Dry reforming of methane to syngas: a potential alternative process for value added chemicals—a techno-economic perspective

During the past decade, there has been increasing global concern over the rise of anthropogenic CO₂ emission into the Earth’s atmosphere (J Air Waste Manage Assoc 53:645–715, 2003). The utilization of CO₂ to produce any valuable product is need of the hour. The production of syngas from CO₂ and CH₄ seems to be one of the promising alternatives in terms of industrial utilization, as it offers several advantages: (a) mitigation of CO₂, (b) transformation of natural gas and CO₂ into valuable syngas, and (c) producing syngas with H₂/CO ratio 1 which may further be used for the production of valuable petrochemicals (J Air Waste Manage Assoc 53:645–715, 2003). A conceptual design for the production of synthesis gas by dry reforming of methane is presented here. An economic assessment of this process with an integrated methanol production section as a case was conceptualized and compared with the conventional steam methane reforming route to produce methanol. The economic study indicated that dry reforming of natural gas/methane is a competitive process with lower operating and capital costs in comparison with steam reforming assuming negligible cost of CO₂ import.     

A survey-based evaluation of community-based co-management of forest resources: a case study of Baishuijiang National Natural Reserve in China

Community-based co-management (CBCM) mechanisms for forest management have matured through the development of new economic analysis and common property theory. However, while many local CBCM mechanisms have been initiated in Chinese Natural Reserves, there are few objective, data-based evaluations of whether these mechanisms improve forest conservation and local livelihoods. This research uses Baishuijiang National Natural Reserve (BNNR) as a study case to evaluate China’s current CBCM mechanisms. The evaluation is based mainly on three criteria: efficiency, equality and sustainability of project operation. Survey data indicate that local CBCM mechanisms provide a wide-participation platform for local villagers, associated administration managers, research institutions and NGOs to join in forest resource protection work while improving local livelihood. CBCM projects have also facilitated a reduction in forest resource dependency, the improvement of household income and encouragement of local people to participate in forest resource protection. Our analysis suggests that most CBCM organizations have made progress in efficiency, equity and sustainability. However, further study should focus on how to deal with the lingering problems of inequity in responsibility and rights among CBCM committee members, poor distribution of benefits, insufficient program-design and management expertise, faulty information dissemination, and insufficient capital investment.     

Oxidative stress response in dye degrading bacterium Lysinibacillus sp. RGS exposed to Reactive Orange 16, degradation of RO16 and evaluation of toxicity

Lysinibacillus sp. RGS degrades sulfonated azo dye Reactive Orange 16 (RO16) efficiently. Superoxide dismutase and catalase activity were tested to study the response of Lysinibacillus sp. RGS to the oxidative stress generated by RO16. The results demonstrated that oxidative stress enzymes not only protect the cell from oxidative stress but also has a probable role in decolorization along with an involvement of oxidoreductive enzymes. Formation of three different metabolites after degradation of RO16 has been confirmed by GC-MS analysis. FTIR analysis verified the degradation of functional groups of RO16, and HPTLC confirmed the removal of auxochrome group from the RO16 after degradation. Toxicity studies confirmed the genotoxic, cytotoxic, and phytotoxic nature of RO16 and the formation of less toxic products after the treatment of Lysinibacillus sp. RGS. Therefore, Lysinibacillus sp. RGS has a better perspective of bioremediation for textile wastewater treatment.     

Risk-based prediction of metal toxicity in sediment and impact on human health due to consumption of seafood (Saccostrea cucullata) found in two highly industrialised coastal estuarine regions of Eastern India: a food safety issue

Estuarine ecosystems of the Bay of Bengal, India, are considered as the most productive environment, which have been persistently threatened by substantial anthropogenic activity. This study aims to investigate the metal contamination in the sediment of two estuaries and possible biomagnifications in the indigenous edible oyster Saccostrea cucullata and related health hazards due to its consumption. The accumulative ecological risks indicated that the sediment is moderate to strongly contaminated with cadmium and lead. The sediment pollution index and pollution load index suggested that the sediment possesses a little ecological stress on the exposed flora and fauna. The statistical interpretation highlights the most metals which have a similar source of origin and are bound to the finer fractions of the sediment, except nickel. Bioaccumulation of sediment-associated Cu and Zn in oyster reflects their potential biomagnifications through aquatic food chain. HPI range was below the critical limit of safe human consumption. The non-carcinogenic (THQ) and carcinogenic (CR) health hazards were estimated from the PTDI provided by USEPA. Except Cr, Hg and Zn, the THQ of all other metals was > 1 suggesting detrimental non-carcinogenic health effects on humans. The TCR of Cr and Cd above safety limit indicates the exposed population might be under severe carcinogenic threat due to those metals.

