Assessment of heavy metal enrichment in the offshore fine-grained sediments of the Caspian Sea

Sampling of the offshore seabed sediments of southwestern part of the Caspian Sea was carried out by gravity corer in order to study heavy metal concentration and the physicochemical factors controlling their distribution in the fine-grained fraction. The grain size distribution, amount, and type of clay minerals, total organic carbon (TOC) content, and Eh–pH of the sediments were determined. The average concentrations of the heavy metals in ppm are Mn (563), Cu (207.5), Sr (187), Zn (94), Pb (26.3), Ni (14.5), Co (11.5), Cd (2.56), and Ag (1.04) in their order of abundances. Co and Zn mostly indicate increase in silt-size fraction of the sediments suggesting their probable detrital provenance but the Mn, Ni, Cu, Sr, Pb, Cd, and Ag concentrations show a similar trend to distribution of the clay-size fraction. The concentrations of Mn, Co, and Cd increase with increase in the TOC content but the Cu, Pb, Ni, Ag, and Sr concentrations decrease with increase of the TOC content. The amounts of Zn, Cu, Sr, Pb, Cd, and Ag increase with increase in the CaCO₃ content. The calculated enrichment factor indicates that the sediments are very strong to extremely enriched in Ag, significantly enriched in Cu and Cd, and depleted to mineral for Pb, Sr, Co, Ni, and Zn. Variations of the Cu, Sr, Cd, Ag, and Pb concentrations are similar to the clay and CaCO₃ distributions.     

The interactions of Cr (VI) concentrations and amendments (biochar and manure) on growth and metal accumulation of two species of Salicornia in contaminated soil

Environmental Science and Pollution Research - Heavy metals are among the most dangerous contaminants in the environment. Organic components and plant species that can accumulate and stabilize...     

Application of nanobalance technique and principal component analysis for detection of the soil fumigant Telone residues in the air

Quartz crystal nanobalance (QCN) technique is considered as a powerful mass sensitive sensor for monitoring of materials in the sub-nanogram level. In the current study, a method based on QCN technique developed to determine Telone in air. Various coating materials including methyl phenyl silicon, 75% phenyl (OV25) and molecularly imprinted polymer (MIP) were employed. The frequency shift of OV25-modified quartz crystal was found to be linear against organohalogen compounds [Telone (soil fumigant), Koril (Herbicide), Endosulfan (organochlorine insecticide) and Chloroform (solvent)] concentrations in the range of 2.4 to 48 mg L(-1) for Telone vapor and 4.8-24 mg L(-1) for three other vapors. The correlation coefficients for Telone, Koril, Endosulfan and Chloroform were 0.992, 0.996, 0.989 and 0.991, respectively. The principal component analysis was also utilized to process the frequency response data of the organic vapors. Using principal component analysis, it was found that more than 93.85% of the data variance could still be explained by use of two principal components (PC1 and PC2). Subsequently, the successful discrimination of Telone and other compounds was quite possible through the principal component analysis of the transient responses of the OV25-modified electrode. In the second method, a molecularly imprinted polymer-coated sensor for Telone was developed. Molecularly imprinted polymer coated quartz crystal (MIP-QCN) showed a selective response to Telone and gave a linear relationship between frequency shift and amount of Telone from 1 to 48 mg L(-1). In this investigation, the proficiency of MIP-QCN and OV25-modified QCN sensors were compared.     

A hybrid statistical decision-making optimization approach for groundwater vulnerability considering uncertainty

Environmental Science and Pollution Research - Recognizing the vulnerable areas for contamination is a feasible way to protect groundwater resources. The main contribution of the paper is...     

Upper trapezius fatigue in carpet weaving: the impact of a repetitive task cycle

Introduction. Shoulder disorders are one of the most prevalent musculoskeletal disorders among carpet weavers. The most important cause of these disorders is muscle fatigue. The aim of the present study is to investigate the effect of carpet weaving characteristics on upper trapezius (UTr) muscle fatigue during a task cycle. Method. In this cross-sectional study, 9 women and 3 men participated. During an 80-min cycle of carpet weaving, a times-series model was applied to assess electromyography amplitude and frequency changes. Result. According to the joint analysis of electromyogram spectrum and amplitude method, the participants experienced 0% force decrease, 0.9% recovery, 18% force increase and 72% fatigue in the left UTr. Furthermore, the rates of force decrease, recovery, force increase and fatigue in the right UTr were 18%, 18%, 18% and 45%, respectively. Fatigue in the right and the left UTr was reported to be the dominant state during one carpet weaving task cycle. Conclusion. Task cycle appears to have a significant impact on UTr fatigue in participants, and UTr fatigue can be considered a serious risk factor in shoulder musculoskeletal disorders. Hence, further studies should focus on better workstations and work–rest periods during various subtasks.     

Sonochemical versus reverse-precipitation synthesis of CuxO/Fe2O3/MoC nano-hybrid: removal of reactive dyes and evaluation of smartphone for colorimetric detection of organic dyes in water media

Environmental Science and Pollution Research - In the present work, an ultrasound-assisted reverse-precipitation method was applied as a new approach for the synthesis of CuxO/Fe2O3/MoC. In the...     

Response of the predatorRhizophagus grandis to host plant derived chemicals inDendroctonus micans larval frass in wind tunnel experiments (Coleoptera: Rhizophagidae,Scolytidae)

Summary Adults of the predatory beetleRhizophagus grandis are strongly attracted to both adult and larval frass of its specific prey,Dendroctonus micans, in walking bioassays. Spruce bark and resin are relatively unattractive. Solvent extracts of larval frass that were attractive toR. grandis adults in a flight wind tunnel contained a mixture of monoterpenes of host plant origin. A synthetic mixture of these monoterpenes, (+)—-pinene, (–)—-pinene, -phellandrene,dl limonene and 3-carene, was responsible for 70–80% of the activity of the most attractive extract. We suggest that a blend of monoterpenes in frass acts as a kairomone forR. grandis but that attraction to monoterpenes is only the first of a sequence of behavioural responses that ensures successful host location and identification.     

A HYBRID OPTIMIZATION APPROACH TO THE ESTIMATION OF DISTRIBUTED PARAMETERS IN TWO-DIMENSIONAL CONFINED AQUIFERS1

ABSTRACT: In using non-linear optimization techniques for estimation of parameters in a distributed ground water model, the initial values of the parameters and prior information about them play important roles. In this paper, the genetic algorithm (GA) is combined with the truncated-Newton search technique to estimate groundwater parameters for a confined steady-state ground water model. Use of prior information about the parameters is shown to be important in estimating correct or near-correct values of parameters on a regional scale. The amount of prior information needed for an accurate solution is estimated by evaluation of the sensitivity of the performance function to the parameters. For the example presented here, it is experimentally demonstrated that only one piece of prior information of the least sensitive parameter is sufficient to arrive at the global or near-global optimum solution. For hydraulic head data with measurement errors, the error in the estimation of parameters increases as the standard deviation of the errors increases. Results from our experiments show that, in general, the accuracy of the estimated parameters depends on the level of noise in the hydraulic head data and the initial values used in the truncated-Newton search technique.