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Yamaguchi N Nakano M Takamatsu R Tanida H 《Journal of environmental radioactivity》2010,101(6):451-9983
The transformation of inorganic iodine (I− and IO3−) incubated in soils with varying amounts of organic matter (Andosols from the surface layer of an upland field and forest, as well as Acrisols from surface and subsurface layers of an upland field) was investigated by using the iodine K-edge X-ray absorption near-edge structure (XANES). After 60 d of reaction, both I− and IO3− were transformed into organoiodine in surface soils containing sufficient amounts of organic matter, whereas IO3− remained unchanged in the subsurface soil of Acrisols with low organic matter contents. Transformation of IO3− into organoiodine was not retarded when the microbial activity in soil was reduced by γ-ray irradiation, suggesting that microbial activity was not essential for the transformation of inorganic iodine into organoiodine. Soil organic matter has the ability to transform inorganic iodine into organoiodine. 相似文献
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Iwahana Yuki Ohbuchi Atsushi Koike Yuya Kitano Masaru Nakamura Toshihiro 《Journal of Material Cycles and Waste Management》2017,19(1):226-234
Journal of Material Cycles and Waste Management - The radioactive nuclides in the incinerator fly ashes from municipal solid waste sampled in June 2006 were analyzed with γ-ray spectrometry.... 相似文献
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Hajime Yasuda Tohru Kamo Mariko Adachi Satoshi Sajima Hideki Nakagome 《Journal of Material Cycles and Waste Management》2010,12(2):123-127
The rapid hydropyrolysis of model compounds for epoxy resin oligomers and biomass tar was carried out in a hydrogen atmosphere
at 1073 K and 973 K. The assumed oligomers were partially pyrolyzed epoxy resin with biomass tar as solvent for the resin.
The product distributions obtained from rapid hydropyrolysis of phenol and bisphenol-A are shown. We also discuss the effects
of reaction temperature and hydrogen partial pressure on the product yield. In particular, more phenol was produced from bisphenol-A
at 973 K than at 1073 K. The yield of methane, which was the final hydropyrolysis product, increased with increasing hydrogen
partial pressure, whereas benzene and phenol were believed to behave as intermediate products in the hydropyrolysis reaction.
The results suggest that phenol could be obtained with high selectivity from tar by optimizing the reaction conditions. 相似文献
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To mitigate global warming caused by burning fossil fuels, a renewable energy source available in large quantity is urgently required. We are proposing large-scale photobiological H(2) production by mariculture-raised cyanobacteria where the microbes capture part of the huge amount of solar energy received on earth's surface and use water as the source of electrons to reduce protons. The H(2) production system is based on photosynthetic and nitrogenase activities of cyanobacteria, using uptake hydrogenase mutants that can accumulate H(2) for extended periods even in the presence of evolved O(2). This review summarizes our efforts to improve the rate of photobiological H(2) production through genetic engineering. The challenges yet to be overcome to further increase the conversion efficiency of solar energy to H(2) also are discussed. 相似文献
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In this study, we analyzed the sustainability and determinant factors of waste reduction through variable charging schemes.
We drew three main conclusions from the study. (1) Waste reduction was achieved by variable charging and was sustained over
an average of at least 10 years. The results regarding the sustainability of the price effect were inconclusive. (2) The main
factors contributing to the combustible waste reduction achieved through variable charging were two-tier pricing and the price
of waste bags. The effect of two-tier pricing programs was positive. (3) Waste paper recycling and variable charging reinforce
each other to promote waste reduction.
Received: September 3, 2001 / Accepted: January 13, 2002 相似文献
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A badge-type personal sampler was developed for measuring personal exposure to nitrogen dioxide (NO2). An absorbent sheet containing triethanolamine (TEA) solution absorbed NO2 which diffused through five layers of hydrophobic fiber filter. Wind effects on absorption rate were suppressed by these filter layers. NO2 was measured by the sampler with a sensitivity of 124.8 μg h/m3 (66 ppb h) and an accuracy of within ± 20%. It could be used for measuring personal exposure to NO2 without interfering with the wearer's daily activities. Nitric oxide (NO) could be measured after a small modification to the sampler provided oxidation ability to the layers of diffusion filter. Three layers of hydrophobic fiber filter were replaced by 12 layers of glass fiber filter containing chromium trioxide solution. NO was oxidized to NO2 in the oxidation layers and absorbed by the absorbent sheet together with the coexisting NO2. Sensitivity and accuracy of the sampler for NO were nearly equal to that for NO2. 相似文献
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Is a voluntary approach an effective environmental policy instrument?: A case for environmental management systems 总被引:6,自引:0,他引:6
Toshi H. Arimura Akira Hibiki Hajime Katayama 《Journal of Environmental Economics and Management》2008,55(3):281-295
Using Japanese facility-level data from an OECD survey, we estimate the effects of implementation of ISO14001 and publication of environmental reports on the facilities’ environmental performance. While most previous studies focused on an index of emissions toxicity, this study examines three areas of impacts, none of which have been explored in the literature: natural resource use, solid waste generation, and wastewater effluent. The study is also unique in that the effectiveness of ISO14001 is considered in relation to environmental regulations. Our findings are summarized as follows. First, both ISO14001 and report publication help reduce all three impacts; the former appears more effective in all areas except wastewater. Second, environmental regulations do not weaken the effect of ISO14001. Third, assistance programs offered by local governments—a voluntary approach—promote facilities’ adoption of ISO14001. These findings suggest that governments can use command-and-control and voluntary approaches concurrently. 相似文献
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Dioxin concentrations from municipal waste incinerators in Japan and elsewhere often show low concentrations that comply with legal limits (in this paper, the term "dioxin" designates WHO-TEQ: PCDD/Fs+dioxin-like PCB). However, such data is usually generated under normal steady state operational conditions, and there has been little investigation of releases occurring during startup and shutdown. It is important, therefore, to ascertain quantitatively emissions in an unsteady state (startup and shutdown) in order to correctly evaluate the relationship between emissions from a facility and the surrounding environment. The present study aimed to examine dioxin emissions of a continuously operated incinerator at startup and shutdown, and estimating the time period of greatest emission, and the processes causing dioxin generation. The startup process was divided into five stages and the shutdown into two; at each stage, dioxins in the flue gas were measured at the boiler outlet and the stack. From the concentration of dioxins and the flue gas volume at each stage, the amount of dioxins at startup and shutdown were calculated, and these were compared with that under steady state conditions. Dioxin concentration at the stack under steady state conditions was a very low level, while those at startup and shutdown were higher. In the case where dioxin concentration under a steady state is a low level like in this study, it is indicated that the total annual dioxin emission from a facility could be attributed to the startup periods. 相似文献