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1.
•Bacterially-mediated coupled N and Fe processes examined in incubation experiments. •NO3 reduction was considerably inhibited as initial Fe/N ratio increased. •The maximum production of N2 occurred at an initial Fe/N molar ratio of 6. •Fe minerals produced at Fe/N ratios of 1–2 were mainly easily reducible oxides. The Fe/N ratio is an important control on nitrate-reducing Fe(II) oxidation processes that occur both in the aquatic environment and in wastewater treatment systems. The response of nitrate reduction, Fe oxidation, and mineral production to different initial Fe/N molar ratios in the presence of Paracoccus denitrificans was investigated in 132 h incubation experiments. A decrease in the nitrate reduction rate at 12 h occurred as the Fe/N ratio increased. Accumulated nitrite concentration at Fe/N ratios of 2–10 peaked at 12–84 h, and then decreased continuously to less than 0.1 mmol/L at the end of incubation. N2O emission was promoted by high Fe/N ratios. Maximum production of N2 occurred at a Fe/N ratio of 6, in parallel with the highest mole proportion of N2 resulting from the reduction of nitrate (81.2%). XRD analysis and sequential extraction demonstrated that the main Fe minerals obtained from Fe(II) oxidation were easily reducible oxides such as ferrihydrite (at Fe/N ratios of 1–2), and easily reducible oxides and reducible oxides (at Fe/N ratios of 3–10). The results suggest that Fe/N ratio potentially plays a critical role in regulating N2, N2O emissions and Fe mineral formation in nitrate-reducing Fe(II) oxidation processes.  相似文献   
2.
5R (Recover, Reduce, Recycle, Resource and Reuse) approaches to manage urban water. 5R harvests storm water, gray water and black water in several forms. 5R offers promise for moving solutions for urban water scarcity in practice. Demand for water is expanding with increases in population, particularly in urban areas in developing countries. Additionally, urban water system needs a novel perspective for upgradation with urbanization. This perspective presents a novel 5R approach for managing urban water resources: Recover (storm water), Reduce (toilet flushing water), Recycle (gray water), Resource (black water), and Reuse (advanced-treated wastewater). The 5R generation incorporates the latest ideas for harvesting storm water, gray water, and black water in its several forms. This paper has briefly demonstrated each R of 5R generation for water treatment and reuse. China has the chance to upgrade its urban water systems according to 5R principles. Already, a demonstration project of 5R generation has been installed in Qingdao International Horticultural Exposition, and Dalian International Convention Center (China) has applied 5R, achieving over 70% water saving. The 5R offers promise for moving solutions for urban water scarcity from “hoped for in the future” to “realistic today”.  相似文献   
3.
自然资源资产是具有商业或交换价值的自然环境要素,是人类生存与发展的基础。生态资产是自然资源资产的重要组成部分,提供各种产品和服务。以生态资产为研究对象,从存量和流量两个方面构建核算体系,并以上海市为案例,探讨了生态资产核算体系的核算方法,评价了上海市2013年的生态资产状况与价值总量。结果显示,存量核算方面,林地的质量等级主要为中,占林地总面积的45.62%;河流的质量等级主要为劣,占总长度的54.65%。2013年生态资产流量总价值量为5 002.76亿元,其中,直接产品价值为866.12亿元,间接服务价值为4 136.64亿元。结果表明,生态资产核算体系体现了生态资产对区域社会经济发展的支撑作用,可以用来定量评估和核算区域的生态资产状况及其变化特征,可以为区域的生态系统管理与绩效考核提供科学依据。  相似文献   
4.
Biomass,as fuelwood,is one of the major sources of energy in rural areas,especially in the mountainous regions of the world.As the increasing human population exerts more pressure on the forest thereby inducing an adverse effect on the sustainability of the ecosystem,which consequently causes fuelwood crisis at a local level,this crisis is spatio-temporal in nature.Thus,the major objective of this study is to assess the sustainability of fuelwood at different probable scenarios at a micro watershed level.The present study was conducted in the Phakot watershed,the Tehri Garhwal district of central Himalaya in India,during 2006-2008.Based on the vegetation composition in the study area,the net primary productivity(NPP)value of the Oak forest,and mixed oak and sal forests,was used for the quantification of fuelwood availability in evergreen and deciduous forests,respectively.The fuelwood demand was calculated on the basis of seasonal fuelwood consumption values.Nine probable permutations for availability-demand scenarios assuming the existence of high(H),low(L)and average(A)conditions were analyzed for evaluating the stress.The available annual harvestable fuelwood in the watershed is in the minimum and maximum ranges of 2283.28 to 4066.00 tons,respectively,per year whereas it has a demand of 110.76 tons as the minimum to 3659 tons as the maximum annually.This shows that in the current availabilitydemand scenario,the watershed does not have fuelwood crisis in the present situation but needs to maintain the sustainability of the system.Based on our study,it is concluded that,globally,more spatio-temporal study is required to understand the issues at the local level.  相似文献   
5.
