Trace metal contents of the pacific oyster (Crassostrea gigas) purchased from markets in Hong Kong

Arsenic, cadmium, chromium, and copper concentrations of the Pacific oyster,Crassostrea gigas, purchased from four different markets were determined in this project. In general, gill tissue had the highest proportion of metal contents (34%–67%) when compared with other tissue parts (mantle, viscera, and adductor muscle), except for arsenic, which showed the highest level in adductor muscle (44%). Smaller oysters (longitudinal length of soft body part less than 6 cm) had higher metal levels than larger ones (longitudinal length of soft body part more than 6 cm), except copper. None of the four metals examined showed an obvious seasonal trend, although cadmium levels seemed to be higher in autumn and winter months. Arsenic, cadmium, and copper levels in oysters purchased from different markets and different months obtained in the present study were higher when compared with past reports. Cadmium levels, as high as 10.98 mg/kg (dry weight basis) have been obtained. This approaches the safety limit that may be hazardous to human health. Continual monitoring of cadmium and other trace metals of toxicological significance to man in Hong Kong seafood is recommended.     

Influence of flue-gas desulfurization systems on coal combustion by-product quality at kentucky power stations burning high-sulfur coal

Two Kentucky power plants burning similar blends of high-sulfur western Kentucky and southern Indiana coal provide a unique opportunity to examine the variations in coal combustion by-products due to differences in the method of wet flue-gas desulfurization (FGD). One plant employed carbide lime-based scrubbing for two units and a dual-alkali process for the third unit. The second plant employed a Mississippian limestone from Kentucky for all four units. This study provides an example of optical and SEM petrographic techniques, supplemented by chemical analyses, applied to the study of, at least from the geologic perspective, non-traditional materials. The coal sources comprise a blend of high volatile C and B bituminous, high vitrinite (85–90%, mmf), high-sulfur (> 3%, dry) coals. The fly ash is dominated by glassy phases (70–80%) with about 5–10% spinel (predominately magnetite), 3–10% quartz, and 4–10% isotropic coke comprising the remaining portion of the ash. SEM observations indicate that the glassy particles exhibit a bimodal size distribution with sub-micron glass spheres and a population of larger (several 10s of microns) spheres. The bottom ash has higher proportions of spinels and mullite, with negligible carbon forms, compared to the fly ash from the same units. Fly ashes were observed to be lower in Fe and higher in Al, Si, and S compared to the bottom ashes. Carbide lime, a by-product of acetylene manufacture, soda ash, and limestone were the reagents used in the flue-gas desulfurization processes. The primary FGD by-product is a calcium sulfite slurry which is vacuum filtered and mixed with fly ash and, usually, lime, to form a stable product for disposal. The FGD by-products have some potential, as yet unrealized, for utilization.     

Germination,Growth, and Nodulation of Sesbania rostrata Grown in Pb/Zn Mine Tailings

Sesbania rostrata in pure and amended Pb/Zn tailings. About 90% of seeds of S. rostrata germinated in pure Pb/Zn tailings, which contained high concentrations of Pb, Zn, Cu, and Cd. Although seedling growth suffered from the adverse environment of Pb/Zn tailings, they became established on tailings stands, in the greenhouse, as well as on the actual tailings dam, and completed their life cycle in 4 months. Dry matter production and nitrogen accumulation was 3200 kg/ha and 69.4 kg/ha, respectively in the actual tailings dam. Applying inorganic fertilizer to Pb/Zn tailings led to no obvious improvement in growth and nodulation of S. rostrata, while tailings amended by river sediment or domestic refuse rich in organic matter improved the growth and nodulation of the species. Azorhizobium caulinodans survived and formed N-fixing stem and root nodules in S. rostrata grown in pure Pb/Zn tailings with a nodule biomass exceeding 300 mg fresh matter per plant.     

Reusability of sewage sludge in clay bricks

Bricks produced from sewage sludge in different compositions were investigated. Results of the tests indicated that the sludge proportion is a key factor in determining the brick quality. Increasing the sludge content results in a decrease in brick shrinkage, bulk density, and compressive strength. Brick weight loss on ignition was mainly due to the contribution of the contained organic matter from the sludge being burnt off during the firing process, as well as inorganic substances found in both clay and sludge. The physical, mechanical, and chemical properties of the bricks that were supplemented with various proportions of dried sludge from 10 to 40wt% and generally complied with the General Specification for Brick as per the Malaysian Standard MS 7.6:1972, which dictates the requirements for clay bricks used in walling in general. A standard leaching test method also showed that the leaching of metals from the bricks is very low.     

