Structure and objectives of the Estonian Environmental Monitoring Program

The transition of Estonia from the fragmented character of environmental protection activities of the former Estonian SSR to a centralised national environmental monitoring program is underway. Estonian Environment Information Centre (EEIC) performed as a main developer of the Estonian Monitoring Program (EMP) structure, coordinates the operation of about 60 subprogrammes of EMP.     

Mobility of heavy metals from polluted sediments of a semi-enclosed basin: in situ benthic chamber experiments in Taranto’s Mar Piccolo (Ionian Sea,Southern Italy)

In situ benthic flux experiments were conducted at two stations in the Mar Piccolo of Taranto (Italy), one of the most industrialised and contaminated coastal areas of the Mediterranean. Sediments of the two stations are notably different in their trace metal content, with a station closer to a Navy harbour showing higher mean concentrations of almost all investigated metals (Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn). Conversely, both stations are characterised by significant Hg contamination, compared to the local baseline. Results of a sequential extraction scheme on surface sediments suggest a relatively scarce mobility of the examined metals (Zn > Ni > Cr > As > Cu > Pb). A Hg-specific extraction procedure showed that most of the element (93.1 %) occurs in a fraction comprising Hg bound to Fe/Mn oxi-hydroxides. Reduction of these oxides may affect Hg remobilisation and redistribution. Porewater profiles of dissolved trace metals were quite similar in the two sites, although significant differences could be observed for Al, Cu, Fe and Hg. The highest diffusive fluxes were observed for As, Fe and Mn. Mobility rates of several trace elements (Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn) were directly measured at the sediment–water interface. Results from benthic in situ incubation experiments showed increasing dissolved metal concentrations with time, resulting in higher fluxes for Cu, Fe, Hg, V and Zn in the most contaminated site. Conversely, fluxes of Mn, Ni and Pb were comparable between the two stations. The estimated flux of Hg (97 μg m^?2 day^?1) was the highest observed among similar experiments conducted in other highly contaminated Mediterranean coastal environments. Benthic fluxes could be partially explained by considering rates of organic matter remineralisation, dissolution of Fe/Mn oxy-hydroxides and metal speciation in sediments. Seasonal and spatial variation of biogeochemical parameters can influence metal remobilisation in the Mar Piccolo area. In particular, metals could be promptly remobilised as a consequence of oxygen depletion, posing a serious concern for the widespread fishing and mussel farming activities in the area.     

Hydrological Controls and Freshening in Meromictic Soap Lake,Washington, 1939-20021

Kallis, Jahn, Leo Bodensteiner, and Anthony Gabriel, 2010. Hydrological Controls and Freshening in Meromictic Soap Lake, Washington, 1939-2002. Journal of the American Water Resources Association (JAWRA) 46(4): 744-756. DOI: 10.1111/j.1752-1688.2010.00446.x Abstract: The chemically stratified layer of naturally formed meromictic lakes exhibits unusual and often extreme physical and chemical conditions that have resulted in the evolution of uniquely adapted species. The Columbia Basin Irrigation Project appears to have had a marked effect on the hydrology of Soap Lake, a meromictic lake in the Grand Coulee of central Washington. The relation of hydrology to salinity was assessed by analyzing water budgets before and after the introduction of the irrigation project. Before irrigation, water gains were balanced by losses; after irrigation began groundwater gains approximately doubled. To manage lake levels and reduce groundwater influx, wells were installed to intercept groundwater. Although the hydrological cycle has been restored to pre-irrigation conditions, the meromictic character of the lake continues to change. Interception wells remove 10 to 16 Mm³ of groundwater annually, but influx continues based on change in the monimolimnion. From 1958 to 2003 the chemocline descended 1.1 m and the volume of the monimolimnion from 698,000 m³ to 114,000 m³. Annual loss of volume is occurring at a rate of 1.9% since 1958. Although groundwater interception wells are maintaining the volume of the entire lake, the recession of the chemocline indicates that conditions that have maintained meromixis at Soap Lake are currently not in equilibrium.     