     

Study of two species prey-predator model in imprecise environment with MSY policy under different harvesting scenario

Parameters involve in various ecological models are mostly uncertain due to ever changing characteristic of nature. This article, deals with a basic predator–prey model where ecological parameters are considered as parametric-functional nature of interval numbers. The dynamical behaviors of the model system have been discussed in the imprecise environment. Moreover, the concept of maximum sustainable yield (MSY) has been incorporated in the model system under imprecise environment, and MSY policies under different harvesting scenarios have been discussed. Finally all the analytical findings are testified through extensive numerical simulations and the article ended with a conclusion.

     

A Power Law Model for River Flow Velocity in Iowa Basins

This study explores power law relationships to estimate water flow velocity as a function of discharge and drainage area across river networks. We test the model using empirical data from 214 United States (U.S.) Geological Survey gauging stations distributed over the state of Iowa in the U.S. The empirical data are the measurements of the mean cross‐sectional velocity and concurrent discharge. The data are used to estimate parameters for a state‐wide model and to test for spatial variability for 15 large river basins contained within the state. Spatial differences among the basins are small but some parameters significantly differ from the state‐wide model. Using individual station data, the authors also explore a simpler power law model that disregards dependence on the drainage area. Overall, the study shows that including drainage area improves the model. Our study provides parameter values that can be directly incorporated into a regional scale routing model, and provides a framework for developing flow velocity models for hydraulically similar rivers in the U.S. and the world.     

Role of GSH in the amelioration of chromium-induced membrane damage

Membrane damage is one of the important consequences of chromium (Cr), an environmental toxicant, induced cytotoxicity. Reduced glutathione (GSH), a membrane protectant may be used to reduce the Cr-induced membrane damage. In the present study, the impact of Cr in presence and absence of GSH was studied on plasma membrane of the liver and kidneys in male Wistar rats. Significant increases in membrane cholesterol levels as well as significant decreases in membrane phospholipid levels in Cr exposed (0.8 mg per 100 g body weight, i.p., for 28 days) animals suggest structural alterations in both the liver and kidney plasma membranes. Alkaline phosphatase (ALP), total ATPase, and Na⁺–K⁺–ATPase activities of plasma membrane were significantly decreased in both the liver and kidneys after Cr treatment. This treatment also produced significant weight loss and increased Cr content in the liver and kidneys. However, GSH (8 mg per 100g body weight, i.p., daily at an interval of 6 h after injection of Cr for a period of 28 days) supplementation restored alterations induced by Cr in plasma membrane of both the liver and kidneys but was not able to eliminate the deposited Cr from the liver and kidney tissues.     

Immunoprotective effect of curcumin on cypermethrin-induced toxicity in rats

Immunotoxicological effects of cypermethrin and their reversal by curcumin following oral administration were evaluated in rats. Mature male Wistar rats were orally administered cypermethrin (25?mg?kg^?1 body wt), curcumin (100?mg?kg^?1 body wt) or both daily for 4 weeks. At the end of fourth week, hematological, serum biochemical, and immunological parameters were studied. Subchronic exposure to cypermethrin significantly reduced body weight, total leukocyte count, lymphocyte count, serum total protein, serum albumin, serum globulin, antibody titer against sheep red blood cells, and cell-mediated immunity. Concomitant curcumin administration restored the changes in the body weight, hematological parameters, and serum biochemical indices and significantly increased the antibody titer, and cell mediated immunity. These results suggest that concurrent curcumin treatment has a beneficial role in mitigating immunotoxicological and other adverse effects of cypermethrin.