Ecological risk and accessibility analysis to assess the impact of roads under Habitats Directive

We propose a method for the appropriate assessment of adverse effects of roads in compliance with the European Union Habitats Directive. The method incorporates an analysis of ecological risk of edge effects by the proposed roads with the related increase in accessibility. The method was tested on 30 km of planned forest roads inside an 8,000-ha reserve included in two Natura 2000 sites. As a result, the cumulative effect of 19 road segments was judged as not significantly affecting the integrity of the sites, although they made accessible an extra 314 ha. On the basis of the accessibility calculation, 20 ha of land were set aside from forest exploitation as a mandatory mitigation measure. The method objectively determined the cumulative adverse effects, enabled comparison of plan revisions and alternatives and proved to measure direct and indirect significant effects with a realistic effort in terms of field survey and geographic information system processing.     

Effects of ammonia from livestock farming on lichen photosynthesis

This study investigated if atmospheric ammonia (NH₃) pollution around a sheep farm influences the photosynthetic performance of the lichens Evernia prunastri and Pseudevernia furfuracea. Thalli of both species were transplanted for up to 30 days in a semi-arid region (Crete, Greece), at sites with concentrations of atmospheric ammonia of ca. 60 μg/m³ (at a sheep farm), ca. 15 μg/m³ (60 m from the sheep farm) and ca. 2 μg/m³ (a remote area 5 km away). Lichen photosynthesis was analysed by the chlorophyll a fluorescence emission to identify targets of ammonia pollution. The results indicated that the photosystem II of the two lichens exposed to NH₃ is susceptible to this pollutant in the gas-phase. The parameter PI_ABS, a global index of photosynthetic performance that combines in a single expression the three functional steps of the photosynthetic activity (light absorption, excitation energy trapping, and conversion of excitation energy to electron transport) was much more sensitive to NH₃ than the F_V/F_M ratio, one of the most commonly used stress indicators.     

Pesticide removal from waste spray-tank water by organoclay adsorption after field application: an approach for a formulation of cyprodinil containing antifoaming/defoaming agents

Purpose  

Many reports on purification of water containing pesticides are based on studies using unformulated active ingredients. However, most commercial formulations contain additives/adjuvants or are manufactured using microencapsulation which may influence the purification process. Therefore, the main objective of this work was to develop and test a pilot scheme for decontaminating water containing pesticides formulated with antifoaming/defoaming agents.     

Comparative study based on sediment characteristics and macrobenthic communities in two Italian lagoons

The aims of this study were to analyse sediment characteristics and macrobenthic assemblages in two very close Italian coastal lagoons (Lesina and Varano) and to assess the different behaviour between the two basins and the relationship between sediment matrix and benthic organisms within and between the two lagoons. The comparative study was performed in July 2007 at 13 sampling sites in Lesina lagoon and 15 sites in Varano basin for sediment grain size, total organic carbon (TOC), total nitrogen (TN), total phosphorus (TP) and macrobenthic structure analyses. Both lagoons were generally dominated by fine-grained sediments (clay and silt components). The average contents of TOC and TN measured in Lesina was higher than in Varano (3.31% vs 2.52% for TOC and 5,200 μg·g^???1 vs 3,713 μg·g^???1 for TN); in contrast, the TP was lower (540 μg·g^???1 vs 620 μg·g^???1). Based on macrobenthic community patterns, the central zone in Varano lagoon and the eastern area in Lesina lagoon were characterised by the lowest abundance (168.7 ind·m^???2 and 503.2 ind·m^???2, respectively) and by the lowest number of species, as highlighted by the diversity indices (Shannon–Wiener, H ^′ range was 0.47–1.45 for Lesina and 0.00–1.68 for Varano; Margalef species richness, d range was 0.00–1.67 for Lesina lagoon and 0.00–2.38 for Varano basin). Ordination diagrams suggested an influence of marine and freshwater inputs on the sediment distribution in Varano lagoon and on macrobenthic assemblages in Lesina lagoon.     

Surface retention and photochemical reactivity of the diphenylether herbicide oxyfluorfen

The photochemical behavior of oxyfluorfen [2-chloro-1-(3-etoxy-4-nitrophenoxy)-4-(trifluoromethyl) benzene] on two Greek soils was investigated. Soils were sampled from Nea Malgara and Preveza regions, characterized by a different organic matter content. Soils were spiked with the diphenyl-ether herbicide and irradiation experiments were performed either in the laboratory with a solar simulator (xenon lamp) or outside, under natural sunlight irradiation; other soil samples were kept in the dark to control the retention reaction. Kinetic parameters of both retention and photochemical reactions were calculated using zero-, first- and second- (Langmuir-Hinshelwood) order equations, and best fit was checked through statistical analysis. The soil behaviors were qualitatively similar but quantitatively different, with the soil sampled from the Nea Malgara region much more sorbent as compared with Preveza soil. All studied reactions followed second-order kinetics and photochemical reactions were influenced by retaining capability of the soils. The contributions of the photochemical processes to the global dissipation rates were also calculated. Two main metabolites were identified as 2-chloro-1-(3-ethoxy-4-hydroxyphenoxy)-4-(trifluoromethyl)benzene and 2-chloro-1- (3-hydroxy-4-nitrophenoxy)-4-(trifluoromethyl)benzene.     

Geomorphological evolution and environmental reclamation of Fusaro Lagoon (Campania Province, southern Italy)

Analysis of morphological, geological and environmental characteristics of the Fusaro Lagoon has shown the present degraded condition of the lagoon and the perilagoon area. The lagoon developed during the mid-Holocene within a wide marine bay confined between the coastal volcanic structures of Mt. Cuma to the north and Torregaveta to the south in the western part of the Phlegrean Fields. Subsequently, the bay was gradually filled with pyroclastic materials from phlegrean eruptive vents and sediments carried by the rivers Volturno and Clanis, thus, creating an open lagoon. It then evolved into a partially closed lagoon due to the formation of a continuous littoral spit during the late Holocene, probably wider than the present-day one and surrounded by marshlands. Finally, the total closure of the lagoon took place in the Graeco-Roman period, following the stabilization of the dune ridge, and it assumed a shape similar to present-day one only towards the end of the 18th century.Between the Roman period and 1941, three lagoon channels were opened in order to avoid the frequent environmental crises which continue to affect, although for different reasons, this salt-water basin. The basin has been exploited for more than 2000 years not only for mollusc culture and pisciculture, but also for the maceration of hemp and flax. In the 1980s, in order to reduce the effects of the environmental crises, dredging of the lagoon bottom has been carried out, altering the hydrogeological equilibrium and that of the ecosystem. Over the past 30 years, the supply of raw sewage of domestic, agricultural and industrial origin has ensured the presence of a high concentration of pollutants, including heavy metals.On the basis of the data obtained and in order to restore this sensitive transitional environment, eco-compatible interventions are proposed which aim at morphological and hydrologic resettlement, abatement of pollutants on the bottom of the basin, reintroduction of endemic molluscs, together with monitoring the quality of sediments and both sea-lagoon waters and groundwater.