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1.
The paper reports a methodology adopted to face problems related to quality assurance in soil sampling. The SOILSAMP project, funded by the Environmental Protection Agency of Italy (APAT), is aimed at (i) establishing protocols for soil sampling in different environments; (ii) assessing uncertainties associated with different soil sampling methods in order to select the "fit-for-purpose" method; (iii) qualifying, in term of trace elements spatial variability, a reference site for national and international inter-comparison exercises. Preliminary results and considerations are illustrated.  相似文献   
2.
The aim of these trials was to study the distribution of dieldrin in soil and its translocation to roots and the aerial parts of vegetable crops grown in greenhouses and fields. The main objectives were to characterize dieldrin accumulation in plant tissues in relation to the levels of soil contamination; uptake capability among plants belonging to different species, varieties and cultivars. The presence of the contaminant was quantified by gas chromatography-electron capture detector (GC-ECD) and confirmed by gas chromatography-mass spectrometer (GC-MS). The results showed a translocation of residues in cucurbitaceous fruits and flowers confirming that zucchini, cucumber and melon are crops with high uptake capability. The maximum level of dieldrin residue at 0.01 mg/kg was found to be a threshold value to safeguard the quality production of cucurbits. Tomato, lettuce and celery were identified as substitute crops to grow in contaminated fields.  相似文献   
3.
The effect of selected organic and inorganic compounds, present in snow and cloudwater was studied. Photolysis of solutions of nitrate to nitrite was carried out in the laboratory using a UVB light source. The photolysis and other reactions were then modelled. It is shown that formate, formaldehyde, methanesulphonate, and chloride to a lesser extent, can increase the initial formation rate of nitrite. The effect, particularly significant for formate and formaldehyde, is unlikely to be caused by scavenging of hydroxyl radicals. The experimental data obtained in this work suggest that possible causes are the reduction of nitrogen dioxide and nitrate by radical species formed on photooxidation of the organic compounds. Hydroxyl scavenging by organic and inorganic compounds would not affect the initial formation rate of nitrite, but would protect it from oxidation, therefore, increasing the concentration values reached at long irradiation times. The described processes can be relevant to cloudwater and the quasi-liquid layer on the surface of ice and snow, considering that in the polar regions irradiated snow layers are important sources of nitrous acid to the atmosphere. Formate and (at a lesser extent) formaldehyde are the compounds that play the major role in the described processes of nitrite/nitrous acid photoformation by initial rate enhancement and hydroxyl scavenging.  相似文献   
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5.
We measured the formation rate and the steady-state concentration of hydroxyl radicals and of singlet oxygen upon irradiation of lake water. There is controversy about the importance of singlet oxygen in the environmental photochemistry, but here we show that the steady-state concentration of 1O2 under irradiation can be higher by about two orders of magnitude compared to the hydroxyl radical. The higher occurrence of singlet oxygen in surface waters is mainly due to a higher rate of formation, because the transformation rate constants of 1O2 (collision with the solvent) and of ·OH (reaction with dissolved compounds) are comparable.  相似文献   
6.
The European Standard on sleeping bag requirements (EN 13537:2002) describes a procedure to determine environmental temperature limits for safe usage of sleeping bags regarding their thermal insulation. However, there are several possible sources of error related to this procedure. The main aim of this work was to determine the influence of the various measuring parameters on the acuity of the respective parameters in order to judge the requirements. The results indicated that air velocity, mattress insulation and time between unpacking the bag and measurement had a significant impact on the result, with a difference of up to 5–15% in thermal insulation between minimum and maximum allowable parameter levels. On the other hand, manikin weight, thickness of the artificial ground and presence of a face mask were found to have a negligible influence. The article also discusses more general aspects of the standard including the calculation methods used.  相似文献   
7.
This work describes the nitration of aromatics upon near-UV photolysis of nitrate and nitrite in aqueous solution and upon photocatalytic oxidation of nitrite in TiO2 suspensions. Phenol is used in this work as a model aromatic molecule and as a probe for *NO2/N2O4. The photoinduced nitration of phenol in aqueous systems occurs upon the reaction between phenol and *NO2 or N2O4, and is enhanced by the photocatalytic oxidation of nitrite to *NO2 by TiO2. Aromatic photonitration in the liquid phase can play a relevant role in the formation of nitroaromatics in natural waters and atmospheric hydrometeors, thus being a potential pathway for the condensed-phase nitration of aromatics. Furthermore, the photoinduced oxidation of nitrite to nitrogen dioxide suggests a completely new role for nitrite in natural waters and atmospheric aerosols.  相似文献   
8.
Photosensitised reactions can produce compounds that closely resemble the humic-like substances (HULIS) occurring in atmospheric aerosols. The relevant processes have been observed in the laboratory, in both gas–solid systems and the aqueous phase. They involve triplet sensitisers (such as benzophenones, anthraquinones and nitroaromatic compounds, which yield reactive triplet states after sunlight absorption) or photogenerated oxidants like ?OH, in the presence of substrates that undergo oligomerisation reactions upon oxidation. Formation of higher molecular weight compounds, modification of the wettability properties of organic films and photoproduction of substances with humic-like fluorescence properties have been observed as a consequence of the photosensitised reactions. Ozone plays an important but still not completely clear role in gas–solid systems.  相似文献   
9.
The Hammett approach, applied to the reaction of various classes of aromatic compounds with the radicals Cl2-*, Br2-*, *NO2, SO3-*, and SO4-* yielded good predictive models, supported by high values of the correlation coefficient r2 in the case of phenols with Cl2-* and of phenolates with *NO2 and SO3-*. Lower but statistically significant correlation coefficients could be obtained for benzoates with Cl2-*, phenolates with Br2-*, and benzoates and anisoles with SO4-*.  相似文献   
10.
The Convention on Biological Diversity proposed the Aichi Biodiversity Targets to improve conservation policies and to balance economic development, social welfare, and the maintenance of biodiversity/ecosystem services. Brazil is a signatory of the Aichi Biodiversity Targets and is the most diverse country in terms of freshwater fish, but its national policies have supported the development of unsustainable commercial and ornamental aquaculture, which has led to serious disturbances to inland ecosystems and natural resources. We analyzed the development of Brazilian aquaculture to show how current aquaculture expansion conflicts with all 20 Aichi Targets. This case suggests that Brazil and many other megadiverse developing countries will not meet international conservation targets, stressing the need for new strategies, such as the environmental management system, to improve biodiversity conservation.  相似文献   
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