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2.
Column experiments were conducted to validate a screening model predicting the influence of pentachlorophenol (PCP) pole-treating oil on the vertical migration of its impurities, chlorinated dioxins and furans (PCDD/Fs). PCP pole-treating oil (15 mL d−1) and water (20 mL d−1) were added daily to the top of sand and organic soil columns during 35 d. Column soil samples were analyzed to determine concentrations of hydrocarbons and PCDD/Fs at several depths in the columns (0-30 cm) and their evolution in time (7, 14, 21 and 35 d).The model predicted a significant vertical migration of PCDD/Fs due to the presence of oil as a free phase and PCDD/Fs were found in the different column layers at concentrations consistent with model predictions (same order of magnitude). Measured PCDD/Fs concentrations are in total disagreement with literature data and with model prediction in the absence of oil free phase, which implies PCDD/F properties alone cannot be used to predict their fate in the current context: the influence of PCP pole-treating oil must be accounted for to properly explain their migration. 相似文献
3.
Magnus Bergknut Hjalmar Laudon 《Environmental pollution (Barking, Essex : 1987)》2010,158(7):2518-2525
The aim of this study was to explore how atmospherically derived soil pollution is affected by environmental processes at two typical boreal catchment landscape type settings: wetlands and forested areas. Measurements of hydrophobic organic compounds (HOCs) in forest soil and peat from an oligotrophic mire at various depths were performed at a remote boreal catchment in northern Sweden. HOCs in peat were evenly distributed throughout the body of the mire while levels of HOCs in the forest soil increased with increased amount of organic matter. Evaluation of HOC composition by principal component analysis (PCA) showed distinct differences between surface soils and deeper soil and peat samples. This was attributed to vertical transport, degradation and/or shifting sources over time. The calculated net vertical transport differed between surface layers (0.3%) and deeper soils (8.0%), suggesting that vertical transport conditions and processes differ in the deeper layers compared to the surface layers. 相似文献
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5.
The objectives of this work were to study the formation mechanisms of polychlorinated dibenzo-p-dioxins/polychlorinated dibenzofurans (PCDD/F) in thermal aluminium recycling processes by use of laboratory experiments. The pattern of isomers of PCDD/F indicates that de novo synthesis is important in aluminium smeltery. The mechanisms of PCDD/F formation in aluminium smelting are similar to that of various incineration processes of waste material. The results of bioanalysis (EROD-test) confirms the existence of de novo synthesis of PCDD/F, but points out to the existence to some additional, toxic compounds of unknown structure. To reduce the amount of PCDD/F the input of carbon at the metal should be reduced; in addition the metal smeltery plants should be cleaned from fly ash particles. It is suggested to use good primary methods in the technical plants like constant feeding of the metal into the oven will minimise PCDD/F concentration. The biological EROD-bioassay is a good tool to estimate PCDD/F-TEQ values also for this technical process simulated in the laboratory. 相似文献
6.
Dioxins and dioxin-like (DL) compounds are some of the most toxic chemicals being highly persistent in the environment. The toxicological effects of dioxins are mediated via the aryl hydrocarbon receptor (AhR). Compounds of diverse structure and lipophility can bind and activate AhR. The AhR transactivation bioassay is utilized in an array of projects to study the AhR-mediated activities of individual chemicals and mixtures and for epidemiological purposes.This review summarizes a series of studies regarding the DL-activity of single compounds and complex compound mixtures in the environment and humans.We found that some pesticides, plasticizers and phytoestrogens can activate the AhR, and the combined effect of compounds with no or weak AhR potency cannot be ignored.The significant DL-activity in the wastewater effluent indicates the treatment is not sufficient to prevent contamination of surface waters with dioxins. Our results from human studies suggest that the serum DL-activity reflect the complex mixture of persistent organic pollutants (POPs). Greenlandic Inuit had lower serum DL-activity level compared to Europeans, probably due to long distance from the dioxin sources and UV degradation of the high potent dioxin and/or the inhibitory effect of the high level of non-DL POPs. Selective bioaccumulation of PCBs in the food chain may contribute to the negative correlation between serum POPs and DL-activity observed in Greenlandic Inuit.Hence the AhR transactivation bioassay provides a cost-effective and integrated screening tool for measurement of the DL-activity in human, environmental and commercial samples. 相似文献
7.
