Selective separation of cobalt versus nickel by split-phosphinate complexation using a phosphonium-based ionic liquid

Environmental Chemistry Letters - The rising demand of metals for batteries is calling for advanced methods to separate metallic mixtures in mineral ores and electronic waste. In particular, the...     

Forest policies and programs affecting vulnerability and adaptation to climate change

Due to large scale afforestation programs and forest conservation legislations, India’s total forest area seems to have stabilized or even increased. In spite of such efforts, forest fragmentation and degradation continues, with forests being subject to increased pressure due to anthropogenic factors. Such fragmentation and degradation is leading to the forest cover to change from very dense to moderately dense and open forest and 253 km² of very dense forest has been converted to moderately dense forest, open forest, scrub and non-forest (during 2005–2007). Similarly, there has been a degradation of 4,120 km² of moderately dense forest to open forest, scrub and non-forest resulting in a net loss of 936 km² of moderately dense forest. Additionally, 4,335 km² of open forest have degraded to scrub and non-forest. Coupled with pressure due to anthropogenic factors, climate change is likely to be an added stress on forests. Forest sector programs and policies are major factors that determine the status of forests and potentially resilience to projected impacts of climate change. An attempt is made to review the forest policies and programs and their implications for the status of forests and for vulnerability of forests to projected climate change. The study concludes that forest conservation and development policies and programs need to be oriented to incorporate climate change impacts, vulnerability and adaptation.     

Implications of climate change on mitigation potential estimates for forest sector in India

Climate change is projected to impact forest ecosystems, including biodiversity and Net Primary Productivity (NPP). National level carbon forest sector mitigation potential estimates are available for India; however impacts of projected climate change are not included in the mitigation potential estimates. Change in NPP (in gC/m²/yr) is taken to represent the impacts of climate change. Long term impacts of climate change (2085) on the NPP of Indian forests are available; however no such regional estimates are available for short and medium terms. The present study based on GCM climatology scenarios projects the short, medium and long term impacts of climate change on forest ecosystems especially on NPP using BIOME4 vegetation model. We estimate that under A2 scenario by the year 2030 the NPP changes by (−5) to 40% across different agro-ecological zones (AEZ). By 2050 it increases by 15% to 59% and by 2070 it increases by 34 to 84%. However, under B2 scenario it increases only by 3 to 25%, 3.5 to 34% and (−2.5) to 38% respectively, in the same time periods. The cumulative mitigation potential is estimated to increase by up to 21% (by nearly 1 GtC) under A2 scenario between the years 2008 and 2108, whereas, under B2 the mitigation potential increases only by 14% (646 MtC). However, cumulative mitigation potential estimates obtained from IBIS—a dynamic global vegetation model suggest much smaller gains, where mitigation potential increases by only 6% and 5% during the period 2008 to 2108.     

Robustness of Meteorological Droughts in Dynamically Downscaled Climate Simulations

We examine the robustness of a suite of regional climate models (RCMs) in simulating meteorological droughts and associated metrics in present‐day climate (1971‐2003) over the conterminous United States (U.S.). The RCMs that are part of North American Regional Climate Change Assessment Program (NARCCAP) simulations are compared with multiple observations over the climatologically homogeneous regions of the U.S. The seasonal precipitation, climatology, drought attributes, and trends have been assessed. The reanalysis‐based multi‐model median RCM reasonably simulates observed statistical attributes of drought and the regional detail due to topographic forcing. However, models fail to simulate significant drying trend over the Southwest and West. Further, reanalysis‐based NARCCAP runs underestimate the observed drought frequency overall, with the exception of the Southwest; whereas they underestimate persistence in the drought‐affected areas over the Southwest and West‐North Central regions. However, global climate model‐driven NARCCAP ensembles tend to overestimate regional drought frequencies. Models exhibit considerable uncertainties while reproducing meteorological drought statistics, as evidenced by a general lack of agreement in the Hurst exponent, which in turn controls drought persistence. Water resources managers need to be aware of the limitations of current climate models, while regional climate modelers may want to fine‐tune their parameters to address impact‐relevant metrics.     

Assessment of inherent vulnerability of forests at landscape level: a case study from Western Ghats in India

Assessment of vulnerability is an important step in building long-term resilience in the forestry sector. The objective of this paper is to present a methodological approach to assess inherent vulnerability of forests at landscape level. The approach involves use of vulnerability indicators, the pairwise comparison method, and geographic information system (GIS) tools. We apply this approach to assess the inherent vulnerability of forests of the Western Ghats Karnataka (WGK) landscape, which is a part of the Western Ghats biodiversity hotspot in India. Four vulnerability indicators, namely biological richness, disturbance index, canopy cover, and slope, are selected. We find that forests in 30, 36, 19, and 15 % grid points in this region show low, medium, high, and very high inherent vulnerability, respectively. The forest showing high and very high inherent vulnerability are mostly dry deciduous forests and plantations located largely on the eastern side of the landscape. We also find that canopy cover is one of the key indicators that determine the inherent vulnerability of forests, and natural forests are inherently less vulnerable than man-made plantations. Spatial assessment of inherent vulnerability of forests at landscape level is particularly useful for developing strategies to build resilience to current stressors and climate change in future.     

Barriers to plantation activities in different agro-ecological zones of Southern India

This paper analyses environmental and socio-economic barriers for plantation activities on local and regional level and investigates the potential for carbon finance to stimulate the increased rates of forest plantation on wasteland, i.e., degraded lands, in southern India. Building on multidisciplinary field work and results from the model GCOMAP, the aim is to (1) identify and characterize the barriers to plantation activities in four agro-ecological zones in the state of Karnataka and (2) investigate what would be required to overcome these barriers and enhance the plantation rate and productivity. The results show that a rehabilitation of the wasteland based on plantation activities is not only possible but also anticipated by the local population and would lead to positive environmental and socio-economic effects at a local level. However, in many cases, the establishment of plantation activities is hindered by a lack of financial resources, low land productivity and water scarcity. Based on the model used and the results from the field work, it can be concluded that certified emission reductions such as carbon credits or other compensatory systems may help to overcome the financial barrier; however, the price needs to be significantly increased if these measures are to have any large-scale impact.     

Physico-Chemical Quality of Drinking Water in Rohtas District of Bihar

Water Quality Survey of Rohtas district of Bihar was conducted. Samples were collected from differentsources and analysed. 209 samples were collectedfrom 196 villages. Results of water quality surveyidentified the problem areas in respect of high iron,manganese, fluoride, nitrate and brackishness of water in the district.