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1.
Garey A. Fox George J. Sabbagh Robert W. Malone Ken Rojas 《Journal of the American Water Resources Association》2007,43(6):1359-1372
Abstract: Few studies exist that evaluate or apply pesticide transport models based on measured parent and metabolite concentrations in fields with subsurface drainage. Furthermore, recent research suggests pesticide transport through exceedingly efficient direct connections, which occur when macropores are hydrologically connected to subsurface drains, but this connectivity has been simulated at only one field site in Allen County, Indiana. This research evaluates the Root Zone Water Quality Model (RZWQM) in simulating the transport of a parent compound and its metabolite at two subsurface drained field sites. Previous research used one of the field sites to test the original modification of the RZWQM to simulate directly connected macropores for bromide and the parent compound, but not for the metabolite. This research will evaluate RZWQM for parent/metabolite transformation and transport at this first field site, along with evaluating the model at an additional field site to evaluate whether the parameters for direct connectivity are transferable and whether model performance is consistent for the two field sites with unique soil, hydrologic, and environmental conditions. Isoxaflutole, the active ingredient in BALANCE® herbicide, was applied to both fields. Isoxaflutole rapidly degrades into a metabolite (RPA 202248). This research used calibrated RZWQM models for each field based on observed subsurface drain flow and/or edge of field conservative tracer concentrations in subsurface flow. The calibrated models for both field sites required a portion (approximately 2% but this fraction may require calibration) of the available water and chemical in macropore flow to be routed directly into the subsurface drains to simulate peak concentrations in edge of field subsurface drain flow shortly after chemical applications. Confirming the results from the first field site, the existing modification for directly connected macropores continually failed to predict pesticide concentrations on the recession limbs of drainage hydrographs, suggesting that the current strategy only partially accounts for direct connectivity. Thirty‐year distributions of annual mass (drainage) loss of parent and metabolite in terms of percent of isoxaflutole applied suggested annual simulated percent losses of parent and metabolite (3.04 and 1.31%) no greater in drainage than losses in runoff on nondrained fields as reported in the literature. 相似文献
2.
To explore neuro-endocrinal changes in the brain of European honeybee (Apis mellifera) queens before and after mating, we measured the amount of several biogenic amines, including dopamine and its metabolite in the brain of 6- and 12-day-old virgins and 12-day-old mated queens. Twelve-day-old mated queens showed significantly lower amounts of dopamine and its metabolite (N-acetyldopamine) than both 6- and 12-day-old virgin queens, whereas significant differences in the amounts of these amines were not detected between 6- and 12-day-old virgin queens. These results are explained by down-regulation of both synthesis and secretion of brain dopamine after mating. It is speculated that higher amounts of brain dopamine in virgin queens might be involved in activation of ovarian follicles arrested in previtellogenic stages, as well as regulation of their characteristic behaviors. 相似文献
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4.
Tohru Kamo Kanji Takaoka Junichiro Otomo Hiroshi Takahashi 《Journal of Material Cycles and Waste Management》2006,8(2):109-115
Steam gasification of dehydrochlorinated poly(vinyl chloride) (PVC) or activated carbon was carried out in the presence of
various alkali compounds at 3.0 MPa and 560°C–660°C in a batch reactor or in a semi-batch reactor with a flow of nitrogen
and steam. Hydrogen and sodium carbonate were the main products, and methane and carbon dioxide were the minor products. Yields
of hydrogen were high in the presence of sodium hydroxide and potassium hydroxide. The acceleration effect of the alkali compounds
on the gasification reaction was as follows: KOH > NaOH > Ca(OH)2 > Na2CO3. The rate of gasification increased with increasing partial steam pressure and NaOH/C molar ratio. However, the rate became
saturated at a molar ratio of NaOH/C greater than 2.0. 相似文献
5.
Ken’ichiro Matsumoto Yuko Arai Rina Nagao Takaaki Murata Kazuma Takase Hideo Nakashita Seiichi Taguchi Hiroaki Shimada Yoshiharu Doi 《Journal of Polymers and the Environment》2006,14(4):369-374
In this paper, the photosynthetic production of short-chain-length/medium-chain-length polyhydroxyalkanoate (PHA) copolymers is reported. The wild-type and highly active doubly mutated PHA synthase 1 (S325T/Q481K, abbreviated ST/QK) genes from Pseudomonas sp. 61-3 were introduced into Arabidopsis thaliana. Peroxisome targeting signal 1 (PTS1) was used to target PHA synthases into the peroxisome to synthesize PHA from the intermediates of the β-oxidation pathway. The transgenic Arabidopsis produced PHA copolymers consisting of 40–57 mol% 3-hydroxybutyrate, 21–49 mol% 3-hydroxyvalerate, 8–18 mol% 3-hydroxyhexanoate, and 2–8 mol% 3-hydroxyoctanoate. The maximum PHA contents were 220μ g/g cell dry weight (cdw) in leaves, and 36μ g/g cdw in stems, respectively. The expression of the ST/QK mutated PHA synthase in leaves gene did not lead to significant difference in PHA content and monomer composition of PHAs, compared to the wild-type PHA synthase gene, suggesting that the supply of monomers may be a rate-determining step of PHA biosynthesis in the peroxisome. However, in stems, there were significant differences dependent on whether the wild-type or ST/QK mutated PHA synthase was expressed. These results suggest that tissue-specific monomer availability is important in determining the final mol% composition of PHA copolymers produced by the peroxisome in plants. 相似文献
6.