• Smart wetland was designed to treat wastewater according to zero waste principle. • The system included a dynamic roughing filter, Cyperus papyrus (L.) and zeolite. • It removed 98.8 and 99.8% of chemical and bacterial pollutants in 3 days. • The effluent reused to irrigate a landscape and the sludge recycled as fertilizer. • The plant biomass is a profitable resource for antibacterial and antioxidants. The present investigation demonstrates the synergistic action of using a sedimentation unit together with Cyperus papyrus (L.) wetland enriched with zeolite mineral in one-year round experiment for treating wastewater. The system was designed to support a horizontal surface flow pattern and showed satisfactory removal efficiencies for both physicochemical and bacteriological contaminants within 3 days of residence time. The removal efficiencies ranged between 76.3% and 98.8% for total suspended solids, turbidity, iron, biological oxygen demand, and ammonia. The bacterial indicators (total and fecal coliforms, as well as fecal streptococci) and the potential pathogens (Escherichia coli, Staphylococcus aureus, and Pseudomonas aeruginosa) showed removal efficiencies ranged between 96.9% and 99.8%. We expect the system to offer a smart management for every component according to zero waste principle. The treated effluent was reused to irrigate the landscape of pilot area, and the excess sludge was recycled as fertilizer and soil conditioner. The zeolite mineral did not require regeneration for almost 36 weeks of operation, and enhanced the density of shoots (14.11%) and the height of shoots (15.88%). The harvested plant biomass could be a profitable resource for potent antibacterial and antioxidant bioactive compounds. This could certainly offset part of the operation and maintenance costs and optimize the system implementation feasibility. Although the experiment was designed under local conditions, its results could provide insights to upgrade and optimize the performance of other analogous large-scale constructed wetlands.  相似文献   
6.
• Strong metal-support interaction exists on Pt/Fe3O4 catalysts. • Pt metal particles facilitate the formation of oxygen vacancies on Fe3O4. • Fe3O4 supports enhance the strength of CO adsorption on Pt metal particles. The self-inhibition behavior due to CO poisoning on Pt metal particles strongly impairs the performance of CO oxidation. It is an effective method to use reducible metal oxides for supporting Pt metal particles to avoid self-inhibition and to improve catalytic performance. In this work, we used in situ reductions of chloroplatinic acid on commercial Fe3O4 powder to prepare heterogeneous-structured Pt/Fe3O4 catalysts in the solution of ethylene glycol. The heterogeneous Pt/Fe3O4 catalysts achieved a better catalytic performance of CO oxidation compared with the Fe3O4 powder. The temperatures of 50% and 90% CO conversion were achieved above 260°C and 290°C at Pt/Fe3O4, respectively. However, they are accomplished on Fe3O4 at temperatures higher than 310°C. XRD, XPS, and H2-TPR results confirmed that the metallic Pt atoms have a strong synergistic interaction with the Fe3O4 supports. TGA results and transient DRIFTS results proved that the Pt metal particles facilitate the release of lattice oxygen and the formation of oxygen vacancies on Fe3O4. The combined results of O2-TPD and DRIFTS indicated that the activation step of oxygen molecules at surface oxygen vacancies could potentially be the rate-determining step of the catalytic CO oxidation at Pt/Fe3O4 catalysts. The reaction pathway involves a Pt-assisted Mars-van Krevelen (MvK) mechanism.  相似文献   
7.
Organophosphates(OPs) are an integral part of modern agriculture; however, due to overexploitation, OPs pesticides residues are leaching and accumulating in the soil, and groundwater contaminated terrestrial and aquatic food webs. Acute exposure to OPs could produce toxicity in insects, plants, animals, and humans. OPs are known for covalent inhibition of acetylcholinesterase enzyme in pests and terrestrial/aquatic organisms, leading to nervous, respiratory, reproductive, and hepatic abnormaliti...  相似文献   
8.
Straw pellets are widely promoted and expected to be a cleaner alternative fuel to unprocessed crop residues and raw coal in rural China.However,the effectiveness of these dissemination programs is not well evaluated.In this?eld study,emission characteristics of burning straw pellets,raw coal,and unprocessed corn cobs in heating stoves were investigated in a pilot village in Northeast China.Emission measurements covering the whole combustion cycle (ignition,?aming,and smoldering phases) shows th...  相似文献   
9.
James E. Lovelock, famed for his Gaia hypothesis, which views the Earth as a living integrated and interconnected self-regulating system whose equilibrium comes about from complex energy-based interactions and feedback loops, ultimately sustaining life, passed away at the end of July, 2022 at the age of 103. Not only are the adaptive mechanisms of Gaia central to the conversation of environmental homeostasis, they lie at the heart of climate change and global warming. Lovelock is also remembered as the co-inventor of the electron capture detector that eventually allowed for the sensitive detection of chlorofluorocarbons and pesticides. Finally, Lovelock’s free-spirited nature and research independence allow academia to rethink current research’s modus operandi.  相似文献   
10.
在分析兴都库什-喜马拉雅地区生物资源和生物贸易特点基础上,本文就《国际生物多样性公约》框架下的《名古屋议定书》在本地区实施的主要机遇和挑战进行了分析。研究认为,本地区各国在具体执行议定书时面临的困难依然严峻,应该不断在议定书的法律框架下规范遗传资源以及相关传统知识的贸易、使用与共享机制。同时,不断完善法律体系建设,提高全民资源保护意识、建立良好信用制度,提高遗传资源获取和鉴定的科学技术水平。  相似文献   
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