In vitro methane removal by volcanic pumice soil biofilter columns over one year

Soil methane (CH(4)) biofilters, containing CH(4)-oxidizing bacteria (methanotrophs), are a promising technology for mitigating greenhouse gas emissions. However, little is known about long-term biofilter performance. In this study, volcanic pumice topsoils (0-10 cm) and subsoils (10-50 cm) were tested for their ability to oxidize a range of CH(4) fluxes over 1 yr. The soils were sampled from an 8-yr-old and a 2-yr-old grassed landfill cover and from a nearby undisturbed pasture away from the influence of CH(4) generated by the decomposing refuse. Methane was passed through the soils in laboratory chambers with fluxes ranging from 0.5 g to 24 g CH(4) m(-3) h(-1). All topsoils efficiently oxidized CH(4). The undisturbed pasture topsoil exhibited the highest removal efficiency (24 g CH(4) m(-3) h(-1)), indicating rapid activation of the methanotroph population to the high CH(4) fluxes. The subsoils were less efficient at oxidizing CH(4) than the topsoils, achieving a maximum rate oxidation rate of 7 g CH(4) m(-3) h(-1). The topsoils exhibited higher porosities; moisture contents; surface areas; and total C, N, and available-P concentrations than the subsoils, suggesting that these characteristics strongly influence growth and activity of the CH(4)-oxidizing bacteria. Soil pH values and available-P levels gradually declined during the trial, indicating a need to monitor chemical parameters closely so that adjustments can be made when necessary. However, other key soil physicochemical parameters (moisture, total C, total N) increased over the course of the trial. This study showed that the selected topsoils were capable of continually sustaining high CH(4) removal rates over 1 yr, which is encouraging for the development of biofilters as a low-maintenance greenhouse gas mitigation technology.     

Interpreting sustainable development

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Fate of nitrogen for subsurface drip dispersal of effluent from small wastewater systems

Subsurface drip irrigation systems apply effluent from onsite wastewater systems in a more uniform manner at a lower rate than has been possible with other effluent dispersal methods. The effluent is dispersed in a biologically active part of the soil profile for optimal treatment and where the water and nutrients can be utilized by landscape plants. Container tests were performed to determine the fate of water and nitrogen compounds applied to packed loamy sand, sandy loam, and silt loam soils. Nitrogen removal rates measured in the container tests ranged from 63 to 95% despite relatively low levels of available carbon. A Hydrus 2D vadose zone model with nitrification and denitrification rate coefficients calculated as a function of soil moisture content fit the container test results reasonably well. Model results were sensitive to the denitrification rate moisture content function. Two-phase transport parameters were needed to model the preferential flow conditions in the finer soils. Applying the model to generic soil types, the greatest nitrogen losses (30 to 70%) were predicted for medium to fine texture soils and soils with restrictive layers or capillary breaks. The slow transport with subsurface drip irrigation enhanced total nitrogen losses and plant nitrogen uptake opportunity.     

Marine protected areas and local coastal conservation and management in Hong Kong

This paper focuses on the role of marine parks and reserves in the conservation of Hong Kong's coastal environment. This environment is under serious threat as a result of pollution of marine waters and habitat loss associated with urbanisation, large-scale reclamation projects, and inadequate treatment and disposal of sewage and industrial effluents. The paper discusses whether in a highly urbanised and stressed environment like Hong Kong, which currently lacks a conservation strategy and an overall framework for handling sustainability issues, small marine parks and reserves can be effective in helping to conserve local biodiversity. The paper also suggests that Hong Kong should adopt a broader regional perspective on its coastal conservation and management problems, a perspective that recognises the significance for the territory of the rapid urban and industrial development taking place in neighbouring Guangdong Province. This will require more extensive and focused liaison with Chinese agencies.     

Environmental education,community mobilization and sustainable development in Hong Kong: a comparative perspective

SUMMARY

This paper focuses on efforts to promote environmental education and community mobilization around environmental issues in Hong Kong. It is primarily concerned with efforts directed at the broader community (i.e. the population as a whole) rather than with environmental education through formal school and college curricula. The paper draws on a recently completed study commissioned by the Environmental Campaign Committee, the principal source of financial support for such efforts undertaken by environmental NGOs, community groups and educational institutions in Hong Kong. The study examined how and to what effect the Committee had used its financial resources between 1994–1999. It also examined international experience with a view to recommending changes in the overall approach to environmental education and community mobilization initiatives and their funding in Hong Kong.

The paper suggests that the existing approach to community-wide environmental education and its funding in Hong Kong have suffered from various weaknesses, most notably the absence of an integrated and goal-oriented strategy, an over-reliance on a ‘top-down’ campaign-based approach, a failure to establish explicit linkages with the concept of sustainable development and to ground initiatives at the local neighbourhood and community levels, and a preoccupation with the financial inputs provided to support this work at the expense of effective monitoring and auditing of project outputs and benefits.     

A social and ecological imperative for ecosystem-based adaptation to climate change in the Pacific Islands

Climate change is predicted to have a range of impacts on Pacific Island ecosystems and the services they provide for current and future development. There are a number of characteristics that can make adaptation approaches that utilise the benefits of ecosystems a compelling and viable alternative to other adaptation approaches. The objective of this paper is to determine what level of relative influence technical and planning considerations currently have in guiding the recognition and application of ecosystem-based adaptation (EbA) approaches in the Pacific Islands context. The technical feasibility of EbA in relation to the expected impacts of climate change and the compatibility of adaptation planning processes of the Pacific Islands with EbA requirements was considered. The main barrier to fully implementing EbA in the Pacific Islands is not likely to be financial capital, but a combination of stable technical capacity within government departments to advise communities on EbA opportunities and the compatibility of planning frameworks.     

Immobilisation of heavy metal in cement-based solidification/stabilisation: a review

Heavy metal-bearing waste usually needs solidification/stabilization (s/s) prior to landfill to lower the leaching rate. Cement is the most adaptable binder currently available for the immobilisation of heavy metals. The selection of cements and operating parameters depends upon an understanding of chemistry of the system. This paper discusses interactions of heavy metals and cement phases in the solidification/stabilisation process. It provides a clarification of heavy metal effects on cement hydration. According to the decomposition rate of minerals, heavy metals accelerate the hydration of tricalcium silicate (C3S) and Portland cement, although they retard the precipitation of portlandite due to the reduction of pH resulted from hydrolyses of heavy metal ions. The chemical mechanism relevant to the accelerating effect of heavy metals is considered to be H+ attacks on cement phases and the precipitation of calcium heavy metal double hydroxides, which consumes calcium ions and then promotes the decomposition of C3S. In this work, molecular models of calcium silicate hydrate gel are presented based on the examination of 29Si solid-state magic angle spinning/nuclear magnetic resonance (MAS/NMR). This paper also reviews immobilisation mechanisms of heavy metals in hydrated cement matrices, focusing on the sorption, precipitation and chemical incorporation of cement hydration products. It is concluded that further research on the phase development during cement hydration in the presence of heavy metals and thermodynamic modelling is needed to improve effectiveness of cement-based s/s and extend this waste management technique.