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排序方式: 共有685条查询结果,搜索用时 15 毫秒
1.
Escher BI Bramaz N Quayle P Rutishauser S Vermeirssen EL 《Journal of environmental monitoring : JEM》2008,10(5):622-631
We propose and evaluate a mode-of-action based test battery of low-complexity and in-vitro bioassays that can be used as a routine monitoring tool for sewage treatment efficiency and water quality assessment. The test battery comprises five bioassays covering five different modes of toxic action. The bioluminescence inhibition test with Vibrio fischeri and a growth rate inhibition test with the green algae Pseudokirchneriella subcapitata are measures of non-specific integrative effects. A second endpoint in the algae test, the specific inhibition of the efficiency of photosynthesis, gives an account of the presence of herbicides. An enzymatic assay covers an important aspect of insecticidal activity, the inhibition of the acetylcholine esterase activity. Estrogenic effects are assessed with the yeast estrogen screen (YES) and genotoxicity with the umuC test. Three field studies, each lasting six to seven consecutive days, were undertaken at a sewage treatment plant (STP) in Switzerland. Samples were collected in summer and late autumn, under dry and rainy conditions. None of the bioassays gave positive results with raw water in whole effluent toxicity testing. Therefore, water samples from various sites during wastewater treatment and from surface water were enriched with solid-phase extraction. The focus was on non-volatile compounds of average to moderate hydrophobicity, a range that includes most pesticides, biocides and pharmaceuticals. Various polar solid phases were evaluated for their extraction efficiency, disturbance by matrix components and overall performance. We finally selected a mixture of a polymeric sorbent and a C18-sorbent, Lichrolut EN and RP-18 or, alternatively, Empore SDB-RPS disks. All bioassays gave clear and robust responses with the SPE extracts. With the bioassay data the treatment efficiency of the STP can be assessed with respect to different modes of toxic action and accordingly different groups of micropollutants. Furthermore, the data allowed for a comparison between the effluent and the receiving river. In all bioassays the primary effluent had a strong effect and this effect was reduced after passing the STP. Treatment efficiency was high (typically over 90%) but varied from bioassay to bioassay, which is expected because each bioassay detects different types of micropollutants and therefore we cannot expect a common answer. 相似文献
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Escher BI Bramaz N Mueller JF Quayle P Rutishauser S Vermeirssen EL 《Journal of environmental monitoring : JEM》2008,10(5):612-621
The toxic equivalency concept is a widely applied method to express the toxicity of complex mixtures of compounds that act via receptor-mediated mechanisms such as induction of the arylhydrocarbon or estrogen receptors. Here we propose to extend this concept to baseline toxicity, using the bioluminescence inhibition test with Vibrio fischeri, and an integrative ecotoxicity endpoint, algal growth rate inhibition. Both bioassays were validated by comparison with literature data and quantitative structure-activity relationships (QSARs) for baseline toxicity were developed for all endpoints. The novel combined algae test, with Pseudokirchneriella subcapitata, allows for the simultaneous evaluation of specific inhibition of photosynthesis and growth rate. The contributions of specific inhibition of photosynthesis and non-specific toxicity could be differentiated by comparing the time and endpoint pattern. Photosynthesis efficiency, measured with the saturation pulse method after 2 h of incubation, served as indicator of specific inhibition of photosynthesis by photosystem II inhibitors. Diuron equivalents were defined as toxicity equivalents for this effect. The endpoint of growth rate over 24 h served to derive baseline toxicity equivalent concentrations (baseline-TEQ). By performing binary mixture experiments with reference compounds and complex environmental samples from a sewage treatment plant and a river, the TEQ concept was validated. The proposed method allows for easier interpretation and communication of effect-based water quality monitoring data and provides a basis for comparative analysis with chemical analytical monitoring. 相似文献
