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1.
Environmental Science and Pollution Research - There has been alarming depletion of manganese (Mn) reserves owing to the ongoing extensive mining operations for catering the massive industrial...  相似文献   
2.
In September 2015, the Sustainable Development Goals (SDGs) were endorsed by the United Nations and adopted by all 193 Member States. The SDGs integrate the 5P’s: People, Planet, Prosperity, Peace, and Partnership and clearly stress the need for all stakeholders to collaborate to create a sustainable world. Most importantly, the SDGs appeal to the central and diverse role that the business sector can play to deliver on the SDGs. This paper provides an analysis of inclusive business (IB) models as market-based solutions to contribute to the achievement of the SDGs and benefit those at the Base of the Pyramid (BoP). We investigate the IB models and their social impact in 20 organizations from emerging economies across five different sectors. The findings should help increase the uptake and scale of quality IB models and practices among the private sector, development communities, and governments to promote inclusive economic growth and social impact.  相似文献   
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The risk of cancer due to PCB exposure in humans is highly debated. In eastern Slovakia, high exposure of the population to organochlorines (especially PCBs) was associated with various disease and disorder pathways, viz., endocrine disruption, metabolic disorder & diabetes, and cancer, thereby disturbing several cellular processes, including protein synthesis, stress response, and apoptosis. We have evaluated a Slovak cohort (45-month children, at lower and higher levels of PCB exposure from the environment) for disease and disorder development to develop early disease cancer biomarkers that could shed new light on possible mechanisms for the genesis of cancers under such chemical exposures, and identify potential avenues for prevention.

Microarray studies of global gene expression were conducted from the 45-month-old children on the Affymetrix platform followed by Ingenuity Pathway Analysis (IPA®) to associate the affected genes with their mechanistic pathways. High-throughput qRT-PCR TaqMan low-density array (TLDA) was performed to further validate the selected genes on the whole blood cells of the most highly exposed children from the study cohort (n = 71).

TP53, MYC, BCL2, and LRP12 differential gene expressions suggested strong relationships between potential future tumor promotion and PCB exposure in Slovak children. The IPA analysis further detected the most important signaling pathways, including molecular mechanism of cancers, prostate cancer signaling, ovarian cancer signaling, P53 signaling, oncostatin M signaling, and their respective functions (viz., prostate cancer, breast cancer, progression of tumor, growth of tumor, and non-Hodgkin’s disease). The results suggest that PCB exposures, even at the early age of these children, may have lifelong consequences for the future development of chronic diseases.

