spitsbergen

The prediction of a higher parasite infection as a consequence of an impaired immune system with increasing persistent organic pollution (POP) and heavy metal levels were investigated in adult glaucous gull (Larus hyperboreus) from Svalbard. The levels of chlorinated pesticides, polychlorinated biphenyls (PCBs), toxaphenes and polybrominated diphenyl ethers (PBDEs) were measured in liver. Cupper, cadmium, lead, mercury, selenium and zinc were measured in kidney samples. An elevated ratio of PCB-118 was found, suggesting that local contamination from the settlement was detectable in the glaucous gull. Eight cestodes, four nematodes, two acanthocephalan and three trematode helminth species were found in the intestine. A positive correlation was found between cestode intensities and selenium levels and between acanthocephalan intensities and mercury levels. No correlation was found between parasite intensities and POP concentrations. It is concluded that the contaminant levels found in glaucous gulls do not cause immune suppression severe enough to affect parasite intensity.     

A computationally feasible quantum chemical model for 13C NMR chemical shifts of PCB-derived carboxylic acids

Two quantum chemical models have been derived for the prediction of 13C NMR chemical shifts of novel PCB acids obtained from PCBs by catalytic carbonylation. 13C isotropic shielding constants were calculated employing the GIAO (gauge-independent atomic orbital) method with density functional theory (DFT). The best results were obtained by cluster calculations, which took the solvent effects into account properly. In this approach, a solvent molecule (acetone) was attached by a hydrogen bond to every hydrogen atom present in a PCB acid, and the geometry of the molecular cluster was optimized employing the AM1 method. For 158 chemical shifts, the cross-validated standard error was 2.8 ppm and the cross-validated correlation coefficient was 0.94.     

Morphological differences between females of different <Emphasis Type="Italic">Jaera</Emphasis> species (Crustacea: Asellota: Isopoda) in the White Sea: a possible solution to an old problem

It is well known that females of “Jaera albifrons” species complex cannot be determined on the basis of morphological analysis. In this work, an attempt to separate females of three Jaera species on the basis of morphometric characters, the length of so-called “coupling zones” (CZ), was made. Coupling zones are those parts of the partners’ bodies that contact during copulation. Female CZ is a region between the posterior edge of the pleotelson and the border between the fourth and the fifth thoracic segments, where openings of dorsal vaginas are situated. Male CZ extends from the anterior edge of the cephalon to the first abdominal segment carrying the copulative organ. Absolute and relative lengths of CZ were used. The latter was calculated as ratio of absolute length of CZ to body length. Two settlements of Jaera in the White Sea were studied for 3 years. Species composition of these populations was quite different (the first one was dominated by J. ischiosetosa and the second by J. albifrons and, 1 year by J. praehirsuta). Males of different species were shown to be distinct in terms of absolute and relative length of CZ. Frequency distributions of absolute and relative CZ length of females differed significantly in the two settlements. The experiments based on male choice in mixed samples were organized. They revealed that females chosen by males of different species differ significantly by CZ parameters.