A fragment constant QSAR model for evaluating the EC50 values of organic chemicals to Daphnia magna.

The quantitative relationship between the median effective concentration (EC50) of organic chemicals to Daphnia magna and the number of molecular fragments was investigated based on experimental EC50 values for 217 chemicals derived from the literature. A fragment constant model was developed based on a multivariate linear regression between the number of fragments and the logarithmically transformed reciprocal values of EC50. Functional correction factors were introduced into the model. The model was verified using an independent set of randomly selected data. The mean residual of the final model was 0.4 log-units. The robustness of the model was discussed based on the results of three jackknife tests.     

Initial ecological risk assessment of eight selected human pharmaceuticals in Japan.

Eight pharmaceuticals were selected on the basis of their domestic consumption in Japan, the excretion ratio of the parent compound and the frequency of detection in the aquatic environment or wastewater treatment plant effluent. Toxicity tests on these pharmaceuticals were conducted using Japanese medaka (Oryzias latipes), daphnia (Daphnia magna), and green algae (Psuedokirchneriella subcapitata). Predicted no effect concentration (PNEC) was calculated using lethal or effect concentration 50 (LC50 or EC50) values and no effect concentration (NOEC) obtained in the toxicity tests for these compounds. Predicted environmental concentration (PEC) was also calculated from annual consumption, the excretion rate of the parent compound, and removal rate in the preliminary batch activated sludge treatment performed in this study. Maximum concentrations found in the aquatic environment or sewage effluent in Japan or foreign countries were also used for another calculation of PEC. Initial risk assessment on the selected pharmaceuticals was performed using the PEC/PNEC ratio. The results of initial risk assessment on the eight selected pharmaceuticals suggest neither urgent nor severe concern for the ecological risk of these compounds, but further study needs to be conducted using chronic toxicity tests, including reproduction inhibition and endocrine disruption assessments.     

金属对催化还原DDT的降解产物及其反应机制的研究

本报告介绍DDT经金属对处理后降解产物的分析鉴定和有关反应机制的初步研究。 降解产物主要是用气相色谱—质谱联用分析鉴定的。水溶液中的DDT用Cu-Zn金属对还原其降解产物经鉴定是DDD、DDMS、DDE_t,它们是DDT分子脱去烷基碳原子上不同数目的氯原子的产物。而在Cu-Fe金属对作用下,水溶液中的DDT的还原则是同时得到四种不同类型的产物。它们是DDT脱去烷基碳原子上的1个和3个氯原子的DDD和DDE_t;DDT脱氯、氧化产物DBP和DBH;DDT脱去HCI生成的DDE;两个DDT分子二聚脱氯的产物TTTB和TTDB。 实验证明金属对对DDT的作用是催化还原反应,金属对起着催化剂和还原剂双重作用。通过实验结果对DDT在金属对作用下的反应机制进行了初步探讨。     

江苏小梅岭硅灰石矿床特征及其成因

江苏溧阳小梅岭硅灰石矿产于二叠系栖霞组硅质岩中，其成矿热液主要来自庙西花岩岩体。矿体以层状产出，矿石为不规则透镜体，方解石和硅灰石常常互层，常见有硅质岩核心。伴生矿物主要有透辉石、绿帘石、符山石、鱼眼石和萤石。根据x射线衍射分析研究，矿区内硅灰石均属三斜低温硅灰石，其a=-7．934，B0＝7．321，C0=7．068，红外光谱和差热分析表明，该硅灰石矿杂质含量较少。根据野外地质条件和理论反应式、反应曲线，小梅岭硅灰石矿形成于半封闭的体系，其形成温度和压力均属中等。     

适宜国内现状的生态工业园建设的初探

生态工业园是实现可持续发展的途径之一.文中根据当前国内工业布局、土地资源现状,并结合各种类型生态工业园特征,指出对现有企业和工业园区的改造,以及构建虚拟型生态工业园,是适宜当前国内现状的生态工业园建设类型.     

海37引信回转体座冷挤压工艺

回转体座是海37引信中的关键件,要求有一定的机械强度、耐磨性.研制期间,曾用压铸铝合金,由于铝合金压铸内部存在着气孔,表面粗糙.不能满足其机械性能的要求.针对这一现象,研制了回转体座冷挤压成形工艺,零件表面质量好,成本低,满足了产品的机械性能要求.     

织物干洗的工业生态研究

正确评价干洗剂对人体的毒副作用，合理地设定干洗过程挥发性有害物质的残留限量，是开发干洗业环境无害技术和绿色服务的先决条件。只有在充分保证环境安全的前提下，通过逐步推行化学清洁产品的总体选择战略，从环境管理和经济发展的结合上来规范企业的环境行为，才能最终实现干洗业的可持续发展。     

大连声环境质量的灰色预测研究

根据1999年～2003年大连市区声环境质量的监测数据，采用两次残差修正GM（1，1）对2010年前声环境质量进行预测结果表明，修正后模型均为一级模型，进行中、短期预测精度高。预测结果可为城市噪声污染防治提供科学的依据。     

超深厌氧塘的技术特性

超深厌氧塘是一种稳定塘新工艺。与常规厌氧塘相比，具有ＢＯＤ５容积负荷大、占地面积小，受温度影响小的优点。探讨了它的工作机理，本研究确定了负荷、水深和去除率之间的定量关系以供实际应用。     

国外感染性废弃物的管理

感染性废气物对人们的身心健康有极大的威胁．然而从目前的实际情况来看，相当一部分是与一般城市生活垃圾混合在一起处理的情况较常见。鉴于上述情况．文中将欧美日发达国家对感染性废气物的收集．管理及处理情况给予介绍。