  相似文献   
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• In situ preparation of FeNi nanoparticles on the sand via green synthesis approach. • Removal of tetracycline using GS-FeNi in batch and column study. • Both reductive degradation and sorption played crucial role the process. • Reusability of GS-FeNi showed about 77.39±4.3% removal on 4th cycle. • TC by-products after interaction showed less toxic as compared with TC. In this study, FeNi nanoparticles were green synthesized using Punica granatum (pomegranate) peel extract, and these nanoparticles were also formed in situ over quartz sand (GS-FeNi) for removal of tetracycline (TC). Under the optimized operating conditions, (GS-FeNi concentration: 1.5% w/v; concentration of TC: 20 mg/L; interaction period: 180 min), 99±0.2% TC removal was achieved in the batch reactor. The removal capacity was 181±1 mg/g. A detailed characterization of the sorbent and the solution before and after the interaction revealed that the removal mechanism(s) involved both the sorption and degradation of TC. The reusability of reactant was assessed for four cycles of operation, and 77±4% of TC removal was obtained in the cycle. To judge the environmental sustainability of the process, residual toxicity assay of the interacted TC solution was performed with indicator bacteria (Bacillus and Pseudomonas) and algae (Chlorella sp.), which confirmed a substantial decrease in the toxicity. The continuous column studies were undertaken in the packed bed reactors using GS-FeNi. Employing the optimized conditions, quite high removal efficiency (978±5 mg/g) was obtained in the columns. The application of GS-FeNi for antibiotic removal was further evaluated in lake water, tap water, and ground water spiked with TC, and the removal capacity achieved was found to be 781±5, 712±5, and 687±3 mg/g, respectively. This work can pave the way for treatment of antibiotics and other pollutants in the reactors using novel green composites prepared from fruit wastes.  相似文献   
6.
Titania (TiO2) has been the focus of attention of researchers since the first demonstration of its capability to generate the photocatalytic splitting of water into hydrogen and oxygen. However, there seems to be a recent surge in the research activity, involving modified TiO2 nanoparticles (NP), which are considered to be more effective due to different physicochemical properties in comparison to unmodified fine particle analogs. Several strategies have been employed to modify TiO2 to reduce recombination rates of photogenerated charge carriers to enhance the optimal functioning of TiO2. Doping with cations and anions and coupling it with another semiconductor are the most well-known modification methods used. Titania nanocomposites are known to have a plethora of applications. Photoexcitation of these particles are seen to be extraordinarily effective in eliciting microbial death which makes it an attractive candidate for the manufacturing of antimicrobial coatings. On the other hand, TiO2 induces the oxidation of various organic refractory compounds like tetracycline, sulfamethazine, and bisphenol. The photo-electrocatalytic oxidation technique which amalgamates the principle of photocatalysis and electrolysis serves as a newer, unswerving, and cost effective water treatment process. In the biomedical arena, use is now acknowledged for the photodynamic therapy of cancer, cell imaging, biological sensors, drug delivery system, and as endonucleases. In the commercial front, it is utilized in creams owing to its small particle size, which facilitates absorption through skin. It is also employed as ultraviolet blocking agents in sunscreen and commonly encountered as a brilliant white pigment in paint due to its brightness, high refractive index and resistance to discoloration. Its use in solar cells has also been reported. This review aims to encompass the new progress of modified TiO2 nanocomposites for efficient applications, emphasizing the future trends of TiO2 in arenas like healthcare, environment, biomedical, food, personal care, and pharmacy and also highlights the commercial implications of this promising nanomaterial.  相似文献   
7.
在这项研究中,我们探索了利用疏水性有机化学品(HOCs)开发的策略对甲基汞(MeHg)进行平衡被动采样的概念。被动取样应允许基于平衡分配到取样器中的基础上预测沉积物孔隙水(MeHgCL)中MeHg的化学不稳定部分的浓度,而无需模拟通过取样器材料的扩散速率。我们的目标是确定具有模拟甲基汞在动物和沉积物中分配的潜力的取样器材料,并在适合于原位取样器的时间框架内提供可逆吸附。测试的候选材料包括一系列嵌有合适的甲基汞吸收剂的聚合物。最有潜力的是琼脂糖包埋的活性炭(AC)、琼脂糖包埋的巯基自组装膜(SMS)和半胱氨酸功能化聚对苯二甲酸乙二醇酯(PET),对MeHgOH和MeHg与溶解有机物(Suwannee河腐殖酸)的络合作用,测井采样器的水分配系数(Kpw)为2.8~5。沉积物中采样器的平衡时间约为1~2周。琼脂糖包埋AC对MeHg积累机制的研究表明,样品受MeHg与AC颗粒相互作用的动力学影响,而不受凝胶扩散的限制。AC显示Hg和MeHg的相对快速解吸,表明该吸附剂能够进行可逆的平衡测量。在沉积物:水的微观结构中,用等温线校准的被动取样器测得的孔隙水浓度与直接测得的浓度在2倍(未经修正的沉积物)或4倍(经修正的AC沉积物)内一致。这项工作为甲基汞的被动采样提供了一种潜在的新途径。  相似文献   
8.
A novel approach for the green synthesis of silver nanoparticles (AgNPs) from aqueous solution of AgNO3 using culture supernatant of phenol degraded broth is reported in this work. The synthesis was observed within 10 h, and AgNPs showed characteristic surface plasmon resonance around 410 nm. Spherical nanoparticles of size less than 30 nm were observed in transmission electron microscopy. X-ray diffraction pattern corresponding to 111, 200, 220, and 311 revealed the crystalline nature of the as-formed nanoparticles. It was found that the colloidal solution of AgNP suspensions exhibited excellent stability over a wide range of ionic strength, pH, and temperature. The effect of pH and ionic strength indicated that stabilization is due to electrostatic repulsion arising from the negative charge of the conjugate proteins. The AgNPs showed highly potent antimicrobial activity against Gram-positive, Gram-negative, and fungal microorganisms. The as-prepared AgNPs showed excellent catalytic activity in reduction of 4-nitrophenol to 4-aminophenol by NaBH4. By manufacturing magnetic alginate beads, the reusability of the AgNPs for the catalytic reaction has been demonstrated.  相似文献   
9.
Coastal regions have long been settled by humans due to their abundant resources for livelihoods, including agriculture, transportation, and rich biodiversity. However, natural and anthropogenic factors, such as climate change and sea-level rise, and land subsidence, population pressure, developmental activities, pose threats to coastal sustainability. Natural hazards, such as fluvial or coastal floods, impact poorer and more vulnerable communities greater than more affluent communities. Quantitative assessments of how natural hazards affect vulnerable communities in deltaic regions are still limited, hampering the design of effective management strategies to increase household and community resilience. Drawing from Driving Forces–Pressure–State–Impact–Response (DPSIR), we quantify the associations between household poverty and the likelihood of material and human loss following a natural hazard using new survey data from 783 households within Indian Sundarban Delta community. The results suggest that the poorest households are significantly more likely to endure material and human losses following a natural hazard and repeated losses of livelihood make them more vulnerable to future risk. The results further suggest that salinization, tidal surge, erosion, and household location are also significant predictors of economic and human losses. Given the current and projected impact of climate change and importance of delta regions as the world’s food baskets, poverty reduction and increase societal resilience should be a primary pathway to strengthen the resilience of the poorest populations inhabiting deltas.  相似文献   
10.
The shoreline position is difficult to predict but the trend of erosion or accretion can be determined by geospatial and statistical techniques which may help in reducing the loss of property. The study aims to assess the shoreline changes and prediction in Sagar Island, a delta of the Ganges, situated in West Bengal, India. Shorelines have been delineated by using Tasseled Cap Transformation techniques from the Landsat MSS (1975), Landsat TM (1989, 1991) and Landsat ETM+ (1999, 2002, 2005, 2008, and 2011) images. The uncertainty was calculated for every year for assessing the positional error related to shoreline extraction. Total shoreline change rate/year has also been calculated and the uncertainty of total shoreline change rate was found ±3.20 m/year. In the present study, End Point Rate (EPR) and Linear Regression (LR) methods have been used for shoreline change rate calculation and prediction of shoreline. Long term (1975–2002) and short term (2002–2011) erosion and accretion rates were calculated for the study area. Sagar is the biggest island of the Sundarban region; so, it was divided into three segments in order to analyze the change on a segment basis. It was observed that the most of erosion occurred in the Segment B (south Sagar). The rate of erosion was ?7.91 and ?7.01 m/year for the periods 1975–2002 and 2002–2011 respectively. The mean shoreline change rate was high in Segment B (South Sagar) with values of ?6.46 m/year (1975–2002) but the rate was decreased into ?5.25 m/year during the later period (2002–2011). The study reveals that most of the southern part of Sagar Island is vulnerable to high rate of shoreline erosion.  相似文献   
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