Reclamation of wastes contaminated by copper,lead, and zinc

Waste materials containing toxic levels of copper, lead, and zinc, such as mine and smelter wastes, present difficult conditions for the establishment of vegetation. This article reviews the many attempts which have been made to reclaim these wastes. Inert wastes from mining and quarrying operations, such as slate quarry waste and certain colliery shales, seem to be good materials for reclaiming wastes contaminated by copper, lead, and zinc. Organic wastes, such as sewage sludge and domestic refuse, may provide only a temporary visual improvement and stabilization of the toxic materials.Nontolerant plant materials may often be planted directly on modern waste materials, which are less toxic than they were in the past. However, tolerant plant materials are needed for revegetating waste materials produced by early and more primitive extraction methods.     

Use of Microbial Community to Evaluate Performance of a Wetland System in Treating Pb/Zn Mine Drainage

The performance of a wetland system in treating lead (Pb)/zinc (Zn) mine drainage was evaluated by using the polyurethane foam unit (PFU) microbial community (method), which has been adopted by China as a standardized procedure for monitoring water quality. The wetland system consisted of four cells with three dominant plants: Typha latifolia, Phragmites australis and Paspalum distichum. Physicochemical characteristics [pH, EC, content of total suspended solid (TSS) and metals (Pb, Zn, Cd, and Cu)] and PFU microbial community in water samples had been investigated from seven sampling sites. The results indicated that the concentrations of Pb, Zn, Cd, Cu, and TSS in the mine drainage were gradually reduced from the inlet to the outlet of the wetland system and 99%, 98%, 75%, 83%, and 68% of these metals and TSS respectively, had been reduced in concentration after the drainage passed through the wetland system. A total of 105 protozoan species were identified, the number of protozoa species and the diversity index (DI) gradually increased, while the heterotrophic index (HI) gradually decreased from the inlet to the outlet of the wetland system. The results indicated that DI, HI, and total number species of protozoa could be used as biological indicators indicating the improvement of water quality.     

Effects of landfill gas on subtropical woody plants

An account is given of the influence of landfill gas on tree growth in the field at Gin Drinkers' Bay (GDB) landfill, Hong Kong, and in the laboratory. Ten species (Acacia confusa, Albizzia lebbek, Aporusa chinensis, Bombax malabaricum, Castanopsis fissa, Liquidambar formosana, Litsea glutinosa, Machilus breviflora, Pinus elliottii, andTristania conferta), belonging to eight families, were transplanted to two sites, one with a high concentration of landfill gas in the cover soil (high-gas site, HGS) and the other with a relatively low concentration of gas (low-gas site, LGS). Apart from the gaseous composition, the general soil properties were similar. A strong negative correlation between tree growth and landfill gas concentration was observed. A laboratory study using the simulated landfill gas to fumigate seedlings of the above species showed that the adventitious root growth ofAporusa chinensis, Bombax malabaricum, Machilus breviflora, andTristania confera was stimulated by the gas, with shallow root systems being induced.Acacia confusa, Albizzia lebbek, andLitsea glutinosa were gas-tolerant, while root growth ofCastanopsis fissa, Liquidambar formosana, andPinus elliottii was inhibited. In most cases, shoot growth was not affected, exceptions beingBombax malabaricum, Liquidambar formosana, andTristania conferta, where stunted growth and/or reduced foliation was observed. A very high CO₂ concentration in cover soil limits the depth of the root system. Trees with a shallow root system become very susceptible to water stress. The effects of low O₂ concentration in soil are less important than the effects of high CO₂ concentration.Acacia confusa, Albizzia lebbek, andTristania conferta are suited for growth on subtropical completed landfills mainly due to their gas tolerance and/or drought tolerance.     

Sludge-grown algae for culturing aquatic organisms: Part II. Sludge-grown algae as feeds for aquatic organisms

This project investigated the feasibility of using sewage sludge to culture microalgae (Chlorella-HKBU) and their subsequent usage as feeds for rearing different organisms. Part II of the project evaluated the results of applying the sludge-grown algae to feedOreochromis mossambicus (fish),Macrobrachium hainenese (shrimp), andMoina macrocopa (cladocera). In general, the yields of the cultivated organisms were unsatisfactory when they were fed the sludge-grown algae directly. The body weights ofO. mossambicus andM. macrocopa dropped 21% and 37%, respectively, although there was a slight increase (4.4%) inM. hainenese. However, when feeding the algal-fed cladocerans to fish and shrimp, the body weights of the fish and shrimp were increased 7% and 11% accordingly. Protein contents of the cultivated organisms were comparable to the control diet, although they contained a rather high amount of heavy metals. When comparing absolute heavy metal contents in the cultivated organisms, the following order was observed: alga > cladocera > shrimp, fish > sludge extracts. Bioelimination of heavy metals may account for the decreasing heavy metal concentrations in higher trophic organisms.