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墨岩 《中国个体防护装备》2005,(6):29-31
国际标准化组织(ISO)是目前世界上最大、最具权威的国际标准化组织之一,它促进了世界统一标准化及其有关活动的发展,从而便于国际物资交流和服务,并扩大了在知识、科学、技术和经济领域中的合作。而我国在加入WTO以后,采用国际标准参与国际标准化活动也成为我国标准化工作的当务之急。 相似文献
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Givelet N Le Roux G Cheburkin A Chen B Frank J Goodsite ME Kempter H Krachler M Noernberg T Rausch N Rheinberger S Roos-Barraclough F Sapkota A Scholz C Shotyk W 《Journal of environmental monitoring : JEM》2004,6(5):481-492
For detailed reconstructions of atmospheric metal deposition using peat cores from bogs, a comprehensive protocol for working with peat cores is proposed. The first step is to locate and determine suitable sampling sites in accordance with the principal goal of the study, the period of time of interest and the precision required. Using the state of the art procedures and field equipment, peat cores are collected in such a way as to provide high quality records for paleoenvironmental study. Pertinent field observations gathered during the fieldwork are recorded in a field report. Cores are kept frozen at -18 degree C until they can be prepared in the laboratory. Frozen peat cores are precisely cut into 1 cm slices using a stainless steel band saw with stainless steel blades. The outside edges of each slice are removed using a titanium knife to avoid any possible contamination which might have occurred during the sampling and handling stage. Each slice is split, with one-half kept frozen for future studies (archived), and the other half further subdivided for physical, chemical, and mineralogical analyses. Physical parameters such as ash and water contents, the bulk density and the degree of decomposition of the peat are determined using established methods. A subsample is dried overnight at 105 degree C in a drying oven and milled in a centrifugal mill with titanium sieve. Prior to any expensive and time consuming chemical procedures and analyses, the resulting powdered samples, after manual homogenisation, are measured for more than twenty-two major and trace elements using non-destructive X-Ray fluorescence (XRF) methods. This approach provides lots of valuable geochemical data which documents the natural geochemical processes which occur in the peat profiles and their possible effect on the trace metal profiles. The development, evaluation and use of peat cores from bogs as archives of high-resolution records of atmospheric deposition of mineral dust and trace elements have led to the development of many analytical procedures which now permit the measurement of a wide range of elements in peat samples such as lead and lead isotope ratios, mercury, arsenic, antimony, silver, molybdenum, thorium, uranium, rare earth elements. Radiometric methods (the carbon bomb pulse of (14)C, (210)Pb and conventional (14)C dating) are combined to allow reliable age-depth models to be reconstructed for each peat profile. 相似文献
5.
人工神经网络用于铅的化学形态模拟计算 总被引:1,自引:0,他引:1
用前馈线性网络法求解水体系中Pb(2+)与OH-之间的反应常数,不同训练算法对求解结果的精度、收敛速度及权值均有影响.结果表明,批处理算法的精度最好,权值不出现负值,但运算时间最长;在线算法的精度虽不如批处理算法,而比数据变换-在线算法好,权值有时会出现负值.运算时间较长;数据变换-在线算法的优点是运算时间短,但相对误差较大,权值出现负值的机会多。采用反馈网络模拟计算铅的各种化学形态的浓度.用物料核算的方法对反馈网络模型进行检验表明,此种模型用于平衡计算是可行的,详细分析了理论模拟和实验曲线的差异的原因,温度的影响最小,在4<pH<9时,CO有重要的影响.在国代检验时,n值取整所引入的误差的影响亦不可忽视。从本文的结果可以看到,采用前馈网络和反馈网络相结合的方法考察水体中的化学形态是可行的.从而为解决这一类问题提供了一种可能的途径. 相似文献
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HydrolyticdynamicsofpesticideN'-(2,4-dimethylphenyl)-N-methylformamidineinaquaticsolution¥MoHanhong;YangKewu;AnFengchun;LiuYe... 相似文献