Survey of the occurrence of residues of methyl tertiary butyl ether (MTBE) in Dutch drinking water sources and drinking water

An indicative survey has been carried out in The Netherlands investigating the presence of methyl tertiary butyl ether (MTBE) in drinking water and the corresponding sources. In total, 71 different sites used for the preparation of drinking water in The Netherlands were sampled in two successive seasons in 2001 involving the analysis of 156 samples. (ground water (n = 88), surface water (n = 17), bank filtrate water (n = 6) and drinking water (n = 45)). To combine high sample throughput with high selectivity and sensitivity, off-line purge and trap for sampling and gas chromatography mass spectrometry equipped with an automated thermal desorption sampler (TDS-GC-MS) was selected as the preferred analytical methodology. The developed procedure enabled the analysis of at least 40 samples per day and provided a limit of quantification of 2 ng l(-1). In the first period 63 samples of raw water were analyzed. Concentrations ranged between < 10 ng l(-1) and 420 ng l(-1) with a median concentration below 10 ng l(-1). The second period was focused at the re-sampling of positive locations (MTBE > 10 ng l(-1)) and a few additional drinking water utilities of which both the raw and drinking water of the utilities were analyzed. The median concentration of MTBE in the selected set of drinking water samples was 20 ng l(-1) (n = 45). At one location MTBE was found at a level of 2900 ng l(-1) caused by point source contamination of the ground water (11 900 ng l(-1)). Special attention has been paid to the quality of the results by analyzing all samples in duplicate and the analysis of control samples during each series of analyses.     

The concept of ecological debt: some steps towards an enriched sustainability paradigm

In this paper, we elaborate on the concept of ecological debt. Starting from the enriching environmental justice perspectives, this grass-roots concept has to offer to sustainability discourse, a broad conceptual discussion is presented resulting in a working definition for ecological debt. In elaborating on this definition, we try both to accommodate these enriching perspectives and to offer a more robust conceptualisation that is applicable in international sustainability discourse. Also, a scientifically sound methodology is presented which allows quantifying different aspects of ecological debt. Finally, both the conceptual analysis as well as the quantification method is applied to the case of climate change.     

Modelling the long-term soil response to atmospheric deposition at intensively monitored forest plots in Europe

The dynamic soil chemistry model SMART was applied to 121 intensive forest monitoring plots (mainly located in western and northern Europe) for which both element input (deposition) and element concentrations in the soil solution were available. After calibration of poorly known parameters, the model accurately simulated soil solution concentrations for most plots as indicated by goodness-of-fit measures, although some of the intra-annual variation especially in nitrate and aluminium concentrations could not be reproduced. Model evaluations of two emission-deposition scenarios (current legislation and maximum feasible reductions) for the period 1970-2030 show a strong reduction in sulphate concentrations between 1980 and 2000 in the soil due to the high reductions in sulphur emissions. However, current legislation hardly reduces future nitrogen concentrations, whereas maximum feasible reductions reduces them by more than half. Maximum feasible reductions are also more effective in increasing pH and reducing aluminium concentrations, mostly below ‘critical’ values.     

OBSERVATIONS ON KINEMATIC RESPONSE IN URBAN RUNOFF MODELS1

ABSTRACT: This paper first discusses the results of sensitivity analyses conducted on various parameters of the San Francisco Stormwater Model ta version of WREM) and the Penn State Runoff Model in terms of their impact on outflow hydrographs. The parameters considered within a idealized catchment include: basin shape, imperivous fraction, overland roughness and slope: deterntion depth; infiltration capacity; and hyetograph timing. Second, the results for the hypothetical catchment are extended to the lazzard laboratory surfaces (asphalt, grass, roofing material) as a mean of illustrating the need for changes in model structure, as opposed to continued parameter adjustment Finally the effect of altering the scale of hydraulic representation in the surface runoff and sewer transport calculations are demonstrated for two gaged watersheds in Hamburg, West Germany.     

FEASIBILITY OF INTERBASIN WATER TRANSFER1

ABSTRACT: Interbasin water transfer is one of the most controversial water-resources-planning topics. Local communities, particularly those from which the water is to be taken (donor regions), generate enough opposition to doom many projects to failure. The opposition often arises because planners have traditionally considered excess water a free commodity rather than a marketable resource. To make transfer schemes mutually acceptable to donor and recipient regions, visible benefits must be offered. Agreement must be made on an acceptable purchase price and/or on other benefits such as a substantial amount of low flow augmentation or possibly some degree of flood control on the donor source stream. The hydrologic and economic feasibility of water transfer from the East Susquehanna River basin to the Delaware Reservoir System for supplemental supply to the New York City area was investigated. Nine alternative schemes for diversions up to 400 cfs and compensations in the form of low flow augmentation and/or flood control were considered resulting in unit costs to the recipient region between $90 and $380/mg. If only the minimum state-mandated flow is released to the Susquehanna River, the savings to the water recipients would be sufficient to pay a purchase price of about $21/mg, which would be equivalent to a total amount of $420,000/year for an average export of 100 cfs.     

Fitting a Gamma Distribution Over a Synthetic Unit Hydrograph1

ABSTRACT: Several methods for synthetic unit hydrographs are available in the literature. Most of these methods involve the hand fitting of a curve over a set of a few hydrograph points, which can sometimes be a subjective task. Besides, the user often finds it difficult or simply neglects to adjust the generated unit graph to a runoff volume of one unit (inch, cm, or mm). It is the purpose of this paper to present to the design hydrologist a simple method to fit a smooth gamma distribution over a single point specified by the unit hydrograph peak and the time to peak with a guaranteed unit depth of runoff.