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1.
Based on density functional theory (DFT) and basic structure models, the chemical reactions on the surface of vanadium-titanium based selective catalytic reduction (SCR) denitrification catalysts were summarized. Reasonable structural models (non-periodic and periodic structural models) are the basis of density functional calculations. A periodic structure model was more appropriate to represent the catalyst surface, and its theoretical calculation results were more comparable with the experimental results than a non-periodic model. It is generally believed that the SCR mechanism where NH3 and NO react to produce N2 and H2O follows an Eley-Rideal type mechanism. NH2NO was found to be an important intermediate in the SCR reaction, with multiple production routes. Simultaneously, the effects of H2O, SO2 and metal on SCR catalysts were also summarized. 相似文献
2.
Ozone (O3), as a harmful air pollutant, has been of wide concern. Safe, efficient, and economical O3 removal methods urgently need to be developed. Catalytic decomposition is the most promising method for O3 removal, especially at room temperature or even subzero temperatures. Great efforts have been made to develop high-efficiency catalysts for O3 decomposition that can operate at low temperatures, high space velocity and high humidity. First, this review describes the general reaction mechanism of O3 decomposition on noble metal and transition metal oxide catalysts. Then, progress on the O3 decomposition performance of various catalysts in the past 30 years is summarized in detail. The main focus is the O3 decomposition performance of manganese oxides, which are divided into supported manganese oxides and non-supported manganese oxides. Methods to improve the activity, stability, and humidity resistance of manganese oxide catalysts for O3 decomposition are also summarized. The deactivation mechanisms of manganese oxides under dry and humid conditions are discussed. The O3 decomposition performance of monolithic catalysts is also summarized from the perspective of industrial applications. Finally, the future development directions and prospects of O3 catalytic decomposition technology are put forward. 相似文献
3.
徐根红 《环境监测管理与技术》2007,19(6):50-51
环境监测实验室的废液处理常常被忽视,提出建立有效的废液管理制度的必要性.有针对性地介绍了环境监测实验室中常见废液的处理方法. 相似文献
4.
环境监测实验室信息管理系统建设——以上海市环境监测中心为例 总被引:6,自引:8,他引:6
简述了实验室信息管理系统(LIMS)的概念和建设LIMS的现实意义,着重介绍了上海市环境监测中心实施LIMS的过程和体会,分析了环境监测实验室在LIMS选型和实施过程中需要注意的问题及LIMS对现行工作的影响,并对需进一步完善的功能提出了建议. 相似文献
5.
郭晓茆 《环境监测管理与技术》2007,19(6):1-3
阐述了环境监测实验室质量监督的重要性及加强质量监督的组织保证、制度建设、工作程序和如何发挥监督作用的思考,以期改善忽视质量监督的局面,进一步提高监测工作质量. 相似文献
6.
流行病学调查结果表明,环境的极低频电磁场暴露与人群某些肿瘤,如白血病、乳腺癌、脑肿瘤等,以及生殖、神经、心血管和内分泌等系统疾患的发病相关,这些结果在一定程度上得到实验室人体测试的支持。然而,极低频电磁场对健康影响的确切效应,迄今尚未能作出结论,亟等进一步开展多层次、多水平的研究。 相似文献
7.
8.
环境监测实验室的检测结果直接为环境管理、污染治理等环保部门提供服务,因此检测数据的准确性十分重要。本文通过对影响环境监测实验室检测结果的因素人、机、料、法、环五个方面入手,详尽地研究这五个方面对检测结果的影响。 相似文献
9.
采用冷原子吸收法,使用便携式测汞仪对实验室空气中汞的浓度进行测定,监测结果表明,环境监测实验室空气中汞的污染较为严重,主要来源于COD、氨氮、大气中氨及汞样品测定时含汞试剂及汞标液的使用和含汞废液的排放。根据对监测结果的评价和分析提出了相应的防治措施,提醒实验室的管理及分析人员,要增强环境保护意识,加强实验室的管理,减少含汞及其它有毒废液的排放,改善实验室的环境空气质量,保护分析人员的身体健康。 相似文献
10.
Travis C Obenshain KR Gunter JT Regens JL Whipple C 《Environmental science and pollution research international》2004,11(5):302-306
GOAL, SCOPE AND BACKGROUND: This paper uses two case studies of U.S. Department of Energy nuclear weapons complex installations to illustrate the integration of expedited site characterization (ESC) and multimedia modeling in the remedial action decision making process. CONCEPTUAL SITE MODELS, MULTIMEDIA MODELS, AND EXPEDITED SITE CHARACTERIZATION: Conceptual site models outline assumptions about contaminates and the spatial/temporal distribution of potential receptors. Multimedia models simulate contaminant transport and fate through multiple environmental media, estimate potential human exposure via specific exposure pathways, and estimate the risk of cancer and non-cancer health outcomes. ESC relies on using monitoring data to quantify the key components of an initial conceptual site model that is modified iteratively using the multimedia model. CASE STUDIES: Two case studies are presented that used the ESC approach: Los Alamos National Laboratory (LANL) and Pantex. LANL released radionuclides, metals, and organic compounds, into canyons surrounding the facility. The Pantex Plant has past waste management operations which included burning chemical wastes in unlined pits, burying wastes in unlined landfills, and discharging plant wastewaters into on-site surface waters. CONCLUSIONS: The case studies indicate that using multimedia models with the ESC approach can inform assessors about what, where, and how much site characterization data needs to be collected to reduce the uncertainty associated with risk assessment. Lowering the degree of uncertainty reduces the time and cost associated with assessing potential risk and increases the confidence that decision makers have in the assessments performed. 相似文献