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Groundwater treatment biowalls may be located close to a surface water body to prevent contaminant discharge from a groundwater plume into the surface water. Groundwater contaminants passing through the biowall are treated within the biowall or immediately downgradient of the biowall. Biowalls designed and constructed for the treatment of chlorinated solvents typically contain either a solid and/or liquid source of organic carbon to promote contaminant degradation by enhanced anaerobic reductive dechlorination. Common solid organic materials in biowalls include wood mulch or similar waste plant material, and common liquid organic materials are vegetable oil (possibly emulsified) or other long‐chain fatty acids. Such biowalls then develop anaerobic conditions in the constructed biowall volume, and potentially downgradient, as dissolved oxygen originally present in the aquifer is consumed. This groundwater condition can lead to the appearance of sulfide if groundwater influent to the biowall contains moderate to high sulfate concentrations. Other researchers have presented evidence for groundwater conditions downgradient of a biowall or a permeable reactive barrier (PRB) that are altered in relation to groundwater quality, besides the desired effect of contaminant degradation or removal by precipitation. The objective of this work was to investigate with modeling the changes in downgradient groundwater species chemistry as a result of a constructed biowall. This was accomplished with a chemical species model to predict levels of sulfate and sulfide present in groundwater in close downgradient proximity to the biowall. The results indicate that downgradient chemical changes could impact a surface water body to which groundwater discharges. The model described could be enhanced by incorporating additional design variables that should be considered in biowall feasibility assessments.  相似文献   
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Environmental Science and Pollution Research - In the energy-environment literature, a handful of the advanced economies, mostly the European Union countries, have met some of the national...  相似文献   
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This study investigates future impacts of global warming on climate and extreme climate events in Nigeria, the most populous African country that depends on rain-fed agriculture. Past and future climate simulations from 9 GCMs were downscaled (using a statistical model) and analyzed for the study. The study considers the impacts of two emission scenarios (B1 and A2) on the future climates (2046–2065 and 2081–2100) over ecological zones in Nigeria. The model evaluation shows that the downscaling adds values to the GCMs simulation, and the results capture all the important climatic features over the country. The model projections show that both B1 and A2 scenarios change the future climate over Nigeria. They significantly increase the temperature over all the ecological zones, with greatest warming (between 1 and 4 °C) over the Sudan (short grass) Savanna in March. The warming, which increases the occurrence of extreme temperature and heat wave events over the entire country, enhances the frequency of the extreme rainfall events in the south and southeast and reduces the annual rainfall over the northeast. Since heavy rains and floods are major problems in the south and southeast, and drought is major problem in the northeast, the global warming may further aggravate these environmental problems in future. These could have negative impacts on agriculture and further threaten livelihood and food security in the rapidly growing country. Hence, there is need for further studies on adaptation and mitigation strategies to address the impacts of global warming in Nigeria.  相似文献   
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Roadside soils were sampled from the Lagos Lagoon catchment during the wet and dry seasons over the period 2005-2009. Lagoon sediment samples were also collected within the same period. All samples were digested with aqua regia to determine total phosphorus and extracted with 0.5 M sodium bicarbonate to determine the bioavailable fraction (Olsen-P). A segmented flow analyser method was used for analysis and good accuracy was demonstrated for two reference soils (SO-2 from CCMET and SRM 2711 from NIST). The Lagos Lagoon is a hypereutrophic water body (1270 ± 1170 μg P L(-1)), with significant areas of anoxia and water hyacinth growth. The total phosphorus concentrations in roadside soils (16 sites; mean ± 2 S.D.) were 285 ± 279 mg kg(-1) in the wet season and 424 ± 629 mg kg(-1) in the dry season, indicating that rainwater leaching is a major source of phosphorus in the lagoon. The bioavailable fractions were 5.17 ± 3.47 mg kg(-1) (2.1 ± 1.5% of the total) in the wet season and 13.0 ± 8.7 mg kg(-1) (4.3 ± 4.5% of the total) in the dry season.  相似文献   
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Oily wastewater poses significant threats to the soil, water, air and human beings because of the hazardous nature of its oil contents. The objective of this review paper is to highlight the current and recently developed methods for oily wastewater treatment through which contaminants such as oil, fats, grease, and inorganics can be removed for safe applications. These include electrochemical treatment, membrane filtration, biological treatment, hybrid technologies, use of biosurfactants, treatment via vacuum ultraviolet radiation, and destabilization of emulsions through the use of zeolites and other natural minerals. This review encompasses innovative and novel approaches to oily wastewater treatment and provides scientific background for future work that will be aimed at reducing the adverse impact of the discharge of oily wastewater into the environment. The current challenges affecting the optimal performance of oily wastewater treatment methods and opportunities for future research development in this field are also discussed.  相似文献   
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Environmental Science and Pollution Research - Although the Organization for Economic Co-operation and Development (OECD) member countries are largely regarded as a high human development index and...  相似文献   
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The prevailing political atmosphere and partisanship in the United States depict the degree of polarization between the two major political parties of the country. Evidently, the polarization between the Democratic Party (DP) and the Republican Party will expectedly drive the partisan conflict to the higher levels. Considering this motivation, this paper examined the role of partisan conflict in the pollutant emissions in the case of the United States. For sound empirical analysis, the impacts of other environmental quality determinants are being examined over the period 1960–2015. In order to present a decent argument that is viable for policy implementation, the study adopts the combined methodologies of Johansen cointegration; the autoregressive distributed lag (ARDL) of Pesaran et al. J Am Stat Assoc 94(446):621–634 (1999); and the Toda and Yamamoto J Econ 66(1–2):225–250 (1995) Granger causality. Empirical outcomes show (i) the kg oil equivalent per capita energy consumed exercise positive and significant impacts on metric tons of per capita CO2 emissions, and it is the principal determinant of environmental degradation in both the short-run and the long-run (ii) renewable energy consumption and economic growth also exercise negative and significant impacts on metric tons of per capita CO2 emissions. Based on our empirical findings, we conclude that partisan conflict indirectly plays a significant role in environmental sustainability targets of the United States. Thus, we are of the opinion that the government should avoid heightened partisan conflict among the political parties in order to promote sustainable environmental policies that would enhance sound and clean environment for both the immediate and the future generation.  相似文献   
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Environmental Science and Pollution Research - More than any other nations, the crude oil–exporting countries and especially the Organization of the Petroleum Exporting Countries (OPEC) are...  相似文献   
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