机动车轮胎磨损颗粒物化学组分特征研究

为研究机动车道路行驶过程中轮胎磨损排放的颗粒物理化特性,利用轮胎轮廓仿真磨耗仪,对国内主流17种轮胎胎面进行仿真磨耗实验,获得颗粒物样品,提取并检测其中18种元素和20种多环芳烃（PAHs）的含量.结果显示,元素和PAHs含量因轮胎品牌和速度等级的不同而差异显著.18种元素平均含量为（99.04±68.43）mg/g,占样品总重的9.90%,其中Si（88.97±67.85）mg/g、Zn（6.77±1.64）mg/g和Na（1.05±0.75）mg/g的平均含量均超过1mg/g,Cd的含量最低,为（0.43±0.31）μg/g.20种PAHs含量之和（∑20PAHs）在12.13~433.64 μg/g,平均为（94.13±110.18）μg/g,PY的平均含量最高（30.98±31.27）μg/g,其次是CHR、BaP、FA、PHE和BghiP,平均含量最低的是AC（0.58±0.2）μg/g;从环数看,以4环PAHs为主（占∑20PAHs的45.03%~67.93%）,其次为3环（平均含量为15.45%）和5环（平均含量为12.62%）.总体来说,国外品牌轮胎样品中元素和PAHs含量略高于国内品牌,而主要PAHs环数略低于国内品牌.     

处理废弃轮胎的一种有效方法——轮胎加筋土结构

废胎占用大量空间 ,且会产生诸多环境问题 ,利用轮胎加筋建筑挡土墙或陡坡 (堤 )是解决该问题的一种有效方法。本文提供了一种加筋堤的设计方法 ,比较了不同加筋模式 ,并对该堤进行了环境及其它指标的评价 ,证明了其可行性。     

关于防范环境突发事件的探索和思考

从环保工作实际出发,阐述了防范环境突发事件的3个长效机制,即排查潜在事故隐患,建立信息系统;依据信息指标,建立预警系统;控制污染事态,构建应急处理系统.     

长大隧道岩爆灾害研究进展

岩爆是长大隧道施工中发生频率较高的突发性地质灾害;岩爆研究对于隧道的勘测设计、施工组织及安全生产具有重要的现实意义.岩爆机理研究是岩爆预测及控制技术发展的基础;由于现有理论的不完善,以之为基础的预报体系及控制技术还不能对岩爆灾害进行准确预报和有效控制.岩石静力学理论在岩爆研究中是重要的,但它还不能阐明岩爆的全部机理.钻爆法开挖过程中,各炮层的顺序起爆、周边眼起爆后开挖轮廓面的瞬时大幅卸载及岩爆事件本身所产生的各类高幅值、陡波前应力波以及它们的叠加效应对于围岩,尤其是处于双向受压、一侧临空、具有发生破坏潜势的既有炮次围岩的扰动作用应该是显著的.围岩也许不会在上述动荷载的一次作用下就发生宏观破坏,但这些应力波的多次扰动,却会在微观-细观尺度上引起围岩累积性损伤的加剧与局部应力环境的恶化,并最终导致裂纹的大规模瞬时动力扩展,伴随晶间、粒间瞬态应变能的高速释放,围岩便会以岩爆的形式失稳.因此,系统进行岩爆灾害的岩石动力学机理研究是必要的.     

页岩气加砂压裂高压管汇失效爆裂风险 控制措施研究与实践

随着页岩气平台井工厂化压裂施工启动,在大排量、高压力、长时间施工条件下,高压管汇失效爆裂大幅增加。为减少高压管汇在压裂过程中失效爆裂风险,运用故障假设、因果分析法从人的因素、物的因素、技术工艺、生产管理、工作环境5个方面分析事故的原因,提出了提升采购产品质量、修订完善高压管汇使用技术规范和管理制度、实施专业化管理、应用大数据管理高压管汇、优化现场地面高压管汇流程分配布局设计与联接工艺等高压管汇失效爆裂风险预防控制措施和失效后应急安全防护措施,建立了生命周期全过程、专业化的高压管汇失效爆裂防控与应急防护体系,实现风险可防受控。为页岩气压裂作业的安全提供了参考。     

废旧轮胎再制造过程的环境污染及防治研究

随着汽车和轮胎行业的迅速发展,由此产生的废旧轮胎也逐年增加。废旧轮胎再利用技术既可解决橡胶资源短缺问题,又能消除黑色污染,是循环经济的重要环节,在推广这一技术的同时,应注意其伴生的环境污染。再利用生产主要分为清洗、打磨、粘中垫胶、粘预硫化胎面、低温硫化等步骤。此过程将产生粉尘、非甲烷总烃废气、橡胶颗粒以及清洗废水等污染物。应对这些污染物采取有效的治理措施,使其满足达标排放和无害化的要求,以达到经济利益和环境保护的双赢。     