Magnus Bergknut Sandra Meijer Anneli Ågren Stephan Köhler Mats Tysklind 《Environmental pollution (Barking, Essex : 1987)》2010,158(9):2964-2969
The fate of hydrophobic organic compounds (HOCs) in soils and waters in a northern boreal catchment was explored through the development of a chemical fate model in a well-characterised catchment system dominated by two land types: forest and mire. Input was based solely on atmospheric deposition, dominated by accumulation in the winter snowpack. Release from soils was governed by the HOC concentration in soil, the soil organic carbon fraction and soil-water DOC content. The modelled export of selected HOCs in surface waters ranged between 11 and 250 ng day−1 during the snow covered period, compared to 200 and 9600 ng/d during snow-melt; highlighting the importance of the snow pack as a source of these chemicals. The predicted levels of HOCs in surface water were in reasonable agreement to a limited set of measured values, although the model tended to over predict concentrations of HOCs for the forested sub-catchment, by over an order of magnitude in the case of hexachlorobenzene and PCB 180. This possibly reflects both the heterogeneity of the forest soils and the complicated and changing hydrology experienced between the different seasons. 相似文献
8.
By using fluidized-bed furnace and rotary-kiln+stoker furnace and four different kinds of industrial wastes such as waste wood, coffee mill, waste oils and waste plastics, we have drawn the following conclusions:
(1) A relationship between H6CBz and DXN is acquired, which is DXN=0.34×H6CBz1.1.
(2) The following means of emission reduction can be considered. (a) Reduction of DXN and Cl accumulation within the furnace, (b) control by the incinerated object, (c) control through the precursors of H6CBz, (d) improvement through operational control, (e) ammonia injection into the high-temperature zone of the furnace seems to be effective in reducing DXN and (f) DXN concentration is high with CO above 1800 ppm, though it decreases with CO below ≈10 ppm. 相似文献
9.
Kunichika Nakamiya Tohru Furuichi Kazuei Ishii 《Journal of Material Cycles and Waste Management》2002,4(2):127-134
This article reports the potential of denitrifying activated sludge to degrade highly chlorinated dioxins, especially from
a (landfill) leacheate treatment plant in Japan, and the isolation from this denitrifying activated sludge of a microorganism
able to degrade highly chlorinated dioxins. Using a 700-ml bioreactor, denitrifying activated sludge was cultivated under
denitrifying conditions by adding 2.0 ng of a mixture of 4- to 8-chlorinated dioxins from fly ash. The dioxin contents of
the sample, effluent, and medium before and after cultivation were measured by gas chromatography–mass spectrometry (GC–MS).
After 7 days cultivation, about 90% of added dioxins were lost (average percentage of isomer depletion). A dioxin-degrading
microorganism was isolated from the activated sludge. Lignin was added to the medium as a color indicator of aromatic compound
degradation, and the lignin-decolorizing microorganisms in the denitrifying activated sludge were screened. Some strains were
isolated, and one major isolated fungus, strain 622, decolorized lignin effectively. Strain 622 was identified as an Acremonium sp. from its morphological characteristics. It could decolorize lignin by 24% under paraffin-sealed anaerobic conditions.
After the cultivation of strain 622 with a 2 ng/ml mixture of 4- to 8-chlorinated dioxins for 1 day, 82% (average for individual
isomers) of the added 4- to 8-chlorinated dioxins had been degraded. Added octachlorodibenzo-p-dioxin (OCDD, 100 ng) was degraded under aerobic conditions after 8 h of incubation. During this process, heptachlorodibenzo-p-dioxin was produced and appeared to be a degradation product of OCDD. 1- or 2-hydroxydibenzo-p-dioxin from OCDD was also identified as the degradation product by GC–MS. These results indicated that OCDD was degraded
to the nonchlorinated dibenzo-p-dioxins through dechlorination by Acremonium sp. strain 622.
Received: October 12, 2001 / Accepted: March 11, 2002 相似文献
10.