Assessment of soils contamination with veterinary antibiotic residues in Northern Poland using developed MAE-SPE-LC/MS/MS methods

Among the wide range of compounds reaching the soil are the veterinary antimicrobials. Since no regulations regarding acceptable levels of drug concentrations in the environment exist, monitoring tests, particularly concerning soils, are carried out very rarely. This study presents a preliminary assessment of the contamination of agricultural soils in Northern Poland with seven antimicrobial veterinary medicines which has never been carried out before. Veterinary drugs were detected in 54% of the examined soil samples; the most commonly detected drugs were sulfonamides and trimethoprim. The highest indicated concentrations refer to enrofloxacin (57.0 μg kg^?1) and trimethoprim (47.8 μg kg^?1). The presence of these target drugs in the soil environment confirms the need for further monitoring studies. The analytical methods developed in this study are an excellent tool to achieve this goal and allow an estimation of the risk connected with the presence of veterinary antimicrobials in soils.

     

Proposal of new convenient extractant for assessing phytoavailability of heavy metals in contaminated sandy soil

Environmental Science and Pollution Research - The aim of the study was to compare the usefulness of 1 M HCl with aqua regia, EDTA, and CaCl2 for the extraction of phytoavailable forms of...     

Method of Testing the Penetration of Acid Solutions Through Safety Gloves

Because they cause burns that are difficult to heal, acids are dangerous, and steps should be taken to ensure that the human skin does not come into contact with them. For this purpose safety gloves are generally used by workers who have to handle acids. Such gloves need to be tested to ensure that they are acid resistant. Standard EN 374 (European Committee for Standardization [CEN], 1993c) specifies a method of testing the permeation of liquid chemicals, on a molecular level, through glove material, but it may be difficult to ensure the fitness of the joints of a two-compartment cell, when gloves are lined with jersey. To deal with this a simple pH-meter method to test the permeation of acid and alkali solutions through safety gloves has been developed. The permeation of H₂S0₄, HCI, HN0₃, and CH₃COOH through gloves made from neoprene, nitrile, and PVC was tested. This method seems to be simple and economical.     

Empirical Estimation of Virtual Point Source Height Over a Bank of Coke Ovens

This paper addresses an empirical method of assessment of the height of a virtual point source. In order to achieve such assessment, three planes defining the location of a virtual point source in a space are created and formulas describing the geometry of observer’s sight and plume orientation are used. Data for calculations are obtained on a basis of plume photographs. The final position of a virtual emission point is described by a set of its coordinates in the Cartesian coordinate system. Presented method may be applied as a means to verify and validate the existing formulas describing the rise of plume above the stack exit or as a tool enabling acquisition of information for the sake of creating new formulas of this type. The calculation of the location of a virtual point source ascribed to the point emission from the roof of the bank of coke oven is presented and illustrated with photographs which reveal position of plume, adequate planes, axes and characteristic objects.     

Current practice and shortcomings of EIA in Lithuania

The paper provides an overview of EIA system applications and assesses its effectiveness in Lithuania. A combination of archival research and quantitative/qualitative analysis was used to identify the main shortcomings of the EIA process in Lithuania: subjectivity in forecasting environmental effects, insufficient consideration of alternatives, politicisation of the process and incompetence of authorities involved. The research revealed that a thorough knowledge of EIA procedures and legal requirements may be a solution to these problems, especially when the stages related to forecasting the effects and evaluating the results are strictly reserved for recognized experts. The work concludes on the suggestions to involve in EIA process relevant authorities and to increase the competence of EIA practitioners.     

Heavy metal accumulation and distribution in Phragmites australis seedlings tissues originating from natural and urban catchment

The retention of heavy metal (HM) was studied in root and rhizomes (BLG), stems (ST), and leaves (LF) of Phragmites australis (common reed) seedlings collected from different locations, differing in the scale of anthropogenic interference. The analysis includes the reference samples of sediments in uncontaminated lake Garczonki and contaminated roadside ditch in Cieplewo. The concentrations of Zn, Cu, Pb, Cd, Ni, and Cr were analyzed in plant tissues and sediments using the atomic absorption spectrometry and inductively coupled plasma mass spectrometry. The general assessment of sediments collected in the Garczonki lake showed a good environmental status; while in the roadside ditch in Cieplewo, the sediments were considerably polluted with HM. In the first stage of plant growth, all of the analyzed HMs are mainly inhibited by BLG system. The decreasing trend of elements was as follows: BLG > ST > LF. The organs followed different decreasing trends of HM concentration; the trend Zn > Cu > Ni > Cr > Pb > Cd was found in ST and LF for the Garczonki lake seedlings and for BLG and LF for the roadside ditch in Cieplewo seedlings. Zn showed the highest concentration, while Cd the lowest concentration in each of the examined organs. The bioaccumulation factor indicated the higher mobility of HM in seedlings in the Garczonki lake than in the roadside ditch in Cieplewo. The morphological studies suggest the good state and health of seedling from both sites; however, the reduction of root hair surface was observed for the roadside ditch seedlings. The anatomical studies present changes in the size of the nucleus and count of chloroplasts in LF. No reaction on HM contamination sediments in the seedlings from the roadside ditch in Cieplewo in the aerenchyma was noted. Potentially, both types of seedlings can be used to decontaminate environments rich in HM. However, the level of HM absorbed by seedlings (in the first stage of growth) should be considered due to the behavior in the target phytoremediation site.

     

Learning in greenhouse gas emission inventories in terms of uncertainty improvement over time

Mitigation and Adaptation Strategies for Global Change - This paper addresses the problem of learning in greenhouse gas (GHG) emission inventories understood as reductions in uncertainty, i.e.,...     

EU Directive, ICNIRP guidelines and Polish legislation on electromagnetic fields.

This review describes the general provisions of and the philosophy behind European Directive 2004/40/EC and ICNIRP (International Commission on Non-Ionizing Radiation Protection) guidelines. As an example of national legislation on the protection of workers against excessive electromagnetic field exposure, regulations established in Poland are summarized. The problems of a practical implementation of the Directive's provisions are discussed.     

Health risk assessment of occupational exposure to a magnetic field from magnetic resonance imaging devices.

Health care staff who operate magnetic resonance imaging (MRI) devices are exposed to a static magnetic field of significant spatial heterogenity always produced by MRI magnets during the whole shift. They can also be exposed to pulses of a time-varying magnetic field (gradient field) present only during patients' examinations. The level of the workers' exposure depends both on the type of the magnet and on the ergonomic design of each MRI device. The paper presents methods used for measuring and assessing workers' exposure. It also discusses the results of inspection measurements carried out next to approximately 20 MRI devices of approximately 0.2-2.0 T. The presented characteristic and overview of the variability of workers' exposure to a variety of MRI devices supports the need for data on monitoring occupational exposure to MRI. International exposure assessment standards and guidelines (International Commission on Non-Ionizing Radiation Protection [ICNIRP], Institute of Electrical and Electronics Engineers [IEEE], American Conference of Governmental and Industrial Hygienists [ACGIH], European Commission directive), and those established in Poland are also compared.