A thermal/optical carbon analyzer (TOA), normally used for quantification of organic carbon (OC) and elemental carbon (EC) in PM2.5 (fine particulate matter) speciation networks, was adapted to direct thermally evolved gases to an electron impact quadrupole mass spectrometer (QMS), creating a TOA-QMS. This approach produces spectra similar to those obtained by the Aerodyne aerosol mass spectrometer (AMS), but the ratios of the mass to charge (m/z) signals differ and must be remeasured using laboratory-generated standards. Linear relationships are found between TOA-QMS signals and ammonium (NH4+), nitrate (NO3?), and sulfate (SO42-) standards. For ambient samples, however, positive deviations are found for SO42-, compensated by negative deviations for NO3?, at higher concentrations. This indicates the utility of mixed-compound standards for calibration or separate calibration curves for low and high ion concentrations. The sum of the QMS signals across all m/z after removal of the NH4+, NO3?, and SO42- signals was highly correlated with the carbon content of oxalic acid (C?H?O?) standards. For ambient samples, the OC derived from the TOA-QMS method was the same as the OC derived from the standard IMPROVE_A TOA method. This method has the potential to reduce complexity and costs for speciation networks, especially for highly polluted urban areas such as those in Asia and Africa.Implications: Ammonium, nitrate, and sulfate can be quantified by the same thermal evolution analysis applied to organic and elemental carbon. This holds the potential to replace multiple parallel filter samples and separate laboratory analyses with a single filter and a single analysis to account for a large portion of the PM2.5 mass concentration. 相似文献
The rapid development of technology has made it easier to distribute products directly, and many enterprises excel at executing a multi-channel strategy to distribute products. The introduction of direct channel adds a new competition dimension to the enterprises. This paper considers three market channel structures: R-Channel, D-Channel and H-Channel. In R-Channel, both new products and remanufactured products are sold through a retailer. In D-Channel, new products are sold through retailers and remanufactured products are sold directly to consumers. In H-Channel, new products are sold through retailers, while remanufactured products through dual channel. Using the game theory, we obtain and analyse the equilibrium prices, market demands and the profits gain under these three settings. At the same time, the influence of consumers’ willingness to pay on the environment performance is researched. Our results show that the manufacturer prefers H-Channel. By introducing the direct channel the manufacturer is always economically better off, but it is not for the retailer. The numerical simulation also confirms the theoretical analysis and shows that H-Channel has advantages of economic benefit and environmental performance. It is feasible for practical application. 相似文献
In this study, farmland and mining ecotypes of Solanum photeinocarpum (a potential cadmium (Cd) hyperaccumulator plant) were reciprocally hybridized each other, and the Cd accumulation characteristics of the F1 hybrids were studied. In pot experiments, higher biomasses and Cd extraction abilities were found for two S. photeinocarpum F1 hybrids than for the parents, but the Cd contents in various organs were lower in the hybrids than the parents. However, the differences between the Cd contents in the two hybrids were not significant. The antioxidant enzyme (superoxide dismutase and peroxidase) activities were higher for the S. photeinocarpum F1 hybrids than the parents. Less DNA methylation was found in the hybrids than the parents because more demethylation occurred in the hybrids than the parents. The biomass, Cd content, and Cd extraction ability effects in field experiments were similar to the effects in the pot experiments. It was concluded that reciprocally hybridizing different S. photeinocarpum ecotypes improved the ability of S. photeinocarpum to be used to phytoremediate contaminated land.