Triphenyl methyl phosphonium tosylate as an efficient phase transfer catalyst for ultrasound-assisted oxidative desulfurization of liquid fuel

Environmental Science and Pollution Research - The novel phosphonium-based ionic liquid (IL), triphenyl methyl phosphonium tosylate ([TPMP][Tos]), has been synthesized and applied as a phase...     

Subsurface nutrient modelling using finite element model under Boro rice cropping system

Boro rice, an emerging low-risk crop variety of rice, cultivated using residual or stored water after Kharif season. To enhance the quality and production of rice, potassium (K) and phosphorus (P) are the common constituents of agricultural fertilizers. However, excess application of fertilizers causes leaching of nutrients and contaminates the groundwater system. Therefore, assessment and optimization of fertilizer dose are needed for better management of fertilizers. Towards this, the present study determines the path, persistence, and mobility of K and P under the Boro rice cropping system. The experimental site consisted of four plots having Boro rice with four different fertilizer doses of nitrogen (N), P, K viz. 100%, 75%, 50%, and 25% of the recommended dose. Disturbed soil samples were analysed for K and P from pre-sown land to tillering stage at 0–5, 5–10, 10–15, 15–30, 30–45, and 45–60 cm depths. Simultaneously, K and available P were also simulated in the subsurface soil layers through the HYDRUS-1D model. The statistical comparisons were made with RMSER, E, and PBIAS between the modelled values and laboratory-measured values. Although, the results showed that all the treatments considered had agreeable simulations for both K and P, the K simulations were found to be better as compared to P simulations except for 25% where P simulations outperformed K. The simulated concentration at all doses was found most appropriate when measured for the subsurface layers (up to 45 cm), while showed an underestimation in the bottom layers (45–60 cm) of soil.

     

Improving the feasibility of aquaculture feed by using microalgae

Environmental Science and Pollution Research - The aquaculture industry is an efficient edible protein producer and grows faster than any other food sector. Therefore, it requires enormous amounts...     

Effect of Common Chemical Treatments on the Process Kinetics and Mechanical Properties of Flax/Epoxy Composites Manufactured by Resin Infusion

Chemical treatments are widely employed to improve the fiber-matrix adhesion in composites based on eco-friendly fibers such as flax. To better understand the influence of these treatments on processing behavior, this study characterized the surface chemistry and morphology of woven flax fabrics treated by acetone, alkaline, silane and diluted epoxy. Flax/epoxy composites were then manufactured by resin infusion and the flow front and preform thickness evolution was monitored. The alkaline treatment was shown to result in a 50 % increase in equivalent permeability due to an increase in porosity which led to a decrease in flexural properties. The processing results were found to be in good agreement with predictions of a 1-dimensional model. This study suggests that infusion times are not considerably affected by the observed changes in surface energy. However, other implications of the treatments such as an increase in fibrillation can alter the infusion times significantly.

     

Fluoride contamination in and around selected geothermal sites in Odisha,Eastern India: assessment of ionic relations,fluoride exposure and remediation

Environmental Science and Pollution Research - Fluoride contamination in groundwater is a major problem throughout the world as well as in India. High-fluoride content was reported in the hot...     

Antioxidant properties and instrumental quality characteristics of spray dried Pangasius visceral protein hydrolysate prepared by chemical and enzymatic methods

Fish protein hydrolysates are digested form of protein with various bioactive properties where, the cleavages of molecular bonds of proteins can be broken by the enzymatic and chemical process. In this study, antioxidant properties of spray dried protein hydrolysate prepared from Pangasius viscera by using enzymatic (papain and pepsin), and chemical methods (hydrochloric acid and sodium hydroxide) were evaluated. Among the different treatments, pepsin-derived visceral protein hydrolysate showed the maximum antioxidant activity when used at higher concentrations. Essential amino acids (EAA) and hydrophobic amino acids are higher in papain-derived visceral protein hydrolysate. In pepsin-derived visceral protein hydrolysate, major proportion was contributed by glycine (Gly), glutamine (Glu), proline (Pro), and asparagine (Asp). Higher amount of aromatic amino acids are found in alkali-derived FVPH. Scanning electron microscopy (SEM) images of pepsin fish visceral protein hydrolysate showed better globular structure than the other treatments. It can be concluded that among the different treatments, the visceral protein hydrolysate prepared with pepsin had better overall quality regarding antioxidant properties and papain in nutritional point of view.

     

The influence of diesel—truck exhaust particles on the kinetics of the atmospheric oxidation of dissolved sulfur dioxide by oxygen

The automobile exhausts are one of the major sources of particulate matter in urban areas and these particles are known to influence the atmospheric chemistry in a variety of ways. Because of this, the oxidation of dissolved sulfur dioxide by oxygen was studied in aqueous suspensions of particulates, obtained by scraping the particles deposited inside a diesel truck exhaust pipe (DEP). A variation in pH showed the rate to increase with increase in pH from 5.22 to about ～6.3 and to decrease thereafter becoming very slow at pH?=?8.2. In acetate-buffered medium, the reaction rate was higher than the rate in unbuffered medium at the same pH. Further, the rate was found to be higher in suspension than in the leachate under otherwise identical conditions. And, the reaction rate in the blank reaction was the slowest. This appears to be due to catalysis by leached metal ions in leachate and due to catalysis by leached metal ions and particulate surface both in suspensions. The kinetics of dissolved SO₂ oxidation in acetate-buffered medium as well as in unbuffered medium at pH?=?5.22 were defined by rate law: k _obs ?=?k ₀?+?k _cat [DEP], where k _obs and k ₀ are observed rate constants in the presence and the absence of DEP and k _cat is the rate constant for DEP-catalyzed pathway. At pH?=?8.2, the reaction rate was strongly inhibited by DEP in buffered and unbuffered media. Results suggest that the DEP would have an inhibiting effect in those areas where rainwater pH is 7 or more. These results at high pH are of particular significance to the Indian subcontinent, because of high rainwater pH. Conversely, it indicates the DEP to retard the oxidation of dissolved SO₂ and control rainwater acidification.

     

Field performance evaluation during fog-dominated wintertime of a newly developed denuder-equipped PM1 sampler

This study presents the performance evaluation of a novel denuder-equipped PM₁ (particles having aerodynamic diameter less than 1 μm) sampler, tested during fog-dominated wintertime, in the city of Kanpur, India. One PM₁ sampler and one denuder-equipped PM₁ sampler were co-located to collect ambient PM₁ for 25 days. The mean PM₁ mass concentration measured on foggy days with the PM₁ sampler and the denuder-equipped PM₁ sampler was found to be 165.95 and 135.48 μg/m³, respectively. The mean PM₁ mass concentration measured on clear days with the PM₁ sampler and the denuder-equipped PM₁ sampler was observed to be 159.66 and 125.14 μg/m³, respectively. The mass concentration with denuder-fitted PM₁ sampler for both foggy and clear days was always found less than the PM₁ sampler. The same drift was observed in the concentrations of water-soluble ions and water-soluble organic carbon (WSOC). Moreover, it was observed that the use of denuder leads to a significant reduction in the PM positive artifact. The difference in the concentration of chemical species obtained by two samplers indicates that the PM₁ sampler without denuder had overestimated the concentrations of chemical species in a worst-case scenario by almost 40 %. Denuder-fitted PM₁ sampler can serve as a useful sampling tool in estimating the true values for nitrate, ammonium, potassium, sodium and WSOC present in the ambient PM.