浅议轮胎企业有机废气排放因子

介绍了AP-42、GB27632—2011中轮胎企业有机废气污染物情况,并与轮胎企业有机废气污染物实测数据进行比较分析,探讨了有机废气的排放因子。结果表明轮胎企业有机废气主要来自于炼胶、硫化工序,排放主要污染物为颗粒物、二甲苯、非甲烷总烃和二硫化碳,排放因子可参照AP-42确定。     

Immunotoxicity of bisphenol a to Carassius auratus Lymphocytes and macrophages following in vitro exposure

Bisphenol A （BPA） is the monomer component of polycarbonate plastics and classified as an endocrine disrupting chemical （EDC）. The reproductive toxicity of BPA has been extensively studied in mammals; however, relatively little information is available on the immunotoxic responses of fish to BPA. In this study, we investigated the effects of BPA on the immune functions of lymphocytes and macrophages in Carassius auratus. The effects of BPA were compared with those of two natural steroid hormones, estradiol and hydrocortisone. Proliferation of the two types of cells in response to PHA was measured using colorimetric MTT assay. Macrophage respiratory burst stimulated by Con A was measured using chemiluminescence assay. Results showed that BPA （0.054-5.4 mg/L）, estradiol （0.0002-2.0 mg/L） and hydrocortisone （5-50 mg/L） significantly induced Carassius auratus lymphocyte proliferation while higher doses of hydrocortisone （500-5000 mg/L） appeared to be inhibitory. BPA （0.005-50 mg/L）, estradiol （0.005-800 mg/L） and hydrocortisone （0.005-500 mg/L） markedly enhanced macrophage proliferation, whereas higher doses of BPA （500-1000 mg/L） appeared to inhibit cell proliferation. Furthermore, higher dosage of BPA （50 mg/L） and hydrocortisone （50 and 500 mg/L） suppressed the macrophages respiratory burst while estradiol is stimulative all the doses tested （0.05-500 mg/L）. In conclusion, BPA could have immunotoxicity to Carassius auratus and functional changes of lymphocyte and macrophage in Carassius auratus may be different between low and high dosages.     

Effects of long-term amendment of organic manure and nitrogen fertilizer on nitrous oxide emission in a sandy loam soil

To understand the effects of long-term amendment of organic manure and N fertilizer on N2O emission in the North China Plain, a laboratory incubation at different temperatures and soil moistures were carried out using soils treated with organic manure （OM）, half organic manure plus half fertilizer N （HOM）, fertilizer NPK （NPK）, fertilizer NP （NP）, fertilizer NK （NK）, fertilizer PK （NK） and control （CK） since 1989. Cumulative N2O emission in OM soil during the 17 d incubation period was slightly higher than in NPK soil under optimum nitrification conditions （25℃ and 60% water-filled pore space, WFPS）, but more than twice under the optimum denitrification conditions （35℃ and 90% WFPS）. N2O produced by denitrification was 2.1-2.3 times greater than that by nitrification in OM and HOM soils, but only 1.5 times greater in NPK and NP soils. These results implied that the long-term amendment of organic manure could significantly increase the N2O emission via denitrification in OM soil as compared to NPK soil. This is quite different from field measurement between OM soil and NPK soil. Substantial inhibition of the formation of anaerobic environment for denitrification in field might result in no marked difference in N2O emission between OM and NPK soils. This is due in part to more rapid oxygen diffusion in coarse textured soils than consumption by aerobic microbes until WFPS was 75% and to low easily decomposed organic C of organic manure. This finding suggested that addition of organic manure in the tested sandy loam might be a good management option since it seldom caused a burst of N2O emission but sequestered atmospheric C and maintained efficiently applied N in soil.     

Immunosuppression in the infaunal bivalve Scrobicularia plana environmentally exposed to mercury and association with its accumulation

This study aimed to test the hypothesis whether mercury (Hg) activates or suppresses inappropriately the immunity of the bivalve Scrobicularia plana inhabiting a Hg contaminated area (Laranjo basin, Ria de Aveiro, Portugal). Immunity endpoints, as well as lipid peroxidation (LPO) as a sign of damage, were evaluated in parallel with total Hg burden. Bivalves from both moderately (MO) and highly (HI) contaminated sites displayed higher haemolymph Hg load and reduced plasma agglutination. Increased haemocytes density and decreased phagocytosis were observed at HI, whereas increased oxidative burst activity (OBA) was observed at MO, pointing out that the immunotoxicity is a result of Hg direct contact involving no ROS intervention. OBA observed at MO was concomitantly associated to peroxidative damage as depicted by LPO increase in haemocytes and haemolymph plasma. Thus, S. plana can be suggested as a suitable bioindicator of metal pollution in coastal areas on the basis of Hg bioaccumulation and immunotoxicity responses.