Dry FGD at United Power Association’s Stanton Station

The United Power Association’s dry FGD system at Stanton, North Dakota was the first utility-operated lime spray dryer to be put into service in the United States. At 60 MW in size, it utilizes a single spray dryer vessel with three rotary atomizers and a ten-compartment fabric filter. It is currently operating at better than expected efficiency and Is meeting state and federal air quality requirements. Start-up and operation have shown that certain areas of design and operating conditions are critical to reliable operation. Flue gas, slurry, and water distribution and mixing must be carefully controlled if reliable, long term operation is to be achieved. Likewise, water chemistry Is Important in the reagent preparation equipment. Start-up of the system was accomplished In a step-wise fashion to bring the baghouse on line first, followed by the spray dryer. The spray dryer was operated at gradually lower outlet temperatures until design conditions were met. Measures taken since start-up to ensure reliable operation, and operation over an eighteen month period are discussed. Both particulate and SO₂ emission performance are evaluated.     

Partitioning of perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) between water and sediment

Laboratory partitioning experiments were conducted to elucidate the sorption behaviour and partitioning of perfluoroalkyl compounds (PFCs). Three different sediment types were used and separately spiked with perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) at low environmentally realistic concentrations. PFOA, PFOS and PFOSA were mainly distributed in the dissolved phase at low suspended solid concentrations, indicating their long-range transport potential in the marine environment. In all cases, the equilibrium isotherms were linear and the organic carbon normalised partition coefficients (K_OC) decreased in the following order: PFOSA (log K_OC = 4.1 ± 0.35 cm³ g⁻¹) > PFOS (3.7 ± 0.56 cm³ g⁻¹) > PFOA (2.4 ± 0.12 cm³ g⁻¹). The level of organic content had a significant influence on the partitioning. For the sediment with negligible organic content the density of the sediment became the most important factor influencing the partitioning. Ultimately, data on the partitioning of PFCs between aqueous media and suspended solids are essential for modelling their transport and environmental fate.     

Dietary exposure to di-isobutyl phthalate increases urinary 5-methyl-2′-deoxycytidine level and affects reproductive function in adult male mice

Phthalates are a large family of ubiquitous environmental pollutants suspected of being endocrine disruptors. Epidemiological studies have associated phthalate metabolites with decreased reproductive parameters and linked phthalate exposure with the level of urinary 5-methyl-2′-deoxycytidine(5mdC, a product of methylated DNA). In this study, adult male mice were exposed to 450 mg di-isobutyl phthalate(DiBP)/(kg·day) via dietary exposure for 28 days. Mono-isobutyl phthalate(Mi BP, the urinary metabolite) and reproductive function parameters were determined. The levels of 5mdC and 5-hydroxymethyl-2′-deoxycytidine(5hmdC) were measured in urine to evaluate if their contents were also altered by DiBP exposure in this animal model. Results showed that DiBP exposure led to a significant increase in the urinary 5mdC level and significant decreases in sperm concentration and motility in the epididymis, accompanied with reduced testosterone levels and downregulation of the P450 cholesterol side-chain cleavage enzyme(P450scc) gene in the mice testes. Our findings indicated that exposure to DiBP increased the urinary 5mdC levels,which supported our recent epidemiological study about the associations of urinary 5mdC with phthalate exposure in the male human population. In addition, DiBP exposure impaired male reproductive function, possibly by disturbing testosterone levels; P450scc might be a major steroidogenic enzyme targeted by DiBP or other phthalates.     

An in vitro/in vivo screening assay as a sensitive tool to assess endocrine disruptive activity in surface water

Adult male fathead minnow were exposed for 14 or 28-days under flow-through conditions to undiluted filtered water samples from the rivers Meuse and Rhine in the Netherlands. The experiment included two vessels per treatment each containing 10 fish and samples of five fish were taken after 14 and 28 days. Additional groups were exposed to 17alpha-ethinylestradiol (EE2) as a reference and untreated drinking water as a negative control. Major endpoints examined included induction of vitellogenin (VTG) synthesis, VTG mRNA activity, hepato- and gonadosomatic indices (HSI and GSI) and gonadal histology. No significant difference was recorded in body weight or mean GSI values between the various treatments. Only exposure to Meuse water resulted in significantly higher HSI means after 14 days. Histological examination showed no apparent effects on gonadal tissue except for eosinophilic blood plasma in fish exposed to Meuse water or EE2. After 14 and 28 days, elevated VTG and VTG mRNA levels were measured in most livers of the fish exposed to Meuse water, but not in the fish exposed to Rhine water. This was confirmed by measuring estrogenic responses in the in vitro ER CALUX assay. Induction of VTG synthesis proved to be the most sensitive endpoint in the Non Spawning Male Fish Assay for in vivo detection of bio-available estrogenic activity supplementary to a sensitive in vitro assay. The other endpoints examined varied too much and required a higher number of fish or replicates to achieve sufficient power for statistical testing making them less animal friendly.     

