Triphenyl methyl phosphonium tosylate as an efficient phase transfer catalyst for ultrasound-assisted oxidative desulfurization of liquid fuel

Environmental Science and Pollution Research - The novel phosphonium-based ionic liquid (IL), triphenyl methyl phosphonium tosylate ([TPMP][Tos]), has been synthesized and applied as a phase...     

Dynamics of Tree and Shrub Vegetation in the Eastern Sayan Mountain Tundra

Russian Journal of Ecology - Climate change entails shifts in the ranges of woody plants along both latitudinal and altitudinal gradients in the boreal forest biome. In this study,...     

Subsurface nutrient modelling using finite element model under Boro rice cropping system

Boro rice, an emerging low-risk crop variety of rice, cultivated using residual or stored water after Kharif season. To enhance the quality and production of rice, potassium (K) and phosphorus (P) are the common constituents of agricultural fertilizers. However, excess application of fertilizers causes leaching of nutrients and contaminates the groundwater system. Therefore, assessment and optimization of fertilizer dose are needed for better management of fertilizers. Towards this, the present study determines the path, persistence, and mobility of K and P under the Boro rice cropping system. The experimental site consisted of four plots having Boro rice with four different fertilizer doses of nitrogen (N), P, K viz. 100%, 75%, 50%, and 25% of the recommended dose. Disturbed soil samples were analysed for K and P from pre-sown land to tillering stage at 0–5, 5–10, 10–15, 15–30, 30–45, and 45–60 cm depths. Simultaneously, K and available P were also simulated in the subsurface soil layers through the HYDRUS-1D model. The statistical comparisons were made with RMSER, E, and PBIAS between the modelled values and laboratory-measured values. Although, the results showed that all the treatments considered had agreeable simulations for both K and P, the K simulations were found to be better as compared to P simulations except for 25% where P simulations outperformed K. The simulated concentration at all doses was found most appropriate when measured for the subsurface layers (up to 45 cm), while showed an underestimation in the bottom layers (45–60 cm) of soil.

     

Investigation of long-term river water quality variations using different urbanization indices and assessment of common scientific perspectives of urbanization on water quality

This study investigated the water quality variation spanning 30 years (1986–2017) in 16 catchments of Hong Kong against different urbanization indices, namely, built area fraction; population; and product of population and built area fraction. Pearson correlations of three different periods of time (1988–1990, 1998–2000, and 2015–2017) indicated that water quality trends were dependent on the urbanization index. Total solids, nitrite-nitrogen, total phosphorus, electrical conductivity, dissolved oxygen, and flow rate had significant deteriorative trends (Pearson r > 0.5 and p < 0.05) with population and product of built area and population. Results also interpreted that built area fraction and product of built area and population were the worst and best indices that represented urbanization and/or its impacts, respectively. Mann-Kendall test for the entire 30 year period showed that water quality had improved with time with respect to certain water quality parameters (e.g., dissolved oxygen, ammoniacal nitrogen and total suspended solids). The results portrayed that although the urbanization of catchments had increased with time, the river water quality with respect to many parameters showed signs of improvement and the legislative measures implemented seemed to be effective in controlling pollution.     

Sulfonated graphene nanomaterials for membrane antifouling,pollutant removal,and production of chemicals from biomass: a review

Water pollution and the unsustainable use of fossil fuel derivatives require advanced catalytic methods to clean waters and to produce fine chemicals from modern biomass. Classical homogeneous catalysts such as sulfuric, phosphoric, and hydrochloric acid are highly corrosive and non-recyclable, whereas heterogeneous catalysts appear promising for lignocellulosic waste depolymerization, pollutant degradation, and membrane antifouling. Here, we review the use of sulfonated graphene and sulfonated graphene oxide nanomaterials for improving membranes, pollutant adsorption and degradation, depolymerization of lignocellulosic waste, liquefaction of biomass, and production of fine chemicals. We also discuss the economy of oil production from biomass. Sulfonated graphene and sulfonated graphene oxide display an unusual large theoretical specific surface area of 2630 m²/g, allowing the reactants to easily enter the internal surface of graphene nanosheets and to reach active acid sites. Sulfonated graphene oxide is hydrophobic and has hydrophilic groups, such as hydroxyl, carboxyl, and epoxy, thus creating cavities on the graphene nanosheet’s surface. The adsorption capacity approached 2.3–2.4 mmol per gram for naphthalene and 1-naphthol. Concerning membranes, we observe an improvement of hydrophilicity, salt rejection, water flux, antifouling properties, and pollutant removal. The nanomaterials can be reused several times without losing catalytic activity due to the high stability originating from the stable carbon–sulfur bond between graphene and the sulfonic group.

     

Changes in the Distribution of Broadleaf Tree Species in the Central Part of the Southern Urals since the 1970s

Russian Journal of Ecology - Changes in the distribution of broadleaf tree species—Tilia cordata Mill., Quercus robur L., Acer platanoides L., and Ulmus glabra Huds.—in the central part...     

The deflectors influence on flow complexity,bed morphology,sediment transport and water quality of urban lotic waters - A laboratory study

In this laboratory study different combinations of bed (sand, pebble gravel [gravel], and a mix of sand and gravel) and flow (typical and overtopping) were experimented with to investigate the impact of porous deflectors in flow diversity, water quality, and fish performance in prismatic open channels. Deflectors changed the gradually varied flow to a rapidly varied flow, as a sudden change in the water depth was observed at the deflectors, and this change was large for smooth beds. With the presence of gravel, the scouring near the downstream deflector was almost twice that of the sand bed, and with the scouring at its own upstream deflector, irrespective of whether the flow was typical or overtopping. This behavior was a result of sand mobilization due to shear stress and sand mobilization aided gravel transport. The mixed bed showed less gravel movement compared to the gravel-only bed. The percentage of sediment washed out was minor for all bed scenarios, indicating that sediment transport was local. Relative to the sand bed without deflectors (representing a typical urban canal), deflectors resulted in reduced and improved water quality (in terms of sediment load) for sand, and mixed bed, respectively. The fishes found refuge and were comfortable in the pool areas created by deflectors unlike in channels without deflectors where they showed exhaustion.     

Responses of Different Test Objects to Experimental Soil Contamination with Crude Oil

Russian Journal of Ecology - Responses to contamination of several soil types with crude oil were comparatively analyzed in organisms of different trophic groups. Samples of soddy podzolic, light...     

Improving the feasibility of aquaculture feed by using microalgae

Environmental Science and Pollution Research - The aquaculture industry is an efficient edible protein producer and grows faster than any other food sector. Therefore, it requires enormous amounts...     

Carbon and nitrogen mineralization in Vertisol as mediated by type and placement method of residue

Selection of appropriate residue application method is essential for better use of biomass for soil and environmental health improvement. A laboratory incubation experiment was conducted for 75 days to investigate C and N mineralization of residues of soybean (Glycine max L.), chickpea (Cicer arietinum L.), maize (Zea mays L.), and wheat (Triticum aestivum L.) placed on the soil surface and incorporated into the soil. The residue of soybean and chickpea had a greater decomposition rate than that of maize and wheat, despite of their placements. Higher rate of decomposition of the residue of soybean and chickpea was recorded when it was kept on the soil surface while soil incorporation of residue of wheat and maize resulted in faster decomposition. Therefore, these findings could be used as guidelines for management of crop residue application in farmland to improve soil and environmental quality.