Ian D. Leith Lucy J. Sheppard David Fowler J. Neil Cape Matt Jones Alan Crossley Ken J. Hargreaves Y. Sim Tang Mark Theobald Mark R. Sutton 《Water, Air, & Soil Pollution: Focus》2005,4(6):207-218
Providing an accurate estimate of the dry component of N deposition to low N background, semi-natural habitats, such as bogs and upland moors dominated by Calluna vulgaris is difficult, but essential to relate nitrogen deposition to effects in these communities. To quantify the effects of NH3 inputs to moorland vegetation growing on a bog at a field scale, a field release NH3 fumigation system was established at Whim Moss (Scottish Borders) in 2002. Gaseous NH3 from a line source was released along of a 60 m transect, when meteorological conditions (wind speed >2.5 m s?1 and wind direction in the sector 180–215°) were met, thereby providing a profile of decreasing NH3 concentration with distance from the source. In a complementary study, using a NH3 flux chamber system, the relationships between NH3 concentrations and cuticular resistances were quantified for a range of NH3 concentrations and micrometeorological conditions for moorland vegetation. Cuticular resistances increased with NH3 concentration from 11 s m?1 at 3.0 μg m?3 to 30 s m?1 at 30 μg m?3. The NH3 concentration data and the concentration-dependent canopy resistance are used to calculate NH3 deposition taking into account leaf surface wetness. The implications of using an NH3 concentration-dependent cuticular resistance and the importance for refining critical loads are discussed. 相似文献
7.
8.
Riggs Rebecca Anne Langston James Douglas Beauchamp Emilie Travers Henry Ken Sereyrotha Margules Chris 《Environmental management》2020,66(1):72-90
Environmental Management - Tropical forest landscapes are undergoing rapid transition. Rural development aspirations are rising, and land use change is contributing to deforestation, degradation,... 相似文献
9.
Muhammad Kunta Biddinika Ahmad Muhammad Diponegoro Raden Muhammad Ali Raden Ibnu Rosyadi Koji Tokimatsu Fumitake Takahashi 《Journal of Material Cycles and Waste Management》2017,19(3):1069-1076
Waste management contributes to renewable energy such as biodiesel production from processes of various types of biomass including vegetable oils, animal fats, and waste of edible oil. Successful waste management effort is influenced by people concern about benefit of waste management including for renewable energy from biomass. It involves their understanding initiated by literacy on biomass energy. To help increase literacy on waste recycle and biomass energy technology, we study readability of online information regarding biomass energy in Indonesian language (Bahasa Indonesia). Indonesia is considered as one of biomass-rich country with a little utilization for energy. The readability is studied by combining two approaches: measurement by readability standard and survey on readability confirming measurement by the standard. This study focuses on the confirmation survey readability standard measured on biomass online information in Indonesian language. In the survey, 19 online text materials were read by respondents and they were asked to give their impression whether the texts are easy or difficult to understand. From this study, what factors influence understandability of text information are shown. The results could be a guidance for preparing text information to raise people concern on waste recycle and renewable energy in general. 相似文献
10.
Costin D. Untaroiu Jeff R. Crandall Yukou Takahashi Masayoshi Okamoto Osamu Ito Rikard Fredriksson 《Safety Science》2010,48(2):259-267
Lack of information from vehicle-to-child pedestrian impacts provides considerable challenges when developing vehicle countermeasures for the pediatric population. Crash reconstructions of real-world incidents provide useful information about the vehicle damage and injury outcome but do not permit definitive and quantitative measures of the impact severity given the high level of uncertainty in the initial conditions of the pedestrian and the vehicle prior the impact. This paper develops an advanced methodology for reconstructing child pedestrian–vehicle impacts that combines the crash data with multi-body simulations and optimization techniques for identifying the pedestrian posture and vehicle speed prior to impact. For the child pedestrian posture, a continuous sequence of the running gait was developed based on the literature data and simulations. Using vehicle damage information from an actual child pedestrian crash, an objective function was developed that minimized the difference between vehicle and pedestrian contact points for the simulated child postures, pedestrian, and vehicle speeds. Simulated annealing and genetic optimization algorithms were used to identify sets of potential solutions for the pedestrian and vehicle initial conditions. Local minimums were observed for several response surfaces of the objective function which shows the non-convex nature of the crash reconstruction optimization problem with the chosen objective function. Based on the results of the real-world reconstruction, this study indicates that numerical simulations coupled with heuristic optimization algorithms can be used to reconstruct child pedestrian and vehicle pre-impact conditions. 相似文献