ESTIMATED RUNOFF FROM MAN-MADE SNOW1

ABSTRACT: The consumptive loss from man-made snowmaking at six Colorado ski areas is calculated. The focus of the procedures in this investigation is on the consumptive loss that occurs to man-made snow particles during the period they reside on or in the snowpack until spring snowmelt (termed the watershed loss). Calculated watershed losses under a variety of precipitation and temperature conditions at six ski areas varied from 7 to 33 percent. These calculations were made using the calibrated Subalpine Water Balance Simulation Model (Leaf and Brink, 1973a, 1973b). The watershed loss of 7 to 33 percent indicates the range of likely watershed losses that can be expected at Colorado ski areas. A previous paper by the authors (Eisel et al., 1988) provided estimates of the mean consumptive loss during the snowmaking process (termed initial loss) for conditions existing at Colorado ski areas to be 6 percent of water applied. Therefore, based on the mean initial loss, the total consumptive loss from man-made snowmaking under conditions found at Colorado ski areas could be expected to range from 13 to 37 percent. These results demonstrate the range of total consumptive losses that could be expected in various years and for various watershed conditions. These total percentage losses cannot be extrapolated directly to other specific sites because the total consumptive loss is dependent on temperature during actual snowmaking, temperature and precipitation throughout the winter at the specific ski area, and watershed conditions at the ski area. Consumptive losses to man-made snow for a specific ski area should be estimated using the handbook procedures developed especially for this purpose (Colorado Ski Country USA, 1986b).     

SOME PROBLEMS IN STOCHASTIC HYDROLOGY1

In order to decrease the uncertainty that results in water resource planning and management studies due to the assumed recurrence of historical hydrological sequences, considerable study of stochastic processes in hydrology has taken place during the past 10 or 15 years. The general objective has been to develop a capability for generating a number of valid sequences, each of which could as resonably occur as could a recurrence of past events. A number of serious problems have been encountered, the consequence of which has been a serious lag in the application of stochastic processes to real planning and management problems. These problems include: a. an inability to generate droughts in some cases that are as extreme as have occurred historically, b. the generation of inconsistent values of stream flow at 2 locations on the same stream, c. the lack of mathematical techniques for the management of incomplete data sets, d. a great increase in the required computation for planning and management studies, and e. theoretical and computational difficulties in expanding the scope of stochastic hydrology from monthly quantities to short-period quantities. This paper discusses these problems and various approaches used in attempting their solution.     

Using air pollution based community clusters to explore air pollution health effects in children

To study respiratory health effects of long-term exposure to ambient air pollutant mixture, we observed 7058 school children 5-16 years of age living in the four Chinese cities of Lanzhou, Chongqing, Wuhan, and Guangzhou. These children were enrolled from elementary schools located in eight districts, one urban district and one suburban district in each of the above cities. Ambient levels of PM(2.5), PM(10-2.5), total suspended particles (TSP), SO(2), and NO(x) were measured in these districts from 1993 to 1996. Based on a cluster analysis of arithmetic mean concentrations of PM(2.5), PM(10-2.5), (TSP-PM(10)), SO(2), and NO(x), we classified these children into four ordinal categories of exposure to ambient air pollutant mixtures. We tested for exposure-response relationships using logistic regression models, controlling for relevant covariates. We observed monotonic, positive relationships of exposure to the pollutant mixture with prevalence rates of cough with phlegm and wheeze. Other outcomes were not associated with the exposure in a monotonic exposure-response pattern. Even so, odds ratios for cough, phlegm, bronchitis, and asthma in the higher exposure district clusters were all higher than in the lowest exposure district cluster. We found evidence that exposure to the pollutant mixtures had adverse effects on children living in the four Chinese cities.